In Situ Photodeposition of Gold Nanoparticles with Exposed High-Activity Crystal Facets under Different Sacrificial Agents.

In situ photodeposition presents a powerful approach for integrating noble metal co-catalysts onto semiconductor surfaces. However, achieving precise control over the microstructure of the deposited co-catalyst remains a major challenge. Au nanoparticles (NPs) are deposited onto H-KCNO using HAuCl4 in the presence of various sacrificial agents in this study. Notably, the choice of sacrificial agent decisively influences the exposed crystal facets, loaded content, and particle size of the deposited Au NPs. Importantly, in situ photodeposition under an ethanol solution facilitates the exposure of the highly active (111) and (220) crystal facets of Au. The introduction of Au NPs significantly enhances photocatalytic hydrogen evolution, achieving rates of 4.93, 57.88, and 15.44 µmol/h for H-KCNO/Au-(water, ethanol, and lactic acid), respectively. The observed photocatalytic activity for hydrogen evolution indicates that the exposure of the highly active planes emerges as critical for significant performance enhancement. Photoelectrochemical and photoluminescence measurements suggest that the highly active (111) and (220) crystal facets effectively segregate sites for redox reactions, thereby impeding the recombination of photogenerated electron-hole pairs.

Unlock the Visible-Light Photocatalytic OWS by Surface Disorder-Engineered Bi-Based Composite Oxides through Phosphorization.

It has been proven that the introduction of disorder in the surface layers can narrow the energy band gap of semiconductors. Disordering the surface's atomic arrangement is primarily achieved through hydrogenation reduction. In this work, we propose a new approach to achieve visible-light absorption through surface phosphorization, simultaneously raising the energy band structure. In particular, the surface phosphorization of BixY1-xVO4 was successfully prepared by annealing them with a small amount of NaH2PO2 under a N2 atmosphere. After this treatment, the obtained BixY1-xVO4 showed distinct absorption in visible light. The surface phosphorization treatment not only improves the photocatalytic activity of BixY1-xVO4 but also enables visible-light photocatalytic overall water splitting. Furthermore, we demonstrate that this surface phosphorization method is universal for Bi-based composite oxides.

Recent Progress on Hydrogen Production from Ammonia Decomposition: Technical Roadmap and Catalytic Mechanism.

Ammonia decomposition has attracted significant attention in recent years due to its ability to produce hydrogen without emitting carbon dioxide and the ease of ammonia storage. This paper reviews the recent developments in ammonia decomposition technologies for hydrogen production, focusing on the latest advances in catalytic materials and catalyst design, as well as the research progress in the catalytic reaction mechanism. Additionally, the paper discusses the advantages and disadvantages of each method and the importance of finding non-precious metals to reduce costs and improve efficiency. Overall, this paper provides a valuable reference for further research on ammonia decomposition for hydrogen production.

Effect of bandgap alignment on the photoreduction of CO2 into methane based on Cu2O-decorated CuO microspheres.

Semiconductors' band gap alignment is important for the photoreduction of CO2 to methane. In the paper, two kinds of Cu2O-decorated CuO microspheres composed with nanoflakes were prepared by using two different methods. Their electron behaviors were studied from the XPS spectra and photoelectrochemical measurements. Both samples are p-type CuO covered with an amount of Cu2O nanoparticles on their surface. Combined with their bandgaps and flat band potentials, CuO-Mic has a well-matched bandgap alignment between Cu2O and CuO, which is favorable for the separation of photogenerated electron-hole pairs. Those photogenerated carriers are beneficial for the conversion of CO2 to CH4, as an 8-electron process for the conversion of CO2 to CH4 will consume more photogenerated electrons for the chemical reactions than that of the 2-electron process for CO2 reduction to CO. Therefore, CuO-Mic has much better photocatalytic activity for CO2 reduction to CH4 with a CH4 yield ten times higher than that of CuO-Hyd under a visible light irradiation, the CO yields of the CO2 reduction are identical.

Safety of the 15-valent pneumococcal conjugate vaccine: A phase I clinical trial.

To evaluate the safety of the 15-valent pneumococcal conjugate vaccine (PCV15 (by LvZhu & Co. Ltd)) in healthy infants aged 2 months (minimum to 6 weeks) and 3 months old. This phase I clinical trial enrolled 80 subjects in Laishui County, Hebei Province, China. The total population was divided into 4 age groups on average: 20 adults (≥18 years) and 20 children (1-5 years) all received one vaccine dose; 20 infants (3 months) received the vaccine according to a 3-dose schedule at 0, 1, and 2 months. Twenty infants (2 months, minimum of 6 weeks old) received the vaccine according to a 3-dose schedule of 0, 2, and 4 months. The adverse events (AEs) until 30 days after each dose and serious adverse events (SAEs) until 6 months after the whole dose were reported. The solicited and unsolicited AE frequencies and laboratory indices were similar among the treatment groups. No vaccine-related SAEs were reported. Most vaccine-related adverse events consisting of systemic and local reactions were fever and pain. One hypersensitivity manifested as systemic urticaria that occurred on the third day after the second dose in the 2-month group. The 15-valent pneumococcal conjugate vaccine was generally well tolerated in infants.

Experimental and numerical investigations of desulfurization wastewater evaporation in a lab-scale flue gas duct: evaporation and HCl release characteristics.

The evaporation of desulfurization wastewater using flue gas has been considered as a promising technique. However, the release of HCl during the evaporation hinders the application of this technique. Herein, we investigated the evaporation in a laboratory-scale flue duct through experimental and numerical methods. The influences of operating parameters on characteristics of evaporation and HCl release were experimentally explored. The results show that when inlet gas temperature increases from 200°C to 350°C, gaseous HCl concentration significantly increases from 5.02 ppm to 70.96 ppm and HCl release ratio accordingly increases from 1.57% to 17.32%. However, when the wastewater only contains CaCl2, the HCl release is effectively inhibited. Subsequently, the established CFD model was validated with the experiments. It was found that relative deviations between predicted and experimental outlet gas temperatures mostly locate within the range of -10%∼0%. The negative deviations are attributed to the neglect of the crust formation. Numerical studies also reveal that droplet evaporation temperature is close to the wet-bulb temperature of the inlet gas ranging from 321.47 K to 337.85 K. Moreover, thermodynamic analysis shows that when the wastewater contains equimolar MgCl2 and CaCl2, MgCl2·6H2O first crystalizes at about d/d0 = 0.3. However, when the wastewater only contains CaCl2, CaCl2·2H2O begins to crystallize at about d/d0 = 0.25. Before crystallization, the equilibrium partial pressure of HCl is close to 0 Pa, indicating the HCl is mainly released at the particle drying stage. Further analysis suggests HCl should be mainly released from the decomposition of MgCl2·6H2O into MgOHCl.

Facile preparation of Zn x Cd1-x S/ZnS heterostructures with enhanced photocatalytic hydrogen evolution under visible light.

Hydrogen evolution from water using solar energy is regarded as a most promising process, thus, exploring efficient photocatalysts for water splitting is highly desirable. To avoid the rapid recombination of photogenerated electrons and holes in CdZnS semiconductors, Zn x Cd1-x S/ZnS composites were synthesized via a one-step hydrothermal method and then annealed at 400 °C for 60 min under argon flow. Zn x Cd1-x S/ZnS composites are composed of ZnS nanosheets decorated with Zn x Cd1-x S nanorods, and TEM and UV-vis absorption spectra confirm the formation of the heterostructure between Zn x Cd1-x S nanorods and ZnS nanosheets. Because of the well-matched band alignment, stronger optical absorption and larger carrier density, Zn0.2Cd0.8S/ZnS has the highest hydrogen production, with a photocatalytic hydrogen production rate up to 16.7 mmol g-1 h-1 under visible light irradiation. Moreover, the photocatalyst also exhibits high stability and good reusability for hydrogen production reaction. The facile and efficient approach for ZnS based heterostructures could be extended to other metal compound materials.

Safety and Immunogenicity of a Shigella Bivalent Conjugate Vaccine (ZF0901) in 3-Month- to 5-Year-Old Children in China.

No licensed Shigella vaccine is presently available globally. A double-blinded, randomized, placebo-controlled, age descending phase II clinical trial of a bivalent conjugate vaccine was studied in China. The vaccine ZF0901 consisted of O-specific polysaccharides purified and detoxified from lipopolysaccharide (LPS) of S. flexneri 2a and S. sonnei and covalently bonded to tetanus toxoid. A total of 224, 310, and 434 children, consented by parents or guardians, aged 3 to 6 and 6 to 12 months and 1 to 5 years old, respectively, were injected with half or full doses, with or without adjuvant or control Hib vaccine. There were no serious adverse reactions in all recipients of ZF0901 vaccine independent of age, dosage, number of injections, or the adjuvant status. Thirty days after the last injection, ZF0901 induced robust immune responses with significantly higher levels of type-specific serum antibodies (geometric mean concentrations (GMCs) of IgG anti-LPS) against both serotypes in all age groups compared with the pre-immune or the Hib control (p < 0.0001). Here, we demonstrated that ZF0901 bivalent Shigella conjugate vaccine is safe and immunogenic in infants and young children and is likely suitable for routine immunization.