Molecular markers of biomass burning in arctic aerosols.

Biomass burning is one of the most important sources of organic matter in the atmosphere as it affects the absorption and scattering of solar radiation, creates cloud condensation nuclei and possibly influences ice and snow albedo. Here we created and validated an analytical method using HPLC/(-)-ESI-MS/MS to determine phenolic compounds (PCLCs): vanillic acid, isovanillic acid, homovanillic acid, syringic acid, syringaldehyde, ferulic acid, p-coumaric acid, and coniferyl aldehyde at trace levels in particulate matter. We analyzed eighteen high-volume air samples from Ny Ålesund (Svalbard) collected during the boreal spring and summer of 2010. Biomass burning molecules including PCLCs (<0.49 µm, mean atmospheric concentration 6 pg m(-3)), levoglucosan (0.004 to 0.682 ng m(-3)) and acrylamide (32 fg m(-3) to 166 fg m(-3)) were present in the sampled aerosols. Levoglucosan concentrations, an unambiguous cellulose combustion tracer, derived from 2010 Russian fires. PCLCs levels in the Ny Alesund atmosphere in different size fractions reflected both long-range transport linked to biomass burning and a terrigenous local source.

Speciation analysis of iodine and bromine at picogram-per-gram levels in polar ice.

Iodine and bromine species participate in key atmospheric reactions including the formation of cloud condensation nuclei and ozone depletion. We present a novel method coupling a high-performance liquid chromatography with ion chromatography and inductively coupled plasma mass spectrometry, which allows the determination of iodine (I) and bromine (Br) species (IO(3)(-), I(-), Br(-), BrO(3)(-) ) at the picogram-per-gram levels presents in Antarctic ice. Chromatographic separation was achieved using an IONPAC® AS16 Analytical Column with NaOH as eluent. Detection limits for I and Br species were 5 to 9 pg g(-1) with an uncertainty of less than 2.5% for all considered species. Inorganic iodine and bromine species have been determined in Antarctic ice core samples, with concentrations close to the detection limits for iodine species, and approximately 150 pg g(-1) for Br(-). Although iodate (IO(3)(-)) is the most abundant iodine species in the atmosphere, only the much rarer iodide (I(-)) species was present in Antarctic Holocene ice. Bromine was found to be present in Antarctic ice as Br(-).

The Great Acceleration of fragrances and PAHs archived in an ice core from Elbrus, Caucasus.

The Great Acceleration of the anthropogenic impact on the Earth system is marked by the ubiquitous distribution of anthropogenic materials throughout the global environment, including technofossils, radionuclides and the exponential increases of methane and carbon dioxide concentrations. However, personal care products as direct tracers of human domestic habits are often overlooked. Here, we present the first research combining fragrances, as novel personal care products, and polycyclic aromatic hydrocarbons (PAHs) as combustion and industrial markers, across the onset of the Great Acceleration in the Elbrus, Caucasus, ice core. This archive extends from the 1930s to 2005, spanning the profound changes in the relationship between humans and the environment during the twentieth century. Concentrations of both fragrances and PAHs rose throughout the considered period, reflecting the development of the Anthropocene. However, within this rising trend, remarkable decreases of the tracers track the major socioeconomic crises that occurred in Eastern Europe during the second half of the twentieth century.

Dissolved organic matter in the deep TALDICE ice core: A nano-UPLC-nano-ESI-HRMS method.

Trace organic compounds in deep ice cores supply important paleoclimatic information. Untargeted analyses of dissolved organic matter provide an overview of molecular species in ice samples however, sample volumes usually required for these analyses are generally not available from deep ice cores. Here, we developed an analytical method using a nano-UPLC-nano-ESI-HRMS to detect major molecular species in ice cores. Samples (4 µL) from the TALos Dome Ice CorE (TALDICE), allowed investigating molecular species across a range of depths including during glacial and interglacial periods. We detected 317 chemical species that were tentatively assigned to fatty acids, hydroxy fatty acids and their degradation products (oxo-fatty acids and dicarboxylic acids), as well as oxidation byproducts of isoprene and monoterpenes. These compounds indicate that the main sources of the organic fraction are microbes as well as primary and secondary aerosols. Interglacial samples encompass a wide range of species including compounds from the oxidation of isoprene and monoterpenes as well as unsaturated fatty acids, while the glacial samples contained less diverse species. This difference may be due to decreased temperatures during the glacial period inhibiting terrestrial vegetation growth and increasing the sea ice extent, thereby weakening the emission sources.

Levoglucosan and phenols in Antarctic marine, coastal and plateau aerosols.

Due to its isolated location, Antarctica is a natural laboratory for studying atmospheric aerosols and pollution in remote areas. Here, we determined levoglucosan and phenolic compounds (PCs) at diverse Antarctic sites: on the plateau, a coastal station and during an oceanographic cruise. Levoglucosan and PCs reached the Antarctic plateau where they were observed in accumulation mode aerosols (with median levoglucosan concentrations of 6.4 pg m(-3) and 4.1 pg m(-3), and median PC concentrations of 15.0 pg m(-3) and 7.3 pg m(-3)). Aged aerosols arrived at the coastal site through katabatic circulation with the majority of the levoglucosan mass distributed on larger particulates (24.8 pg m(-3)), while PCs were present in fine particles (34.0 pg m(-3)). The low levoglucosan/PC ratios in Antarctic aerosols suggest that biomass burning aerosols only had regional, rather than local, sources. General acid/aldehyde ratios were lower at the coastal site than on the plateau. Levoglucosan and PCs determined during the oceanographic cruise were 37.6 pg m(-3) and 58.5 pg m(-3) respectively. Unlike levoglucosan, which can only be produced by biomass burning, PCs have both biomass burning and other sources. Our comparisons of these two types of compounds across a range of Antarctic marine, coastal, and plateau sites demonstrate that local marine sources dominate Antarctic PC concentrations.

Fukushima nuclear accident recorded in Tibetan Plateau snow pits.

The ß radioactivity of snow-pit samples collected in the spring of 2011 on four Tibetan Plateau glaciers demonstrate a remarkable peak in each snow pit profile, with peaks about ten to tens of times higher than background levels. The timing of these peaks suggests that the high radioactivity resulted from the Fukushima nuclear accident that occurred on March 11, 2011 in eastern Japan. Fallout monitoring studies demonstrate that this radioactive material was transported by the westerlies across the middle latitudes of the Northern Hemisphere. The depth of the peak ß radioactivity in each snow pit compared with observational precipitation records, suggests that the radioactive fallout reached the Tibetan Plateau and was deposited on glacier surfaces in late March 2011, or approximately 20 days after the nuclear accident. The radioactive fallout existed in the atmosphere over the Tibetan Plateau for about one month.

Temporal variations of perfluoroalkyl substances and polybrominated diphenyl ethers in alpine snow.

The occurrence and temporal variation of 18 perfluoroalkyl substances (PFASs) and 8 polybrominated diphenyl ethers (PBDEs) in the European Alps was investigated in a 10 m shallow firn core from Colle Gnifetti in the Monte Rosa Massif (4455 m above sea level). The firn core encompasses the years 1997-2007. Firn core sections were analyzed by liquid chromatography-tandem mass spectrometry (PFASs) and gas chromatography-mass spectrometry (PBDEs). We detected 12 PFASs and 8 PBDEs in the firn samples. Perfluorobutanoic acid (PFBA; 0.3-1.8 ng L(-1)) and perfluorooctanoic acid (PFOA; 0.2-0.6 ng L(-1)) were the major PFASs while BDE 99 (