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Proc Natl Acad Sci U S A ; 111(11): 4049-54, 2014 Mar 18.
Artigo em Inglês | MEDLINE | ID: mdl-24591620

RESUMO

P-glycoprotein is an ATP-binding cassette multidrug transporter that actively transports chemically diverse substrates across the lipid bilayer. The precise molecular mechanism underlying transport is not fully understood. Here, we present crystal structures of a eukaryotic P-glycoprotein homolog, CmABCB1 from Cyanidioschyzon merolae, in two forms: unbound at 2.6-Å resolution and bound to a unique allosteric inhibitor at 2.4-Å resolution. The inhibitor clamps the transmembrane helices from the outside, fixing the CmABCB1 structure in an inward-open conformation similar to the unbound structure, confirming that an outward-opening motion is required for ATP hydrolysis cycle. These structures, along with site-directed mutagenesis and transporter activity measurements, reveal the detailed architecture of the transporter, including a gate that opens to extracellular side and two gates that open to intramembranous region and the cytosolic side. We propose that the motion of the nucleotide-binding domain drives those gating apparatuses via two short intracellular helices, IH1 and IH2, and two transmembrane helices, TM2 and TM5.


Assuntos
Membro 1 da Subfamília B de Cassetes de Ligação de ATP/química , Descoberta de Drogas/métodos , Ativação do Canal Iônico/fisiologia , Modelos Moleculares , Neoplasias/tratamento farmacológico , Conformação Proteica , Rodófitas/química , Trifosfato de Adenosina/metabolismo , Cristalografia , Ativação do Canal Iônico/genética , Pichia , Saccharomyces cerevisiae , Difração de Raios X
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