Dynamic Effects during the Capillary Rise of Fluids in Cylindrical Tubes.

The mathematical models for the capillary-driven flow of fluids in tubes typically assume a static contact angle at the fluid-air contact line on the tube walls. However, the dynamic evolution of the fluid-air interface is an important feature during capillary rise. Furthermore, inertial effects are relevant at early times and may lead to oscillations. To incorporate and quantify the different effects, a fundamental description of the physical processes within the tube is used to derive an upscaled model of capillary-driven flow in circular cylindrical tubes. The upscaled model extends the classical Lucas-Washburn model by incorporating a dynamic contact angle and slip. It is then further extended to account for inertial effects. Finally, the solutions of the different models are compared to experimental data. In contrast to the Lucas-Washburn model, the models with dynamic contact angle match well the experimental data, both the rise height and the contact angle, even at early times. The models have a free parameter through the dynamic contact angle description, which is fitted using the experimental data. The findings here suggest that this parameter depends only on the properties of the fluid but is independent of geometrical features, such as the tube radius. Therefore, the presented models can predict the capillary-driven flow in tubular systems upon knowledge of the underlying dynamic contact-angle relation.

Event-based contact angle measurements inside porous media using time-resolved micro-computed tomography.

HYPOTHESIS: Capillary-dominated multiphase flow in porous materials is strongly affected by the pore walls' wettability. Recent micro-computed tomography (mCT) studies found unexpectedly wide contact angle distributions measured on static fluid distributions inside the pores. We hypothesize that analysis on time-resolved mCT data of fluid invasion events may be more directly relevant to the fluid dynamics. EXPERIMENT: We approximated receding contact angles locally in time and space on time-resolved mCT datasets of drainage in a glass bead pack and a limestone. Whenever a meniscus suddenly entered one or more pores, geometric and thermodynamically consistent contact angles in the surrounding pores were measured in the time step just prior to the displacement event. We introduced a new force-based contact angle, defined to recover the measured capillary pressure in the invaded pore throat prior to interface movement. FINDINGS: Unlike the classical method, the new geometric and force-based contact angles followed plausible, narrower distributions and were mutually consistent. We were unable to obtain credible results with the thermodynamically consistent method, likely because of sensitivity to common imaging artifacts and neglecting dissipation. Time-resolved mCT analysis can yield a more appropriate wettability characterization for pore scale models, despite the need to further reduce image analysis uncertainties.