1.
Inorg Chem
; 60(16): 11888-11892, 2021 Aug 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34351755
RESUMO
The Th(NO3)4·5H2O/di(2-pyridyl) ketone [(py)2CO] reaction system gives a pentanuclear cluster containing the doubly deprotonated form of the gem-diol derivative of the ligand. The cluster consists of a tetrahedral arrangement of four ThIV ions centered on the fifth ion, which is the first characterized ThIV5 complex. The analysis of its structure reveals that this is a Kuratowski-type coordination compound.