RESUMO
Among the IV-VI compounds, GeSe has wide applications in nanoelectronics due to its unique photoelectric properties and adjustable band gap. Even though modulation of its physical characteristics, including the band gap, by an external field will be useful for designing novel devices, experimental work is still rare. Here, we report a detailed anisotropic Raman response of GeSe flakes under uniaxial tension strain. Based on theoretical analysis, the anisotropy of the phonon response is attributed to a change in anisotropic bond length and bond angle under in-plane uniaxial strain. An enhancement in anisotropy and band gap is found due to strain along the ZZ or AC directions. This study shows that strain-engineering is an effective method for controlling the GeSe lattice, and paves the way for modulating the anisotropic electric and optical properties of GeSe.
RESUMO
This paper addresses the robust stochastic finite-time and fixed-time chaos synchronization of two permanent magnet synchronous motors (PMSMs) in noise environment. The novel adaptive finite-time and fixed-time control schemes are implemented, respectively, which can not only ensure that the stochastic chaos synchronization of PMSMs can be achieved in a fast rate, but also determine the control gains successfully(not necessary to set them in advance). The sufficient conditions are derived in the light of the stochastic finite-time and fixed-time stability theories, where the upper bound of synchronization time can be estimated. Furthermore, the stochastic fixed-time synchronization can get rid of the dependence of initial conditions in PMSMs, which overcomes the critical deficiency of stochastic finite-time synchronization of PMSMs. Finally, simulation results demonstrate the validity of proposed theoretical analysis with comparisons.
RESUMO
Solid-liquid interface is a key concept of many research fields, enabling numerous physical phenomena and practical applications. For example, electrode-electrolyte interfaces with electric double layers have been widely used in energy storage and regulating physical properties of functional materials. Creating a specific interface allows emergent functionalities and effects. Here, we show the artificial control of ferroelectric-liquid interfacial structures to switch polarization states reversibly in a van der Waals layered ferroelectric CuInP2S6 (CIPS). We discover that upward and downward polarization states can be induced by spontaneous physical adsorption of dodecylbenzenesulphonate anions and N,N-diethyl-N-methyl-N-(2-methoxyethyl)-ammonium cations, respectively, at the ferroelectric-liquid interface. This distinctive approach circumvents the structural damage of CIPS caused by Cu-ion conductivity during electrical switching process. Moreover, the polarized state features super-long retention time (>1 year). The interplay between ferroelectric dipoles and adsorbed organic ions has been studied systematically by comparative experiments and first-principles calculations. Such ion adsorption-induced reversible polarization switching in a van der Waals ferroelectric enriches the functionalities of solid-liquid interfaces, offering opportunities for liquid-controlled two-dimensional ferroelectric-based devices.