Microfluidic mid-infrared spectroscopy via microresonator-based dual-comb source.

Over the past decade, microresonator-based soliton combs based on photonic integration have broadened the scope of applications in sensing, ranging, and imaging. The large comb line spacing on the order of hundreds of gigahertz allows for rapid acquisition of absorption spectra in the condensed matter phase without aliasing via a dual-comb interferometer. We present a proof-of-principle demonstration of high-throughput label-free microresonator-based dual-comb spectroscopy in a microfluidic chip that dynamically probes the linear absorption of liquid acetone in the mid-infrared wavelength regime. We measure the flow dynamics of an acetone droplet with a spectral acquisition rate of 25 kHz (40 µs per spectrum) covering a spectral range from 2900 to 2990 nm. Combining microfluidics and silicon-photonic technology would potentially enable a compact time-resolved spectroscopy system for a wide range of applications such as chemical synthesis, biological cell-sorting, and lab-on-a-chip.

Microresonator-based high-resolution gas spectroscopy.

We report the first demonstration of a microresonator-based tunable mode-locked frequency comb source. We achieve a mode-hop-free tuning range of 16 GHz by simultaneously tuning both the pump laser and the cavity resonance while keeping the system in a multi-soliton mode-locked state. The optical spectrum spans 2520-4125 cm-1 (2.425-3.970 µm) pumping at 3508 cm-1 (2.850 µm) in a silicon microresonator with a comb line spacing of 4.23 cm-1 (127 GHz). Our scanning technique can be used to increase the effective resolution of the microresonator-based comb spectroscopy. As a proof-of-principle demonstration, we record the absorption spectrum of the rovibrational transitions of the υ3 and υ2+(υ4+υ5)+0 bands of acetylene. We measure absorption features as narrow as 0.21 cm-1 (6.4 GHz) full width at half-maximum at a frequency sampling step of 80 MHz.

Competition between Raman and Kerr effects in microresonator comb generation.

We investigate the effects of Raman and Kerr gain in crystalline microresonators and determine the conditions required to generate mode-locked frequency combs. We show theoretically that a strong, narrowband Raman gain determines a maximum microresonator size allowable to achieve comb formation. We verify this condition experimentally in diamond and silicon microresonators and show that there exists a competition between Raman and Kerr effects that leads to the existence of two different comb states.

Coherent mid-infrared frequency combs in silicon-microresonators in the presence of Raman effects.

We demonstrate the first low-noise mid-IR frequency comb source using a silicon microresonator. Our observation of strong Raman scattering lines in the generated comb suggests that interplay between Raman and four-wave mixing plays a role in the generated low-noise state. In addition, we characterize, the intracavity comb generation dynamics using an integrated PIN diode, which takes advantage of the inherent three-photon absorption process in silicon.

Octave-spanning mid-infrared supercontinuum generation in silicon nanowaveguides.

We report, to the best of our knowledge, the first demonstration of octave-spanning supercontinuum generation (SCG) on a silicon chip, spanning from the telecommunications c-band near 1.5 µm to the mid-infrared region beyond 3.6 µm. The SCG presented here is characterized by soliton fission and dispersive radiation across two zero group-velocity dispersion wavelengths. In addition, we numerically investigate the role of multiphoton absorption and free carriers, confirming that these nonlinear loss mechanisms are not detrimental to SCG in this regime.

Silicon-chip-based mid-infrared dual-comb spectroscopy.

The development of a spectroscopy device on a chip that could realize real-time fingerprinting with label-free and high-throughput detection of trace molecules represents one of the big challenges in sensing. Dual-comb spectroscopy (DCS) in the mid-infrared is a powerful technique offering high acquisition rates and signal-to-noise ratios through use of only a single detector with no moving parts. Here, we present a nanophotonic silicon-on-insulator platform designed for mid-infrared (mid-IR) DCS. A single continuous-wave low-power pump source generates two mutually coherent mode-locked frequency combs spanning from 2.6 to 4.1 µm in two silicon microresonators. A proof-of-principle experiment of vibrational absorption DCS in the liquid phase is achieved acquiring spectra of acetone spanning from 2900 to 3100 nm at 127-GHz (4.2-cm-1) resolution. These results represent a significant step towards a broadband, mid-IR spectroscopy instrument on a chip for liquid/condensed matter phase studies.

Breather soliton dynamics in microresonators.

The generation of temporal cavity solitons in microresonators results in coherent low-noise optical frequency combs that are critical for applications in spectroscopy, astronomy, navigation or telecommunications. Breather solitons also form an important part of many different classes of nonlinear wave systems, manifesting themselves as a localized temporal structure that exhibits oscillatory behaviour. To date, the dynamics of breather solitons in microresonators remains largely unexplored, and its experimental characterization is challenging. Here we demonstrate the excitation of breather solitons in two different microresonator platforms based on silicon nitride and on silicon. We investigate the dependence of the breathing frequency on pump detuning and observe the transition from period-1 to period-2 oscillation. Our study constitutes a significant contribution to understanding the soliton dynamics within the larger context of nonlinear science.

Silicon-chip mid-infrared frequency comb generation.

Optical frequency combs are a revolutionary light source for high-precision spectroscopy because of their narrow linewidths and precise frequency spacing. Generation of such combs in the mid-infrared spectral region (2-20 µm) is important for molecular gas detection owing to the presence of a large number of absorption lines in this wavelength regime. Microresonator-based frequency comb sources can provide a compact and robust platform for comb generation that can operate with relatively low optical powers. However, material and dispersion engineering limitations have prevented the realization of an on-chip integrated mid-infrared microresonator comb source. Here we demonstrate a complementary metal-oxide-semiconductor compatible platform for on-chip comb generation using silicon microresonators, and realize a broadband frequency comb spanning from 2.1 to 3.5 µm. This platform is compact and robust and offers the potential to be versatile for use outside the laboratory environment for applications such as real-time monitoring of atmospheric gas conditions.