Europe-Wide Atmospheric Radionuclide Dispersion by Unprecedented Wildfires in the Chernobyl Exclusion Zone, April 2020.

From early April 2020, wildfires raged in the highly contaminated areas around the Chernobyl nuclear power plant (CNPP), Ukraine. For about 4 weeks, the fires spread around and into the Chernobyl exclusion zone (CEZ) and came within a few kilometers of both the CNPP and radioactive waste storage facilities. Wildfires occurred on several occasions throughout the month of April. They were extinguished, but weather conditions and the spread of fires by airborne embers and smoldering fires led to new fires starting at different locations of the CEZ. The forest fires were only completely under control at the beginning of May, thanks to the tireless and incessant work of the firefighters and a period of sustained precipitation. In total, 0.7-1.2 TBq 137Cs were released into the atmosphere. Smoke plumes partly spread south and west and contributed to the detection of airborne 137Cs over the Ukrainian territory and as far away as Western Europe. The increase in airborne 137Cs ranged from several hundred µBq·m-3 in northern Ukraine to trace levels of a few µBq·m-3 or even within the usual background level in other European countries. Dispersion modeling determined the plume arrival time and was helpful in the assessment of the possible increase in airborne 137Cs concentrations in Europe. Detections of airborne 90Sr (emission estimate 345-612 GBq) and Pu (up to 75 GBq, mostly 241Pu) were reported from the CEZ. Americium-241 represented only 1.4% of the total source term corresponding to the studied anthropogenic radionuclides but would have contributed up to 80% of the inhalation dose.

Airborne 210Pb, Si, Zn and Pb as tracers for atmospheric pollution in Helsinki metropolitan area.

This study analyzed 16070 daily and 608 weekly air filter samples from the Helsinki metropolitan area collected between 1962 and 2005. The aim was to use the Potential Source Contribution Function (PSCF) to determine potential sources of silicon (Si), zinc (Zn), lead (Pb), and radioactive isotope 210Pb. The main sources for Si and Pb were industrial activities, particularly mining, metal industry, and traffic. Common source areas for Zn and 210Pb were identified in the eastern and southeastern parts of the measuring site.

The origin of Uranium in groundwater of the eastern Halkidiki region, northern Greece.

Uranium (U) pollution in groundwater has become a serious problem worldwide. Even in low concentrations, U has both radiological and toxicological impacts on human health. In this study an integrated hydrogeological approach was applied to conceptualize an aquifer system, and determine the origin of U detected in the aquifer of the eastern Halkidiki region in northern Greece. Data from measurements of groundwater level and hydrochemical and stable isotope analyses of groundwater samples were applied to perform geochemical modeling and multivariate statistical analysis. The modeling and statistical analysis identified three hydrogeochemical groups within the studied hydro-system, and U(VI) as the dominant U species. The first group is linked to the deeper aquifer which is characterized by water-rock interactions with weathering products of granodiorite. In this group the dominant U species is uranyl phosphate and U concentration is 3.7 µg/L. The upper aquifer corresponds to the second hydrogeochemical group where U concentrations are mainly influenced by high concentrations of nitrogen species (NO3- and NO2-). Factor analysis further discriminated the upper aquifer into a saline coastal zone and an inland zone impacted by agricultural activities. The third hydrogeochemical group presents the highest concentration of U (up to 15 µg/L) in groundwater and corresponds to the internal aquifer system. The U within this system is triggered by the presence of Mn2+, while the long residence time of the groundwater contributes synergistically to the hydrogeochemical process. Manganese triggers U oxidation in parallel with Fe2+ precipitation that acts as a regulator of U concentration. Groundwater depletion of the upper aquifers promotes the up-coning of geothermal fluids from fault zones leading to increased concentrations of U in the mid-depth aquifers.

Radon and its progenies variation in the urban polluted atmosphere of the Mediterranean city of Thessaloniki, Greece.

Radon and Rn progenies' concentrations were determined in the urban polluted atmosphere of Thessaloniki's city center using two experimental procedures: (i) filter with 0.8-µm porosity measured using α-counting technique determining the radon equilibrium equivalent concentration (CEER), which varies from 2.6 to 8.9 Bq m-3, and (ii) filter with 0.3-µm porosity measured in the laboratory using γ-spectrometry determining 214Pb activity concentration 1.3-7.5 Bq m-3 and 214Bi activity 3.1-11.5 Bq m-3. Strong daily correlation with the relative humidity is presented, in association to an inverse correlation with the temperature gradient. Radon and its daughter's concentration correlate well smoke particles' content because radon is trapped inside them due to their high effective porosity, and so the Rn daughter collection in the filter increases. Gas pollutants have similar daily distribution with the radon activity, while SO2 levels are correlated the best with 214Pb and 214Bi concentrations, as Pb is more chemically associated to sulfuric complex ions than nitric formation in presence of vapors. The lower 214Pb/ 214Bi activity ratio appeared during the highest temperature gradient and amount of vapors, smoke, and gases giving rise to high formation of ultrafine aerosol particles. The ultrafine aerosol creation boosts 214Pb recoil effect taken place during 218Po α-decay, so 214Pb nuclei become free starting the clustering process yet again having ingrowth coefficient ~ 0.1 nm2 s-1 regarding accumulation mode aerosols.

Determination of low 137Cs concentration in the atmosphere due to Chernobyl contaminated forest-wood burning.

The determination procedure of low 137Cs concentrations in air using γ-spectrometry is essential wherever the net counts are smaller than the background of the spectrum. Such measurements have performed in April 2020 during the Chernobyl wildfires period. A significant event recorded in Thessaloniki's atmosphere during April 12, 2020, with 25.7 ± 0.7 µBq m-3 of 137Cs, was measured. Besides, a minor incident with a lower 137Cs concentration of 9.6 ± 0.8 µBq m-3 has occurred on April 21, 2020. The above results resemble to a previous one noticed during winter 2013, when signals up to 12.1 ± 0.8 µBq m-3 of 137Cs detected in the atmosphere, due to extensive use of 137Cs contaminated wood for residential heating. The results obtained demonstrate that no radiation hazard rose for the general public due to inhalation of the 137Cs in the air of Thessaloniki, Greece. Moreover, the residence time of the aerosol-bound 137Cs has estimated. The data presented are useful for basic simulation-inputs and comparison with global atmospheric models, which also discussed after comparison with the back trajectories predicted by the NOAA-HYSPLIT model.

Origin, implications and management strategies for nitrate pollution in surface and ground waters of Anthemountas basin based on a δ15N-NO3- and δ18O-NO3- isotope approach.

Nitrate pollution of surface and groundwater resources is a major worldwide environmental problem. In this study nitrogen isotopes of water, soil, fertilizer and manure were analyzed to determine the pollution sources of nitrate in the groundwater and surface waters of Anthemountas basin. The SIAR model and multivariate statistical analysis were used to determine and quantify the contribution of different NO3̄ sources in groundwater and surface water. Additionally, a detailed literature overview was carried out to identify the origin of nitrate pollution in surface and ground waters based on ΝΟ3- isotopes. The Piper diagram identified the dominant water types as Mg-Ca-HCO3 and Ca-Mg-HCO3. Nitrate concentrations reached 162.0 mg/L in groundwater and 39.0 mg/L in surface waters. The main source of nitrate in groundwater was mainly nitrified ammonium-based synthetic urea and less nitrate-based synthetic fertilizers. The correlation of SIAR results with other trace elements revealed a negative correlation between hexavalent chromium and a) nitrate-based synthetic fertilizers, and b) nitrification of urea synthetic fertilizers. However, a positive correlation was observed between hexavalent chromium and anthropogenic organic matter. The literature overview provided the basis to design a novel management protocol for nitrate pollution that includes three steps: a) fundamental research, b) management tools, c) monitoring and preservation actions. However, an integrated management protocol for nitrate pollution requires a deeper understanding of the hydro-system and the full participation of local farmers and stakeholders.

Temporal investigation of radionuclides and heavy metals in a coastal mining area at Ierissos Gulf, Greece.

Vertical variations of radionuclides, trace metals, and major elements were determined in two sediment cores, which were collected in the marine environment of Ierissos Gulf near Stratoni's mining area. The enrichment factors (EFs) were also estimated and provided moderately severe to extremely severe enrichment for most trace elements and Mn, describing the anthropogenic influence in the gulf during the previous century. According to the applied dating models based on 210Pb and 137Cs, the effect in the marine sediment due to the exploitation of pyrite for the production of sulfuric acid during 1912-1920 was observed. Additionally, the decrease of mining activity during 1935-1945 due to the Second World War and the type of ore exploitation, the alteration of the exploited ores, and the construction and operation of Olympiada's floatation plant during 1950-1970 were identified. The end of tailing discharging into the marine environment during 1980-2010 was also noted.

Aerosol particle size distribution of atmospheric lead-210 in northern Finland.

Size-segregated aerosol samples were collected with a high-volume 6-stage cascade impactor at Sodankylä, Finland, 100 km north of the Arctic Circle. The 210Pb content of the samples were determined with radiochemical separation of in-grown 210Po followed by alpha spectrometry. Most of the 210Pb activity was incorporated in accumulation mode aerosol particles. The activity median aerodynamic diameter (AMAD) ranged from 0.53 µm to 0.98 µm 38-61 per cent of 210Pb activity was found to be associated with aerosol particles smaller than 0.69 µm. A slight downward tendency of 210Pb activity median aerodynamic diameter was observed as a function of increasing 210Pb activity concentration. This is related to the continental origin of airborne 210Pb on one hand, and various aerosol particle growth processes on the other hand. Also a clear tendency towards a higher 7Be/210Pb activity ratio as a function of increasing aerosol particle diameter was observed. This, in turn, reflects the different origin of 210Pb, exhalation of 222Rn from the soil into the air, and 7Be, formation by cosmic radiation in the upper troposphere and the stratosphere.

The uranium isotopes in the characterisation of groundwater in the Thermi-Vasilika region, northern Greece.

The activity concentrations of (238)U and (234)U have been determined in groundwater samples in the Thermi-Vasilika region, northern Greece. The analysis was performed by alpha spectrometry after pre-concentration and separation of uranium by cation exchange and finally its electrodeposition on stainless steel discs. The obtained isotopic ratio (234)U/(238)U varies between 0.95 and 3.50 and is correlated with the different aquifer types and water flow paths in the study area. Lower values (up to 1.10) are located in the shallow porous aquifer indicating younger waters. Moderate values of the activity ratio characterise the deeper porous aquifer as well as the fissured rock aquifer (1.5-2.05). The geothermal spring illustrates the highest activity ratio (3.5) due to older water.

7Be aerosols and their deposition on the sea: a possible method to estimate trace metals deposition on the sea.

The activity size distributions of (7)Be aerosols in different size fractions (<0.39 µm, 0.39-0.69 µm, 0.69-1.3 µm, 1.3-2.1 µm, 2.1-4.2 µm, 4.2-10.2 µm and >10.2 µm) were determined at the city of Thessaloniki, Greece, Eastern Mediterranean. The Activity Median Aerodynamic Diameter (AMAD) values ranged from 0.58 to 1.22 µm while more of the 80% of the (7)Be activity was associated with particles smaller than 1.3 µm. Sea salt aerosol particles were defined in a small size range, lower than 0.39 µm. Field measurements at a coastal location allow the estimation of (7)Be deposition on the sea. Since the (7)Be aerosol particles were mainly below 1 µm, scavenging by precipitation was the main process depositing (7)Be on the sea. Acting as an excellent tracer, (7)Be could be used for determination of the deposition of the trace metals on the sea, since they are expected to be deposited at similar rate by wet and dry deposition processes as the (7)Be.

Fukushima fallout at Milano, Italy.

The radionuclides (131)I, (137)Cs and (134)Cs were observed in the Milano region (45°) of Italy early after the nuclear accident in Fukushima, Japan. Increased atmospheric radioactivity was observed on an air filter taken on 30 March 2011, while the maximum activity of 467 µBq m(-3) for (131)I was recorded at April 3-4, 2011. The first evidence of Fukushima fallout was confirmed with (131)I and (137)Cs measured in precipitation at two sampling sites at Milano on 28 March, 2011, with the concentrations of (131)I and (137)Cs in the rainwater equal to 0.89 Bq L(-1) and 0.12 Bq L(-1), respectively. A sample of dry deposition that was collected 9 days after the first rainfall event of 27-28 March, 2011 showed that the dry deposition was more effective in the case of (137)Cs than it was for (131)I, probably because iodine was mainly in gaseous form whereas caesium was rapidly bound to aerosols and thus highly subject to dry deposition. The relatively high observed values of (137)Cs in grass, soil and fresh goat and cow milk samples were probably from Chernobyl fallout and global fallout from past nuclear tests rather than from the Fukushima accident. Finally, a dose assessment for the region of investigation showed clearly that the detected activities in all environmental samples were very far below levels of concern.