Optimal parameter selection for the THz-CCS system based on an incoherent light source.

Terahertz cross correlation spectroscopy (THz-CCS) systems using broadband incoherent light as the pumping source have received increasing attention from researchers in recent years. However, a comprehensive and in-depth understanding of THz-CCS is still needed to obtain a detailed optimization scheme. Here we systematically investigate the influences of the detection parameters, light propagation process, and pump source on the CCS signals. The impacts of the filter slopes and time constants in lock-in detection are revealed for optimizing the signal-to-noise ratio and bandwidth of the THz signal. By varying the optical fiber length and dispersion coefficient, the dispersion insensitivity of THz-CCS was experimentally demonstrated. The comparison of different pump sources (SLD and ASE) shows that the over-wide and non-flat pump spectrum may attenuate the CCS signal because of the energy waste brought by the photomixing process under the limited bandwidth of the photomixer. Our research may lead to a deeper understanding and further optimization of the THz-CCS system, which will promote the development and widespread application of what is to the best of our knowledge a new technique.

Terahertz fingerprint reveals the effect of alcohols on sodium ions hydration shell.

Ion hydration plays a crucial role in numerous fundamental processes. Various spectroscopic methods are employed to investigate the slowing down of hydration bond dynamics in the proximity of both anions and cations. To date, most of these studies have primarily focused on the properties of binary systems. However, in comparison to ion-water binary systems, ternary systems that involve ions, water, and organic matter are more prevalent in nature and provide more realistic insights into biological processes. This study focuses on ion hydration in water and alcohol mixture using terahertz spectroscopy and x-ray diffraction (XRD). The results reveal a distinct behavior depending on the type of alcohol used. Specifically, the presence of both methanol and ethanol results in the disappearance of absorption peaks associated with NaCl hydrate at low temperatures. In contrast, tert-butanol does not exhibit such an effect, and isopropanol demonstrates a more complex response. By combining these terahertz spectroscopic findings with low-temperature XRD data, we gain insights into the formation, or lack thereof, of NaCl · 2H2O hydrate crystals. Crucially, our observations suggest a dominant correlation between the polarity of the alcohol molecules and its impact on the Na+ hydration. Strongly polar alcohols preferentially solvating the Na+ ion lead to the failure of hydrate formation, while weakly polar alcohols do not have this effect.

High sensitivity gas sensor based on surface exciton polariton enhanced photonic spin Hall effect.

In this paper, the sub-wavelength transverse displacement of photonic spin Hall effect (PSHE) is significantly enhanced by the surface exciton polariton (SEP) for application in gas sensing. The transverse displacement of 14.4 times the wavelength of incident light is achieved with the SEP enhanced PSHE, which is about 3 times that of surface plasmon resonance enhanced PSHE. A gas sensor based on SEP enhanced PSHE is proposed for the detection of SO2, and the refractive index sensitivity of 6320.4 µm/RIU is obtained in the refractive index range from 1.00027281 to 1.00095981. These results undoubtedly demonstrate SEP to be a promising mechanism for PSHE enhancement, and open up new opportunities for highly sensitive gas sensing, biosensing, and chemical sensing.

Ultracompact terahertz plasmonic mode division multiplexer.

In this Letter, an ultracompact terahertz (THz) mode division multiplexer based on THz spoof surface plasmon polaritons (SPPs) is proposed. Compared with traditional optical multiplexing devices, the proposed mode multiplexer can be designed with a reduced footprint by exploiting more degrees of freedom in the parameters of the unit cell, namely a rectangular metallic pillar. The ultracompact mode division multiplexer can simultaneously support the propagation of four mode channels: the TM0, TM1, TM2, and TM3 modes. Then, we numerically evaluate the performance of a cascaded plasmonic mode division circuit composed of a mode multiplexer and demultiplexer. The cross talk and excess loss of the whole circuit are lower than -15 dB and 3.7 dB, respectively, for all four mode channels at a center frequency of 0.65 THz. The footprint of the whole device is about 27 × 2.3 mm and the length of each coupling region is about 2.7 mm. For the first time, to the best of our knowledge, a mode division multiplexer based on THz spoof SPPs is reported, which will form core devices for future THz on-chip multimode communication systems.

Magnetic moiré effects and two types of topological transition in a twisted-bilayer hyperbolic metasurface with double-split ring arrays.

Moiré configurations have recently attracted much attention due to their ability to enhance photonic responses and manipulate surface waves in the subwavelength ranges. However, previous studies have usually been focused on natural hyperbolic materials with limitations on patterning procedures, controlling rotation angles, and merely manipulating electric surface plasmons. Here, we theoretically and numerically investigate a novel magnetic moiré hyperbolic metasurface in the terahertz region, which enables two types of topological transition and a plethora of unusual magnetic moiré effects (magnetic surface wave manipulation, dispersion engineering, magic angles, spacer-dependent topological transition, and local field enhancement). This work extends twistronics and moiré physics to the terahertz region and magnetic polaritons, with potential applications in quantum physics, energy transfer, and planarized magnetic plasmonic devices.

Phase mismatch induced suppression of eigenmode resonance in terahertz metasurfaces.

In this paper, we observe the distinguishable modulation of the different eigenmodes by lattice mode in terahertz U-shaped metasurfaces, and a remarkable lattice induced suppression of the high order eigenmode resonance is demonstrated. With the quantitative analysis of Q factor and loss of the resonances, we clarify that the peculiar phenomenon of suppression is originated from the phase mismatch of the metasurfaces via introducing the phase difference between the neighboring structures. These results provide new insights into the phase mismatch mediated transmission amplitude of eigenmode resonance in metasurfaces and open a new path to developing terahertz multifunctional devices.

Terahertz metasurface with multiple BICs/QBICs based on a split ring resonator.

Bound state in the continuum (BIC) refers to the trapped state in the radiation continuum of a system. In the terahertz band, BIC provides a unique and feasible method to design devices with ultra-high quality factor (Q factor) and to achieve intense terahertz-matter interaction, which is of great value to terahertz science and technology. Here, multiple BICs protected by the resonance symmetry in the terahertz metasurface consisting of metallic split ring resonators (SRR) is demonstrated. The evolution from the BIC to the quasi-BIC (QBIC) is induced by changing the gap width of the SRRs. The proposed BICs are experimentally demonstrated and analyzed by the coupled mode theory along with the numerical simulation. It is found that the leakage behavior of these QBICs is strongly affected by the intrinsic Ohmic loss in the SRRs while it is quite robust to the tilted incidence.

Anisotropic coding metasurfaces and their active manipulation based on vanadium dioxide for multifunctional applications in the terahertz region.

Various kinds of metasurfaces have been proposed because they can be tailored to achieve the desired modulations on electromagnetic wave that do not occur in nature. Compared to conventional metamaterials, coding metasurfaces integrated with information science theory possess numerous distinctive advantages - simple design, time-saving and compatibility with digital devices. Here we propose terahertz multifunctional anisotropic reflective metasurfaces with a metal-insulator-metal cavity structure whose top constructional layer consists of a pair of gold arc-rings and a gold cut-wire located between them. Two different functions of narrow-band absorption and broadband polarization conversion are realized based on different coding matrices using the binary codes '0' and '1'. Furthermore, we integrate a specific coding metasurface with vanadium dioxide (VO2) to realize a temperature-controlled active metasurface. Through the temperature change, dynamic functionalities switching between a narrow-band polarization converter with a polarization conversion ratio over 94% and an efficient low-pass filter are achieved under the phase transition of VO2, and the active metasurface is polarization independent. The proposed coding metasurfaces are verified numerically and experimentally, and have promising applications in terahertz modulation and functional devices.

Monitoring MgCl2 hydrate formation from aqueous solutions using terahertz time-domain spectroscopy.

The interaction of MgCl2 with H2O is heavily involved in biological and chemical processes. In this work, freezing-induced hydrate formation from MgCl2 aqueous solution was monitored using terahertz time-domain spectroscopy. At low temperatures, two phase transitions from brine to hydrate formation could be clearly observed, and the formation of hydrate was accompanied by the emergence of new THz fingerprint peaks at 1.02, 1.56, and 1.84 THz, respectively. Integrating XRD and quantum chemical calculations, we attributed the absorption peaks to the vibrational modes of the formed MgCl2·12H2O. This demonstrates the potential of THz spectroscopy for application in the detection of biological processes in low-temperature environments, such as cell freezing.

Water dynamics in the hydration shell of hyper-branched poly-ethylenimine.

We performed THz and GHz dielectric relaxation spectroscopy to investigate the reorientational dynamics of water molecules in the hydration shell of amphiphilic hyper-branched poly-ethylenimine (HPEI). Four Debye equations were employed to describe four types of water in the hydration shell, including bulk-like water, under-coordinated water, slow water (water molecules hydrating the hydrophobic groups and water molecules accepting hydrogen bonds from the NH2 groups) and super slow water (water molecules donating hydrogen bonds to and accepting hydrogen bonds from NH groups). The time scales of undercoordinated and bulk-like water show a slight decline from 0.4 to 0.1 ps and from 8 to 2 ps, respectively. Because of hydrophilic amino groups, HPEI molecules exhibit a strong retardation effect, where the time scales of slow and super slow water increase with concentration from 17 to 39.9 ps and from 88 to 225 ps, respectively.

Terahertz spoof surface plasmonic demultiplexer based on band-stop waveguide units.

Demultiplexers play an important role in wavelength division multiplexing optical transmission systems and constitute an essential component of future terahertz integrated circuits. In this work, we propose a terahertz spoof surface plasmonic demultiplexer, which is capable of distinguishing between three different frequencies by exploiting the band-stop effect of the waveguide units. The waveguide units are composed of metallic pillars of different sizes, where the transmission of spoof surface plasmons in the terahertz range is strongly influenced by the pillar size. The frequency-splitting feature can be achieved by selecting waveguide units with proper parameters that allow the passbands of the waveguides to be completely non-overlapping. As the effective working section, the length of the band-stop units is 1 mm, and extinction ratios of 21.5 dB, 18.0 dB, and 23.9 dB are obtained at 0.578 THz, 0.632 THz, and 0.683 THz, respectively. The proposed band-stop unit and its tunable characteristics have important applications for further development of terahertz integrated communication systems and terahertz on-chip plasmonic circuity.

Design and analysis of terahertz filters based on multilayer metamaterials.

We numerically and experimentally demonstrate a series of multilayer metamaterial filters in the terahertz region. The designed structure consists of multiple metal-polyimide composite layers and cyclic olefin copolymer layers. The transmission spectra of the filters are characterized by terahertz time-domain spectroscopy, and the measured results agree well with simulations. In addition, the mechanism of the multilayer structure is theoretically studied by a thin film multibeam interference model. The proposed filters exhibit high efficiency at passband and can be broadly utilized as compact devices in practical applications at terahertz frequencies.

Integrated Terahertz Generator-Manipulators Using Epsilon-near-Zero-Hybrid Nonlinear Metasurfaces.

In terahertz (THz) technologies, generation and manipulation of THz waves are two key processes usually implemented by different device modules. Integrating THz generation and manipulation into a single compact device will advance the applications of THz technologies in various fields. Here, we demonstrate a hybrid nonlinear plasmonic metasurface incorporating an epsilon-near-zero (ENZ) indium tin oxide (ITO) layer to seamlessly combine efficient generation and manipulation of THz waves across a wide frequency band. The coupling between the plasmonic resonance of the metasurface and the ENZ mode of the ITO thin film enhances the THz conversion efficiency by more than 4 orders of magnitude. Meanwhile, such a hybrid device is capable of shaping the polarization and wavefront of the emitted THz beam via the engineered nonlinear Pancharatnam-Berry (PB) phases of the plasmonic meta-atoms. The presented hybrid nonlinear metasurface opens a new avenue toward miniaturized integrated THz devices and systems with advanced functionalities.

Application of terahertz spectroscopy on monitoring crystallization and isomerization of azobenzene.

Terahertz spectroscopy provides a powerful and informative link between infrared spectroscopy and microwave spectroscopy, and is now beginning to make its transition from initial development to broader use by chemists, materials scientists and biologists. In this study, utilizing terahertz spectroscopy we monitored the crystallization and isomerization of azobenzene. In flash-frozen trans-azobenzene solutions, the processes of crystallization and phase transition were observed. A new phase has been experimentally confirmed to exist stably at low temperatures. The results on gradual-frozen experiment indicate that the formation of the observed new phase is determined by the cooling rate. Besides, based on the distinctive spectral features of the isomers, the thermal- and photo-induced isomerization processes of azobenzene were investigated. This work presents that the terahertz spectroscopy has a great potential to study the phase transitions and crystallization of liquid samples under different freezing conditions.

Temperature-controlled terahertz polarization conversion bandwidth.

Active control of metasurfaces has attracted widespread attention because of the adjustable electromagnetic properties obtained. Here we designed and experimentally studied a dynamically controllable polarization converter in the terahertz band. By designing the structural parameters and utilizing the insulator-to-metal phase transition of vanadium dioxide and principle of current resonance, dynamic tunability of the polarization conversion function from dual-broadband (0.45∼0.77 THz and 0.97∼1.2 THz) to ultra-broadband (0.38∼1.20 THz) can be realized with a high polarization conversion ratio. The scheme proposed here can find potential applications in integrated terahertz systems, sensing, imaging and communications areas.

Topological edge state bandwidth tuned by multiple parameters in two-dimensional terahertz photonic crystals with metallic cross structures.

Originating from the study of topological photonic crystals (TPCs), analogues of the quantum spin Hall effect have been used as a potential way to control the propagation of electromagnetic waves. Due to the topological robustness of the spin TPCs, the edge states along the interface between the trivial and topological areas are topologically protected and not reflected from structural defects and disorders. Here, on the basis of the time-spatial reversal symmetry and topological defect theory, we demonstrate broadening of the edge state bandwidth in spin TPCs made of regular metallic cross structures by simultaneously deforming the hexagonal honeycomb lattice and adjusting the rotation angle. Due to the simultaneous tuning of the two parameters, the designed spin TPCs possess more flexibility. Topologically protected one-way propagating edge states are observed in the terahertz regime, where electromagnetic waves propagate along sharp corners without backscattering. Our findings offer the potential application for topological devices in terahertz technology and are beneficial for the development of 6G mobile communications.

Exceptional point in a metal-graphene hybrid metasurface with tunable asymmetric loss.

Observation of exceptional points (EPs) in non-Hermitian parity-time (PT) symmetric systems has led to various nontrivial physics and exotic phenomena. Here, a metal-graphene hybrid non-Hermitian metasurface is proposed in the terahertz regime, whose unit cell is composed of two orthogonally oriented split-ring resonators (SRRs) with identical dimensions but only one SRR containing a graphene patch at the gap. An EP in polarization space is theoretically observed at a certain Fermi level of the graphene patch, where the induced asymmetric loss and the coupling strength between the two SRRs match a certain relation predicted by a coupled mode theory. The numerical fittings using the coupled mode theory agree well with the simulations. Besides, an abrupt phase flip around the EP frequency is observed in the transmission in circular polarization basis, which can be very promising in ultra-sensitive sensing applications.

All-dielectric nanograting for increasing terahertz radiation power of photoconductive antennas.

Photoconductive antenna (PCA) is a widely used terahertz (THz) radiation source, but its low radiated power limits the signal-to-noise ratio and bandwidth in THz imaging and spectroscopy applications. Here, we achieved significant PCA power enhancement through etching nanograting directly on the surface of the PCA substrate. The integrated nanograting not only maximizes the generation of photocarriers, but also benefits the bias electric field loaded on the photocarriers. Comparing with the conventional PCA, our PCA realizes a frequency independent THz power enhancement of 3.92 times in the range of 0.05-1.6 THz. Our results reported here not only provide a new method for increasing the THz power of PCAs, but also reveal another way that artificial nanostructures affect the PCAs, which paves the way for the subsequent researches of next-generation PCAs.

Asymmetric transmission of linearly polarized waves based on Mie resonance in all-dielectric terahertz metamaterials.

Interest in asymmetric transmission (AT) at terahertz frequencies has increased dramatically in recent years. We present an all-silicon metamaterial to achieve the AT effect for linearly polarized electromagnetic waves in the terahertz regime. The metamaterial is constructed by rectangular silicon pillars and a thick silicon substrate. The magnetic Mie resonance excited by the incident polarized terahertz wave contributes to the AT effect, which is verified by the field distributions. In addition, the rotation angle and dimensions of the silicon pillars are shown to have a great influence on the AT efficiency. The proposed metamaterial with straightforward design has promising applications in polarization control scenarios.

Curved terahertz surface plasmonic waveguide devices.

Strongly confined surface waves can be achieved on periodically structured metal surfaces and are known as spoof surface plasmon polaritons (SPPs). In this work, several terahertz SPP devices based on curved waveguides are demonstrated. The transmittance and bending loss of 90-degree curved spoof SPP waveguides with a radius of curvature ranging from 200 to 2300 µm are investigated to identify the regime for high transmission. A commutator is designed and experimentally demonstrated. Furthermore, coupling equations are derived and verified for efficient coupling between bend-straight waveguides and between bend-bend waveguides. The results will be of great value for future integrated terahertz plasmonic systems.