Mobilization and health risk assessment of fertilizer induced uranium in coastal groundwater.

Uranium (U) in groundwater is hazardous to human health, especially if it is present in drinking water. The semiarid regions of southern India chiefly depend on groundwater for drinking purposes. In this regard, a comprehensive sampling strategy was adopted to collect groundwater representing different lithologies of the region. The samples were collected in two different seasons and analysed for major and minor ions along with total U in the groundwater. Two samples during pre monsoon (PRM) and seven samples during post monsoon (POM) had U > 30 µgL-1, which is above the World Health Organization's provisional guideline value. The high concentration of U (188 µgL-1) was observed in the alluvial formation though a few samples showed the release of U near the pink granite (39 µgL-1) and the concentration was low in the lateritic formation (10 µgL-1). The uranyl carbonato complexes UO2(CO3)22- and UO2(CO3)34- were associated with high pH which facilitated the transport of U into groundwater especially during POM. U3O8 is the major form observed in groundwater compared to either UO2 or UO3 in the both seasons. The uranium oxides were observed to be more prevalent at the neutral pH. Though U concentration increases with pH, it is mainly governed by the redox conditions. The principal component analysis (PCA) analysis also suggested redox conditions in groundwater to be the major process facilitating the U release mechanism regardless of the season. The POM season has an additional source of U in groundwater due to the application of nitrogenous fertilizers in the alluvium region. Furthermore, redox mobilization factor was predominantly observed near the coastal region and in the agricultural regions. The process of infiltration of the fertilizer-induced U was enhanced by the agricultural runoff into the surface water bodies in the region. Health risk assessment was also carried out by determining annual effective dose rate, cancer mortality risk, lifetime average daily dose and hazard quotient to assess the portability of groundwater in the study area. Artificial recharge technique and reducing the usage of chemical based fertilizers for irrigation are suggested as sustainable plans to safeguard the vulnerable water resource in this region.

Determination of vulnerable regions of SARS-CoV-2 in Malaysia using meteorology and air quality data.

This study aims to explore the state-wise assessment of SARS-CoV-2 (COVID-19) pandemic spread in Malaysia with focus on influence of meteorological parameters and air quality. In this study, state-wise COVID-19 data, meteorological parameters and air quality index (AQI) were collected from March 13 to April 30, 2020, which encompass three movement control order (MCO) periods in the country. Overall, total infected cases were observed to be higher in MCO phase 1 and 2 and significantly reduced in MCO phase 3. Due to the variation in the spatial interval of population density and individual immunity, the relationship of these parameters to pandemic spread could not be achieved. The study infers that temperature (T) between 23 and 25 °C and relative humidity (RH) (70-80%) triggered the pandemic spread by increase in the infected cases in northern and central Peninsular Malaysia. Selangor, WP Kuala Lumpur and WP Putrajaya show significantly high infected cases and a definite trend was not observed with respect to a particular meteorological factor. It is identified that high precipitation (PPT), RH and good air quality have reduced the spread in East Malaysia. A negative correlation of T and AQI and positive correlation of RH with total infected cases were found during MCO phase 3. Principal component analysis (PCA) indicated that T, RH, PPT, dew point (DP) and AQI are the main controlling factors for the spread across the country apart from social distancing. Vulnerability zones were identified based on the spatial analysis of T, RH, PPT and AQI with reference to total infected cases. Based on time series analysis, it was determined that higher RH and T in Peninsular Malaysia and high amount of PPT, RH and good air quality in East Malaysia have controlled the spreading during MCO phase 3. The predominance of D614 mutant was observed prior to March and decreases at the end of March, coinciding with the fluctuation of meteorological factors and air quality. The outcome of this study gives a general awareness to the public on COVID-19 and the influence of meteorological factors. It will also help the policymakers to enhance the management plans against the pandemic spreading apart from social distancing in the next wave of COVID-19. Supplementary Information: The online version contains supplementary material available at 10.1007/s10668-021-01719-z.

Distribution of natural radioactivity in different geological formations and their environmental risk assessment in Malaysia.

Labuan, Miri, Kundasang and Raub regions of Malaysia have very different geological formations and settings that could result in different levels of natural radioactivity. Hence, this study determines the influence of different geological formations on radioactivity in these locations using field measurements, petrology and geochemistry. A total of 141 gamma dose rates and 227 beta flux measurements were collected using Polimaster survey meters (PM1405) in these four regions. The gamma dose rate values range from 0.37 to 0.05 µSv/h with a mean value of 0.11 µSv/h. Beta flux values range from 3.46 to 0.12 CPS with a mean value of 0.57 CPS. Mineralogy and elemental composition of the different rock types were analysed using thin-section petrography, XRD, ICP and pXRF methods. Felsic igneous rocks such as syenite and granite have higher natural radioactivity and contain more radionuclide-bearing minerals such as apatite, zircon, allanite, K-feldspar, titanite, muscovite and biotite. Metamorphic rocks have the second highest natural radioactivity and contain fewer radioactive minerals. The natural radioactivity of sedimentary rocks mostly depends on their clay content. The gamma dose rate maps show that igneous and metamorphic regions around Raub have higher radioactivity compared to the sedimentary-dominated regions around Miri and Labuan. Annual effective dose (AED) and excess lifetime cancer risk (ELCR) were calculated to evaluate the potential health risk for inhabitants of these regions. Labuan and Miri are considered to be safe zones with respect to natural radioactivity as the results show little to no risk for the public, compared with the Raub region, which is medium to high risk.

Occurrence and distribution of geochemical elements in Miri estuary, NW Borneo: Evaluating for processes, sources and pollution status.

In this study, estuarine water samples were collected at diverse hot spots in Miri River Estuary, East Malaysia to appraise the geochemical processes, which controls the river water quality. The collected water samples were analysed for various physicochemical parameters (insitu parameters, nutrients, major ions and trace metals), including stable isotopes (oxygen and hydrogen). Suspended solids are also extracted from the water samples and analysed for trace metals. Standard graphs, Piper plot, Gibbs diagram, water quality indices, geochemical modelling and statistical analysis were used for the data analysis. The acquired water quality data was compared with national and international guidelines for the suitability of water for various purposes. Interpretation of data reveals that the estuarine water quality is deemed unsuitable to be used for both drinking and irrigation purposes. Overall, the elemental concentrations are increasing from downstream to river mouth. Based on pollution indices (HEI and Cd), downstream region shows high vulnerability to metal pollution due to anthropogenic disturbance. Isotope values of river water indicate direct atmospheric precipitation with minimal evaporation. Factor analysis reveals that seawater influx, urban pollution, domestic and agricultural discharges at the downstream region are the main controlling factors to the river water quality. It is also deduced that suspended solids play a vital role in the adsorption and desorption of trace metals in the estuarine water. The outcome of this study provides a comprehensive information on pollution status of Miri estuary, which helps the policy makers to practice sustainable management of this water resource for Miri community.

Assessment on urban lakes along the coastal region of Miri, NW Borneo: implication for hydrochemistry, water quality, and pollution risk.

The main purpose of this study is to assess the urban lake water quality along the coastal region of Miri City, Sarawak, East Malaysia. This study concentrates on the hydrochemical characteristics and the mechanisms controlling the suitability of the lakes for domestic, irrigation, and industrial purposes. A total of 15 lake water samples were collected and analysed for physical parameters, major ions, nutrients, BOD, COD, and heavy metals. The results show that Lakes 6, 7, and 8 commonly exceeded the National Drinking Water Quality Standards (NDWQS) limits, particularly in physical parameters and major ions. The cation dominance was Na+ > Mg2+ > K+ > Ca2+, while the anion dominance was Cl- > HCO3- > SO42-. It is inferred that lake 8 was affected by the seawater intrusion through the inlet flow, resulting in an excess concentration of ions present in that lake. The concentrations of heavy metals in these lakes were considerably low, indicating that most of them were from the geogenic source. Most of the lakes were NaCl water type and the main controlling mechanism were weathering and ionic exchange processes, with anthropogenic impacts. Based on the calculated Water Quality Index (WQI) according to the National Water Quality Standards (NWQS), all lakes were suitable for irrigation use (class IV), while most of these lakes fell under the "polluted" index. Apart from that, based on the National Lake Water Quality Standards (NLWQS), all lakes were classified under category D, indicating that the lakes must be kept in good condition. According to the irrigation quality indices, lakes 1, 2, 3, 4, and 5 were the most suitable for irrigation purposes. As for metal pollution indices (HPI and HEI), lakes 1, 2, 3, 4, 5, and 15 were considered safe with low pollution status. From the multivariate statistical analysis, it is deduced that both anthropogenic and geogenic impacts mostly influenced the quality of these lake waters. The outcome of this study will help the policymakers under the national water department in sustainable management of water resources in this region.

Spatial and temporal variations of geochemical processes and toxicity of water, sediments, and suspended solids in Sibuti River Estuary, NW Borneo.

A comprehensive geochemical study was conducted in the Sibuti River estuary by considering water, suspended solids (SS), and sediment samples from 36 stations during southwest monsoon (SWM) and northeast monsoon (NEM). In this study, the distribution of in situ parameters, major ions, nutrients, trace metals, and isotopes (δD, δ18O) were analyzed in water samples, whereas sediments and SS were studied for trace metals. The distribution revealed that suspended solids were the major carrier of Cd, Zn, and Mn, whereas sediments worked as a major source of Co, Cr, Ba, Se, Cu, and Pb. Na-Cl water type and ion exchange dominated the lower part of the estuary during both seasons. However, the mixed mechanism of Ca-Cl, Ca-Mg-Cl, and higher weathering indicated reverse ion exchange in the intermediate and upper parts of the estuary. Isotopic signatures of δD and δ18O in estuarine water indicate that the precipitation over the Limbang area dominates during SWM, whereas higher evaporation was confirmed during NEM. The factor analysis revealed that seawater influence in the estuary majority controlled the water chemistry irrespective of seasons. Major ions were mainly regulated by the tidal influence during the low flow time of the river (SWM), whereas the mixing mechanism of weathering and seawater controlled the concentrations during NEM. Nutrients such as NO3, SO42-, NH3, and NH4+ mainly originated from the agricultural fields and nitrification along with ammonification were responsible for the recycling of such nutrients. Trace metals except Cd were found to be geogenic in nature and originating mainly from the oxidation of pyrites present in the sandstone and mudstones of the Sibuti Formation. Redox condition was catalyzed by microorganisms near the river mouth, whereas Al-oxyhydroxides and Fe-oxyhydroxides complexes in the intermediate and upper part under oxygenated conditions controlled the absorption of metals. Overall, the estuary was found to be absorptive in nature due to ideal pH conditions and was confirmed by the saturation index (SI) of minerals.

Spatiotemporal distribution of microplastics in Miri coastal area, NW Borneo: inference from a periodical observation.

The current study aims to investigate the spatiotemporal distribution of microplastics (MPs) in the Miri coast, targeting their occurrences, characterisation, and potential sources. For a periodical study, coastal sediments were collected from three different time intervals (monsoon, post-monsoon, and post-COVID) and subjected to stereomicroscope, ATR-FTIR, and SEM-EDX analyses. These results show a significant increase of MPs in post-COVID samples by approximately 218% and 148% comparatively with monsoon and post-monsoon samples, respectively. The highest concentration of MPs was detected near the river mouths and industrial areas where the waste discharge rate and anthropogenic activities dominate. Fibre-type MPs are the most abundant, with an average of nearly 64%, followed by fragments, films, microbeads, and foams. The most dominant polymer types were polytetrafluoroethylene (PTFE), polyethylene (PE), polypropylene (PP), polystyrene (PS), and polyester (PET). Overall, the current study shows a better understanding of MPs occurrence and potential sources in the Miri coastal area.

Occurrence, distribution and sources of microplastics in beach sediments of Miri coast, NW Borneo.

Microplastics (MPs) pollution has gained a lot of global interests due to its toxicity to the surrounding ecosystems. The aim of this study is to identify the abundances, physical characteristics, polymer type and elemental composition of MPs in beach sediments of Miri coast, located in Sarawak State, East Malaysia. A total of 1553 particles from 24 sediment samples, collected from eight different beaches along Miri coastline were identified. MPs from the sediments were extracted using density separation method and analyzed through stereoscopic microscope, ATR-FTIR and SEM-EDX. MPs were present most abundant in Lutong Beach, which is the hotspot for the recreational activities. Fragments were identified as the highest abundance type of MPs, followed by fiber, foam and pellet. MPs of size of <1 mm were predominantly present in the samples. Varieties of colors were distinguished in which transparent or no color MPs were the highest quantity studied in the samples. Polymers identified were mainly polyethylene (PE), polyester (PET), polystyrene (PS) and polypropylene (PP), derived from primary and secondary MPs. Carbon and oxygen were dominant and have the highest concentration identified with other elements such as Ca, Al, Ti and Cl. The primary use of these elements as additives are associated with the manufacturing process as they are used to enhance the quality during plastic production. The outcome of this study is to be the first report to identify and characterize the MPs in beach sediments of Miri coast. The occurrence of MPs in Miri beaches may negatively impact marine organisms as this affects their food chain. As consumers, humans are most likely to be affected by the presence of MPs due to their consumption of marine animals, particularly fish present in this region.

Delineation of highland saline groundwater sources in Ba'kelalan region of NE Borneo to improve the salt-making production using geochemical and geophysical approaches.

The extraction of mountain salt from the saline waters is the basic livelihood of the Ba'kelalan communities of Sarawak. The current integrated approach is the first attempt to study the sources and geochemical processes of the saline groundwaters in this mountain region. Hence, in this study, saline groundwater samples from five existing wells in different seasons were analysed for hydrochemical parameters and multi-isotope composition (δ18O, δD, δ34S, δ11B and δ37Cl). The significant increase in TDS, EC and salinity was due to seasonal variation and fluctuation in water level based on hourly, daily and monthly observations. The geochemical ratios and the statistical techniques revealed that the salinity was due to the dissolution of marine evaporites as a dominant process, coupled with other factors such as water-rock interaction, ion exchange and sulphate reduction. From the isotopic signatures, it was inferred that the origin of saline groundwater was from the intense dissolution of marine evaporites such as halite dissolution and oxidation of -sulphide (pyrite). 2D electrical resistivity and seismic refraction methods were used to identify the lithological variations, depth of potential sources of saline groundwater, and the subsurface structures. It was inferred the probability of a conductive zone at a depth of 1-14 m, from which the saline groundwater plume migrates towards the perched aquifer. The presence of subsurface faults facilitated the movement of hypersaline groundwater from the saturated zone to the surface. The outcome of the study will support the dependent community to enhance their commercial salt production.

SARS-CoV-2 phase I transmission and mutability linked to the interplay of climatic variables: a global observation on the pandemic spread.

The study aims to determine the impact of global meteorological parameters on SARS-COV-2, including population density and initiation of lockdown in twelve different countries. The daily trend of these parameters and COVID-19 variables from February 15th to April 25th, 2020, were considered. Asian countries show an increasing trend between infection rate and population density. A direct relationship between the time-lapse of the first infected case and the period of suspension of movement controls the transmissivity of COVID-19 in Asian countries. The increase in temperature has led to an increase in COVID-19 spread, while the decrease in humidity is consistent with the trend in daily deaths during the peak of the pandemic in European countries. Countries with 65°F temperature and 5 mm rainfall have a negative impact on COVID-19 spread. Lower oxygen availability in the atmosphere, fine droplets of submicron size together with infectious aerosols, and low wind speed have contributed to the increase in total cases and mortality in Germany and France. The onset of the D614G mutation and subsequent changes to D614 before March, later G614 in mid-March, and S943P, A831V, D839/Y/N/E in April were observed in Asian and European countries. The results of the correlation and factor analysis show that the COVID-19 cases and the climatic factors are significantly correlated with each other. The optimum meteorological conditions for the prevalence of G614 were identified. It was observed that the complex interaction of global meteorological factors and changes in the mutational form of CoV-2 phase I influenced the daily mortality rate along with other comorbid factors. The results of this study could help the public and policymakers to create awareness of the COVID-19 pandemic.