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1.
Langmuir ; 39(15): 5495-5504, 2023 Apr 18.
Artigo em Inglês | MEDLINE | ID: mdl-37018471

RESUMO

Superhydrophobic coatings have garnered significant research interest due to their potential applications in areas such as ant-icing and windows. This study focuses on the development of superhydrophobic coatings using air-assisted electrospray and the effect of different carbon additives as templates in the coating. Carbon templates, with their unique topological varieties, offer a cost-effective alternative to other patterning technologies such as photolithography. By introducing dispersed carbon black, carbon nanotubes, and graphene additives in TEOS solution, silica is given the ability of localized secondary growth on or around the carbon surfaces as well as the building structure to provide adequate roughness on the substrate surface. The templated silica formations provide a thin coating with nano-scale roughness for heightened water resistance. As compared with the template-free coating that has small silica particles, a surface roughness of 135 nm, and a water contact angle (WCA) of 101.6° (non-superhydrophobic), the carbon templating effect allowed for increased silica particle size, a surface roughness as high as 845 nm, a WCA above 160°, and the ability to maintain superhydrophobicity over 30 abrasion cycles. The morphological characteristics that resulted from the templating effect correlate directly with heightened performance of the coatings. Herein, the carbon additives have been found to serve as cheap and effective templates for silica formation in thin TEOS-derived superhydrophobic coatings.

2.
Int J Phytoremediation ; : 1-13, 2023 Dec 02.
Artigo em Inglês | MEDLINE | ID: mdl-38042992

RESUMO

Herein, the application of granular activated carbon, jujube, and barberry tree stem powder for the removal of gasoline and kerosene from water was investigated. Kerosene removal rates upwards of 68.48, 83.87, and 99.02% were achieved using jujube tree stem powder, barberry tree stem powder, and granular activated carbon, respectively. Besides, gasoline removal rates upwards of 69.35, 55.02, and 95.59% were attained using jujube tree stem powder, barberry tree stem powder, and granular activated carbon, respectively. Isotherm data were further investigated and fitted using Langmuir, Freundlich, and Elovich models. The results indicated that the adsorption onto jujube adsorbent is a multilayer adsorption process over a heterogeneous surface, which is best illustrated by the Temkin (Ave. R2= 0.95) model. It was found that the Temkin isotherm (Ave. R2= 0.81) best describes the properties of barberry stem powder in the adsorption of gasoline and kerosene from water. Moreover, the best models to describe the characteristics of granular activated carbon in the adsorption of gasoline and kerosene from water were Freundlich (Ave. R2= 0.74) and Langmuir (Ave. R2= 0.73) isotherms, respectively. The adsorption kinetics showed that the pseudo-second-order was appropriate in modeling the adsorption kinetics of gasoline and kerosene to the studied adsorbents (R2>0.74).


The objective of this study was to identify the potential of agricultural biowastes derived biosorbents to remove petroleum products from contaminated water. Previously, jujube and barberry tree wastes had not been used to remove petroleum pollutants. Moreover, in this research agricultural wastes were used without any processing or energy consumption and all experiments were performed at water pH, so there was no need to add chemicals to adjust the pH.

3.
Int J Environ Health Res ; 33(12): 1465-1478, 2023 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-35921515

RESUMO

BACKGROUND: This study aimed to present a strategic waste management in two private hospitals in Yazd using models of the strengths, weaknesses, opportunities, and threats (SWOT) and quantitative strategic planning matrix (QSPM). METHODS: The strengths, weaknesses, opportunities, and threats of the organization was identified according to existing documents and expert team. The internal and external factors were identified by internal factor evaluation (IFE) and external factor evaluation (EFE) matrices. The strategies to improve waste management in two hospitals were presented by comparing internal and external factors. Finally, the attractiveness table was compiled and weighted using the QSPM method to prioritize the strategies. RESULTS: The results demonstrated that 24 strengths, 30 weaknesses, 16 opportunities, and 22 threats were identified. The final score of internal and external factors for hospital A and B were (X: 2.37, Y:1.88) and (X: 2.37, Y: 2.01), respectively. Based on the results, 12 strategies were presented. Finally, the strategy of "the improvement of green management indicators" was implemented as a priority according to QSPM matrix. CONCLUSION: The result of this study duplicated that using the QSPM and SWOT models is assist to present viable strategies to improve the health-care waste management.


Assuntos
Planejamento Estratégico , Gerenciamento de Resíduos , Hospitais Privados
4.
World J Microbiol Biotechnol ; 39(5): 137, 2023 Mar 28.
Artigo em Inglês | MEDLINE | ID: mdl-36976392

RESUMO

Electrical instruments are an integral part of human life resulting in a vast electronic waste generation (74.7 Mt by 2030), threatening human life and the environment due to its hazardous nature. Therefore, proper e-waste management is a necessity. Currently, bio-metallurgy is a sustainable process and an emerging research field. Simultaneous leaching of metals using two groups of indigenous heterotrophs and autotrophs was an exciting work done in this study. Bioleaching experiments using pre-adapted cultures were investigated at three e-waste densities: 5, 10, and 15 g/L. Statistical analysis was done using two-way ANOVA. Copper (93%), zinc (21.5%), and nickel (10.5%) had the highest recovery efficiencies. There was a significant difference between copper, nickel, tin, and zinc concentrations and the bacterial group (P < 0.05); Iron-oxidizing bacteria showed the most weight decrease and recovered 46-47% of total metals, mainly copper and nickel, while sulfur oxidizers were more capable of zinc leaching. The heterotrophs solubilized tin preferably and substantially decreased e-waste weight. Using heterotrophs alongside autotrophs is proposed to promote metal recovery.


Assuntos
Cobre , Resíduo Eletrônico , Humanos , Ferro , Níquel , Estanho , Metais , Bactérias , Zinco
5.
Waste Manag Res ; 41(4): 894-902, 2023 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-36245414

RESUMO

The growing consumption of electrical and electronic equipment leads to high amounts of electronic waste (e-waste), which is now considered the fastest-growing waste stream at the national and international levels. As well as being a potential secondary resource due to its precious metals content, e-waste also contains strategic metals and plastics. For instance, mobile phones have about 25-55% plastic substances. A few studies have been performed to investigate the potential of indigenous bacteria in metals' bioleaching from the polluted environment. Heterotrophic bioleaching potential in acidic conditions had been preliminarily investigated. Two soil types of iron ore were considered the source of indigenous bacteria. Despite the acidophilic nature of the bacterial consortium, they continued their leaching activity regardless of alkaline conditions. Maximum biorecovery rate related to copper (4%) responding to the main soil, owing to the higher copper content of mobile phone waste. Chromium had the least recovery rate (⩽0.002%). Overall, the maximum metal recovery rate was 4.7%, achieved by tailing heterotrophs at an e-waste loading of 10 g l-1. Statistical analysis had shown that there was no significant difference between the metal recovery rates and soil type or even the solid-liquid ratio (p > 0.05). Although acidophilic indigenous heterotrophs could not be an appropriate alternative for a large amount of metal recovery process, they might have considerable potential in the bioremediation of e-waste plastic fractions and metals in low concentrations simultaneously.


Assuntos
Resíduo Eletrônico , Ferro , Cobre/análise , Resíduo Eletrônico/análise , Metais , Bactérias , Solo
6.
Langmuir ; 38(9): 2852-2861, 2022 Mar 08.
Artigo em Inglês | MEDLINE | ID: mdl-35192772

RESUMO

Superhydrophobic surface is an enabling technology in numerous emerging and practical applications such as self-cleaning, anticorrosion, antifouling, anti-icing coatings, and oil-water separation. Here, we report a facile air-assisted electrospray approach to achieve a superhydrophobic surface by systematically studying spray conditions and the chemistry of a coating precursor solution consisting of silicon dioxide nanoparticles, polyacrylonitrile, and N,N-dimethylformamide. The wettability behavior of the surface was analyzed with contact angle measurement and correlated with surface structures. The superhydrophobic coating exhibits remarkable water and oil repellent characteristics, as well as good robustness against abrasion and harsh chemical conditions. This air-assisted electrospray technique has shown great control over the coating process and properties and thus can be potentially used for various advanced industrial applications for self-cleaning and anticorrosion surfaces.

7.
Environ Monit Assess ; 194(5): 362, 2022 Apr 13.
Artigo em Inglês | MEDLINE | ID: mdl-35416506

RESUMO

An accidental or intentional contamination event can raise health and sociopolitical concerns, erode public trust, and affect the operation of water distribution systems. In this regard, emergency management plans are required to describe the necessary measures in order to deal with a threat. This study was carried out to investigate the best ways to manage intrusion in a water distribution network. In this research, the optimal management approach to deal with chemical contamination in a water distribution network was examined under three scenarios using the particle swarm optimization method. In each scenario, three management solutions were used to manage the contamination, including closing the pipe, opening the fire hydrant, and using a combination of pipe closure and fire hydrant opening. Contamination risk impact on consumers' health was assessed in the network's emergency status and after implementation of the best pollution management scenarios. The results showed that in the benchmark network, pipe closure was slightly more successful than opening of the fire hydrant valve. In pollution management of a real network, pipe closure was less effective than the hydrant opening in all scenarios. Generally, all applied scenarios were successful in reducing the contamination risk among the exposed people, so that carcinogenic and non-carcinogenic risks reduced by 100% in all scenarios compared to the non-management state.


Assuntos
Abastecimento de Água , Água , Monitoramento Ambiental/métodos , Humanos , Medição de Risco , Qualidade da Água , Abastecimento de Água/métodos
8.
Air Med J ; 41(2): 228-232, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35307148

RESUMO

OBJECTIVE: Making an accurate clinical diagnosis in the field of prehospital is of great challenge in medical services. This study aimed to determine agreement between prehospital and in-hospital diagnoses. METHODS: The diagnostic agreement was determined by a comparison of the discharge diagnosis with the prehospital emergency technicians in a period of 6 months at the emergency medical services in northwest Azerbaijan. The diagnostic agreement of discharge diagnoses was compared with the fist diagnosis by the paramedics. The results were analyzed using the kappa agreement coefficient and the chi-square test. RESULTS: The overall agreement between the diagnosis made by the emergency medical technicians and the hospital's first diagnosis was 67% (95% confidence interval [CI], 61%-77%; k = 0.61; 95% CI, 0.56-0.67), whereas the agreement between the first diagnosis made by the emergency medical technicians and the hospital discharge diagnosis was 58% (95% CI, 49%-65%; k = 0.42; 95% CI, 0.37-0.48).There was a high proportion of diagnostic agreement for pregnancy (100%), poisoning by drugs (88%), essential (primary) hypertension (86%), and ischemic heart diseases (72%). There was a low proportion of diagnostic agreement for weakness (39%), mixed anxiety and depressive disorder (43%), and cerebellar stroke syndrome (59%). CONCLUSION: Our attention in practice and emergency medical courses should be directed to diseases that have a subjective history, such as weakness and anxiety, due to the high proportion of incorrect diagnoses by the prehospital emergency technician. It should be noted that most of the incorrectly diagnosed cases were overestimated with another coronary syndrome.


Assuntos
Serviços Médicos de Emergência , Auxiliares de Emergência , Pessoal Técnico de Saúde , Serviços Médicos de Emergência/métodos , Hospitais , Humanos
9.
Med J Islam Repub Iran ; 36: 73, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-36128278

RESUMO

Background: Cardiovascular diseases (CVDs) contribute to over 30% of deaths worldwide and more than 40% in Iran in 2019. Establishing a cost-effective program to control cardiovascular diseases is essential for any country. This study aimed to estimate the cost-effectiveness of the primary prevention program (IraPEN) for cardiovascular diseases in Iran. Methods: This methodological cost-effectiveness study was performed to estimate the cost-effectiveness of the IraPEN program by modifying cardiovascular disease risk factors in the IraPEN program. We calculated the economic burden of CVDs risk factors from 2016 to 2018 in 4 pilot cities in Iran. We observed 160,833 individuals for 2 years to measure the economic burden of cardiovascular diseases. To estimate the variation of the 1-year risk of cardiovascular illnesses, and according to the study's goal of estimating the 1-year risk of cardiovascular disease, only 36,631 people remained in the study who compiled the program's instruction for 1 year. Propensity scores were used to consider the effect of those excluded from the study. The 10-year risk of CVDs was estimated by the laboratory tests and information registered in the population's electronic records. To evaluate the effect of the IraPEN program in reducing the risk factors for cardiovascular diseases, major CVD risk factors were studied by the World Health Organization formula (whocvdrisk) and cardiovascular diseases risk scoring. We used the 10-year risk for CVDs to conduct a cost-effectiveness analysis in terms of cost per disability-adjusted life-year (DALY) saved. Results: According to estimates of the 1-year relative risk reduction in cardiovascular disease, the results showed that relative risk reductions for men and women were 0.74 and 0.65, respectively. Hence, about 174,088 annual acute CVDs events reduction would be expected; this decrease is predicted for men (93,034) more than women (81,054) for the total population of Iran. The total cost of treatment for people with cardiovascular diseases was 165 USD for coronary heart disease or stroke per individual. All risk factors were further reduced in women than men, except for smoking. DALYs averted was 1057.66 for samples who were in the study for a year (36631 samples). The total cost per averted DALY was 47.16. Conclusion: Estimating the costs associated with disease prevention programs is more important in developing countries. The most cost-effective strategies have been preventive therapies that target high-risk individuals. PEN risk reduction programs for primary prevention such as Ira-pen are highly cost-effective and efficient in low- and middle-income countries.

10.
Water Sci Technol ; 84(5): 1182-1189, 2021 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-34534115

RESUMO

Considering high concentrations of multidrug-resistant bacteria and antibiotic resistance genes (ARGs) in wastewater, agricultural reuse of treated wastewater may be a public health threat due to ARG dissemination in different environmental compartments, including soil and edible parts of crops. We investigated the presence of antibiotic-resistant Escherichia coli as an indicator bacterium from secondary treated wastewater (STWW), water- or wastewater-irrigated soil and crop samples. ARGs including blaCTX-m-32, blaOXA-23, tet-W, sul1, cml-A, erm-B, along with intI1 gene in E. coli isolates were detected via molecular methods. The most prevalent ARGs in 78 E. coli isolates were sul1 (42%), followed by blaCTX-m-32 (19%), and erm-B (17%). IntI1 as a class 1 integrons gene was detected in 46% of the isolates. Cml-A was detected in STWW isolates but no E. coli isolate from wastewater-irrigated soil and crop samples contained this gene. The results also showed no detection of E. coli in water-irrigated soil and crop samples. Statistical analysis showed a correlation between sul1 and cml-A with intI1. The results suggest that agricultural reuse of wastewater may contribute to the transmission of antibiotic-resistant bacteria to soil and crop. Further research is needed to determine the potential risk of ARB associated with the consumption of wastewater-irrigated crops.


Assuntos
Integrons , Águas Residuárias , Antagonistas de Receptores de Angiotensina , Inibidores da Enzima Conversora de Angiotensina , Antibacterianos/farmacologia , Farmacorresistência Bacteriana Múltipla , Escherichia coli/genética , Genes Bacterianos , Integrons/genética
11.
Ecotoxicol Environ Saf ; 171: 798-804, 2019 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-30660973

RESUMO

To manage the pistachio de-hulling waste (PW), investigated the co-composting process using a mixture of PW and cattle manure (CM) (5.5:10 dry weight) as well as PW and municipal dewatering sewage sludge (DSS) (1:10 dry weight) at the laboratory scale for 60 days. Compost toxicity was evaluated using the seed germination index (GI). The maximum temperatures in co-composting processes of PW+CM (51.9 °C) and PW+DSS (49.9 °C) were reported on the seventh day. The increase of temperature was higher in PW+CM and remained in the thermophilic phase for five days. In both reactors, the pH rates decreased, increased, and finally remained neutral. The C/N ratio decreased in both reactors, but the reduction rate was faster in the PW+DSS reactor. Sodium (Na%) and potassium (K%) contents were increased, while the concentrations of Cu, Zn, Fe, and Mn were decreased during the processes. The numbers of parasite eggs in the final composts of the reactors containing PW+CM and PW+DSS were zero and 8 Number/4gDW, respectively. The amounts of Salmonella were zero in the final products of reactors containing PW+CM and PW+DSS. The results of GI showed that the final compost of PW+CM process was not toxic for the plants, whereas the PW+DDS final compost was toxic. In conclusion, the co-compost product of the PW+CM reactor had higher quality than the PW+DSS reactor. So, it is suitable for PW management.


Assuntos
Esterco , Pistacia , Esgotos , Gerenciamento de Resíduos , Resíduos/efeitos adversos , Animais , Bovinos , Compostagem , Metais/análise , Temperatura
12.
Water Sci Technol ; 2017(3): 636-649, 2018 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-30016281

RESUMO

The aim of study is removal of atenolol from aqueous solutions by multiwalled carbon nanotubes modified with ozone. The design of the experiment was adopted across four levels with the L16 matrix arrangement. The factors influencing atenolol adsorption include changes in the pH value, contact time, the dose of the modified multiwall carbon nanotube, and the initial concentration of atenolol in the solution; these factors were evaluated along with the extent of their influence on removal efficiency. Data analyses were performed by the Design Expert 6 software. The results indicated that the pH, contact time, adsorbent dose, and the initial concentration were 7, 20 min, 0.15 g/L and 1 mg/L, respectively. In this state, the removal efficiency was calculated to be 75.79%. The maximum adsorption capacity was obtained as 5.05 mg/g under optimal conditions. The data were analyzed using adsorption models obtained from the isotherm fitting tool software. The results suggested that the data had a greater congruence with the Freundlich model (corrected Akaike information criterion = 2.58). Furthermore, the kinetics of the reactions followed pseudo second order kinetics (R2 = 0.95). Based on this study, it can be concluded that modified multiwall carbon nanotubes enjoy high potential and efficiency as adsorbents for the removal of atenolol from aqueous solutions.


Assuntos
Atenolol/química , Nanotubos de Carbono , Ozônio , Poluentes Químicos da Água/química , Purificação da Água/métodos , Adsorção , Concentração de Íons de Hidrogênio , Cinética , Soluções , Eliminação de Resíduos Líquidos/métodos , Água
13.
J Environ Manage ; 193: 312-317, 2017 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-28235730

RESUMO

In this study, performance of Integrated Fixed-film Activated Sludge (IFAS) system in treatment of Linear Alkylbenzene Sulfonate (LAS), and oil & grease in synthetic greywater and effect of Organic Loading Rates (OLRs) on removal efficiency within a period of 105 days were investigated. Present study was carried out in a pilot scale under such conditions as temperature of 30 ± 1 °C, dissolved oxygen of 2.32 ± 0.91 mg/l, pH of 8.01 ± 0.95 and OLRs of 0.11-1.3gCOD/L.d. Also, Scanning Electron Microscopy (SEM) images were employed to specify rate of the biofilm formed on the media inside the reactor IFAS. The best removal efficiency for COD, LAS and oil and grease were respectively obtained as 92.52%, 94.24% and 90.07% in OLR 0.44gCOD/L.d. The assessment of loading rate indicated that with increased OLR to 0.44gCOD/L.d, removal efficiency of COD, oil and grease was increased while with increased OLR, removal efficiency was decreased. In doing so, based on the statistical test ANOVA, such a difference between removal efficiencies in diverse OLRs was significant for COD (p = 0.003), oil and grease (p = 0.01). However, in terms of LAS, with increased value of OLR to 0.44gCOD/L.d, the removal efficiency was increased and then with higher OLRs, removal efficiency was slightly decreased that is insignificant (p = 0.35) based on the statistical test ANOVA. The SEM images also showed that the biofilm formed on the media inside IFAS reactor plays a considerable role in adsorption and biodegradation of LAS, and oil & grease in greywater. The linear relation between inlet COD values and rate of removed LAS indicated that the ratio of inlet COD (mg/L) to removed LAS (mg/L) was 0.4. Therefore, use of IFAS system for biodegradation of LAS, oil and grease in greywater can be an applicable option.


Assuntos
Benzeno , Esgotos , Biodegradação Ambiental , Biofilmes , Reatores Biológicos , Oxigênio , Eliminação de Resíduos Líquidos
14.
Environ Monit Assess ; 189(7): 342, 2017 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-28623574

RESUMO

Bacteria prevalence has increased in health centers and hospitals. Infection control can decrease the number of bacteria. Bacteria cause 90% of nosocomial infections and fungi, viruses, or protozoa are less involved. Bacteria control can decrease the number of diseases. The Simultaneous titanium oxide (SMTiO) is a new method of disinfection. This process degrades bacteria by producing hydroxyl radical. The present study was conducted with the aim of analyzing the bactericidal effect of simultaneous titanium oxide on common hospital bacteria. In this study, SMTiO system was placed under a laminar hood. Escherichia coli, Klebsiella pneumonia, Staphylococcus aureus, Pseudomonas aeruginosa, and Citrobacter freundii were selected as common hospital bacteria. Treatment operations were conducted at the bacteria concentration 106 cells/mL and the exposure times of 1 to 48 h. Then, the bacteria colonies were counted and removal rate calculated separately each of the bacteria. Finally, data analysis was conducted by using one-way ANOVA. Results showed that E. coli and C. freundii had the highest removal rate (40%) and the lowest removal (14%), respectively. Results confirmed that SMTiO can degrade Gram-positive and Gram-negative bacteria, but its effects were lower on Gram-positive bacteria. Results showed that removal efficiency increased gradually during exposure periods. We recommend that future studies should analyze the structure of bacteria after the treatment with SMTiO.


Assuntos
Antibacterianos/toxicidade , Titânio/toxicidade , Bactérias/efeitos dos fármacos , Infecção Hospitalar/prevenção & controle , Desinfecção/métodos , Monitoramento Ambiental , Escherichia coli/efeitos dos fármacos , Fungos/efeitos dos fármacos , Hospitais , Humanos , Testes de Sensibilidade Microbiana , Pseudomonas aeruginosa/efeitos dos fármacos , Staphylococcus aureus/efeitos dos fármacos
15.
Water Sci Technol ; 74(11): 2569-2581, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27973362

RESUMO

Atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) is a component of S-triazine. Its characteristics make it a pollutant of ecosystems and a probable human carcinogen. The present study evaluated volcanic pumice stone as a suitable media for biological growth and biofilm development in a fixed-bed sequencing batch reactor (FBSBR) for atrazine removal from aquatic environments. The FBSBR was fed with synthetic wastewater containing sucrose and atrazine at four hydraulic retention times to assess biodegradation of atrazine by a microbial consortium for removal from aquatic environments. The maximum efficiency for atrazine and soluble chemical oxygen demand removal were 97.9% and 98.9%, respectively. The results of this research showed that the Stover-Kincannon model was a very good fit (R2 > 99%) for loading atrazine onto the FBSBR. Increasing the initial concentration of atrazine increased the removal efficiency. There was no significant inhibition of the mixed aerobic microbial consortia by the atrazine. Atrazine degradation depended on its initial concentration in the wastewater and the amount of atrazine in the influent. Although this system shows good potential for atrazine removal from aqueous environments, that remaining in the effluent does not yet meet international standards. Further research is required to make this system effective for removal of atrazine from the environment.


Assuntos
Atrazina/metabolismo , Reatores Biológicos , Herbicidas/metabolismo , Silicatos , Poluentes Químicos da Água/metabolismo , Biodegradação Ambiental , Biofilmes , Análise da Demanda Biológica de Oxigênio , Consórcios Microbianos/fisiologia , Eliminação de Resíduos Líquidos/métodos , Purificação da Água/métodos
16.
Environ Monit Assess ; 188(10): 570, 2016 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-27640165

RESUMO

Poor air quality is one of the most important environmental problems in many large cities of the world, which can cause a wide range of acute and chronic health effects, including partial physiological disorders and cardiac death due to respiratory and cardiovascular diseases. According to the latest edition of the national standard for air quality, maximum contamination level is 15 µg/m(3) per year and 35 µg/m(3) per day. The aim of this study was to evaluate cardiovascular, respiratory, and total mortality attributed to PM2.5 in the city of Mashhad during 2013. To this end, the Air Q model was used to assess health impacts of PM2.5 and human exposure to it. In this model, the attributable proportion of health outcome, annual number of excess cases of mortality for all causes, and cardiovascular and respiratory diseases were estimated. The results showed that the number of excess cases of mortality for all causes and cardiovascular and respiratory diseases attributable to PM2.5 was 32, 263, and 332 µg/m(3), respectively. Moreover, the annual average of PM2.5 in Mashhad was obtained to be 37.85 µg/m(3). This study demonstrated that a high percentage of mortality resulting from this pollutant could be due to the high average concentration of PM2.5 in the city during 2013. In this case, using the particle control methods, such as optimal use of fuel, management of air quality in urban areas, technical inspection of vehicles, faster development of public transport, and use of industrial technology can be effective in reducing air pollution in cities and turning existing situations into preferred ones.


Assuntos
Poluentes Atmosféricos/toxicidade , Poluição do Ar/análise , Doenças Cardiovasculares/mortalidade , Monitoramento Ambiental/métodos , Material Particulado/toxicidade , Doenças Respiratórias/mortalidade , Poluentes Atmosféricos/análise , Doenças Cardiovasculares/induzido quimicamente , Humanos , Irã (Geográfico) , Masculino , Modelos Teóricos , Material Particulado/análise , Doenças Respiratórias/induzido quimicamente , Fatores de Tempo
17.
Clin Lab ; 60(2): 207-15, 2014.
Artigo em Inglês | MEDLINE | ID: mdl-24660532

RESUMO

BACKGROUND: Beta-thalassemia major is one of the most frequent hemoglobinopathies in the world. This is a study on the levels of prooxidant-antioxidant balance (PAB) that can measure the pro-oxidant burden and the anti-oxidant capacity simultaneously in one assay, giving a redox index, as well as an assessment of high-sensitivity C-reactive protein (hs-CRP) in patients with beta-thalassemia major. It also determines the impact both on kidney function tests. METHODS: Ninety subjects with beta-thalassemia major (betaTM) and 90 more healthy subjects as the control group were enrolled in the study. Laboratory parameters, serum hs-CRP, and the novel assay of prooxidant-antioxidant balance were measured. RESULTS: Biochemical and hematological variables, except MCHC, were significantly decreased in patients. Ferritin (p < 0.001) and PAB (p < 0.001) values were statistically increased in patients, whereas hs-CRP (p > 0.05) did not significantly increase in patients. Spearman's correlation univariate analysis showed no significant correlation between PAB with hs-CRP or ferritin. However, there was a significant statistical correlation between hs-CRP with creatinine and triglycerides. Also we found a slight and negative correlation between high-density lipoprotein cholesterol, hemoglobin, and hemotocrit with inflammatory factor. CONCLUSIONS: Briefly, we found higher levels of PAB values and a slight increase in hs-CRP concentration in patients, which may be involved in the pathological consequences of beta-thalassemia major and contribute to the gradual development of injury to the organs.


Assuntos
Antioxidantes/metabolismo , Proteína C-Reativa/metabolismo , Oxidantes/metabolismo , Talassemia beta/metabolismo , Envelhecimento/sangue , Estudos de Casos e Controles , Demografia , Feminino , Ferritinas/sangue , Humanos , Modelos Lineares , Masculino , Análise Multivariada , Oxidantes/sangue , Adulto Jovem , Talassemia beta/sangue
18.
Heliyon ; 10(9): e29601, 2024 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-38765125

RESUMO

Antibiotic resistance (AR) is a major global health concern, but current surveillance efforts primarily focus on healthcare settings, leaving a lack of understanding about AR across all sectors of the One Health approach. To bridge this gap, wastewater surveillance provides a cost-effective and efficient method for monitoring AR within a population. In this study, we implemented a surveillance program by monitoring the wastewater effluent from two large-scale municipal treatment plants situated in Isfahan, a central region of Iran. These treatment plants covered distinct catchment regions and served a combined population about two million of residents. Furthermore, the effect of physicochemical and microbial characteristics of wastewater effluent including biological oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), temperature, total coliforms and Escherichia coli concentration on the abundance of ARGs (blaCTX-M, tetW, sul1, cmlA, and ermB) and class 1 integron-integrase gene (intI1) were investigated. Sul1 and blaCTX-M were the most and least abundant ARGs in the two WWTPs, respectively. Principal Component Analysis showed that in both of the WWTPs all ARGs and intI1 gene abundance were positively correlated with effluent temperature, but all other effluent characteristics (BOD, COD, TSS, total coliforms and E. coli) showed no significant correlation with ARGs abundance. Temperature could affect the performance of conventional activated sludge process, which in turn could affect the abundance of ARGs. The results of this study suggest that other factors than BOD, COD and TSS may affect the ARGs abundance. The predicted AR could lead to development of effective interventions and policies to combat AR in the clinical settings. However, further research is needed to determine the relationship between the AR in wastewater and clinical settings as well as the effect of other influential factors on ARGs abundance.

20.
Sci Rep ; 14(1): 12575, 2024 05 31.
Artigo em Inglês | MEDLINE | ID: mdl-38822086

RESUMO

This study investigated batch-fed vermicomposting of cow manure, with a specific focus on assessing the effects of tylosin on the weight of earthworms and the overall quality of the resulting manure. Five reactors, including three concentrations of tylosin (50, 100, and 150 mg/kg) and two control reactors, were employed. Residual tylosin concentrations were measured using high-performance liquid chromatography (HPLC). Quality parameters such as pH, temperature, volatile solids (VS), organic carbon content (OCC), electrical conductivity (EC), ash content, C/N ratio, total Kjeldahl nitrogen (TKN), and microbial content were evaluated. The toxicity and maturity of vermicompost were assessed by determining the germination index (GI). The study also monitored variations in the earthworm's weight. The results demonstrated a decreasing trend in VS, OCC, C/N, and fecal coliforms, along with increased pH, EC, ash content, and TKN during the vermicomposting process. Furthermore, investigations revealed significant reductions in the reactors with tylosin concentrations of 50, 100, and 150 mg/kg, resulting in the removal of 98%, 90.48%, and 89.38% of the initial tylosin, respectively. This result confirms the faster removal of tylosin in reactors with lower concentrations. Degradation of tylosin also conforms to first-order kinetics. The findings showed a significant influence of tylosin on the weight of Eisenia fetida earthworms and the lowest antibiotic concentration led to the highest weight gain. Finally, the high percentage of germination index (90-100%) showed that the quality and maturity of vermicompost is by national and international standards.


Assuntos
Compostagem , Esterco , Oligoquetos , Tilosina , Animais , Tilosina/farmacologia , Esterco/análise , Oligoquetos/efeitos dos fármacos , Oligoquetos/metabolismo , Bovinos , Compostagem/métodos , Solo/química , Antibacterianos/farmacologia , Concentração de Íons de Hidrogênio
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