Thermally assisted optical processes in InP/ZnS quantum dots.

The utilization of InP-based biocompatible quantum dots (QDs) necessitates a comprehensive understanding of the structure-dependent characteristics influencing their optical behavior. The optimization of core/shell QDs for practical applications is of particular interest due to their reduced toxicity, enhanced photostability, and improved luminescence efficiency. This optimization involves analyzing thermally activated processes involving exciton and defect-related energy levels. This study investigates water-soluble colloidal InP/ZnS QDs with varying shell thicknesses and stabilizing coatings using temperature-dependent optical absorption (OA) and photoluminescence (PL). Our results indicate that all samples experience temperature-induced shifts in exciton absorption and luminescence peaks due to interactions with acoustic phonons. Despite the wide size distribution of nanocrystals, the halfwidth of the bands remains constant. We observe a temperature-dependent Stokes shift in InP/ZnS QDs, revealing the fine structure of exciton states across different configurations. Furthermore, our findings demonstrate common mechanisms underlying PL thermal quenching in these QDs, regardless of the shell thickness or coating type. Specifically, defect-related emissions arise from localized energy levels at the core/shell interface. At the same time, exciton PL quenching primarily occurs through thermally activated electron migration from the InP core to the ZnS shell. Overall, our study highlights the potential for tailoring the temperature response of InP/ZnS QDs by adjusting shell thickness, offering opportunities to optimize their performance for specific applications.

Research Process on Photodetectors based on Group-10 Transition Metal Dichalcogenides.

Rapidly evolving group-10 transition metal dichalcogenides (TMDCs) offer remarkable electronic, optical, and mechanical properties, making them promising candidates for advanced optoelectronic applications. Compared to most TMDCs semiconductors, group-10-TMDCs possess unique structures, narrow bandgap, and influential physical properties that motivate the development of broadband photodetectors, specifically infrared photodetectors. This review presents the latest developments in the fabrication of broadband photodetectors based on conventional 2D TMDCs. It mainly focuses on the recent developments in group-10 TMDCs from the perspective of the lattice structure and synthesis techniques. Recent progress in group-10 TMDCs and their heterostructures with different dimensionality of materials-based broadband photodetectors is provided. Moreover, this review accounts for the latest applications of group-10 TMDCs in the fields of nanoelectronics and optoelectronics. Finally, conclusions and outlooks are summarized to provide perspectives for next-generation broadband photodetectors based on group-10 TMDCs.

Exploration of the origin of the excellent charge-carrier dynamics in Ruddlesden-Popper oxysulfide perovskite Y2Ti2O5S2.

Although the efficient separation of electron-hole (e-h) pairs is one of the most sought-after electronic characteristics of materials, due to thermally induced atomic motion and other factors, they do not remain separated during the carrier transport process, potentially leading to rapid carrier recombination. Here, we utilized real-time time-dependent density functional theory in combination with nonadiabatic molecular dynamics (NAMD) to explore the separated dynamic transport path within Ruddlesden-Popper oxysulfide perovskite Y2Ti2O5S2 caused by the dielectric layer and phonon frequency difference. The underlying origin of the efficient overall water splitting in Y2Ti2O5S2 is systematically explored. We report the existence of the bi-directional e-h separate-path transport, in which, the electrons transport in the Ti2O5 layer and the holes diffuse in the rock-salt layer. This is in contrast to the conventional e-h separated distribution with a crowded transport channel, as observed in SrTiO3 and hybrid perovskites. Such a unique feature finally results in a long carrier lifetime of 321 ns, larger than that in the SrTiO3 perovskite (160 ns) with only one carrier transport channel. This work provides insights into the carrier transport in lead-free perovskites and yields a novel design strategy for next-generation functionalized optoelectronic devices.

Mach-Zehnder interferometer based integrated-photonic acetone sensor approaching the sub-ppm level detection limit.

The detection of acetone in the gaseous form in exhaled breath using an integrated sensor can provide an effective tool for disease diagnostics as acetone is a marker for monitoring human metabolism. An on-chip acetone gas sensor based on the principle of Mach-Zehnder interferometer is proposed and demonstrated. The sensing arm of the device is activated with a composite film of polyethyleneimine and amido-graphene oxide as the gas-sensitive adsorption layer. The composite film demonstrates good selectivity to acetone gas, can be used repeatedly, and is stable in long-term use. Room temperature operation has been demonstrated for the sensor with high sensitivity under a 20 ppm acetone environment. The detection limit can reach 0.76 ppm, making it feasible to be used for the clinical diagnosis of diabetes and the prognosis of heart failure.

Simultaneous negative reflection and refraction and reverse-incident right-angle collimation of sound in a solid-fluid phononic crystal.

The square lattice phononic crystal (PnC) has been used extensively to demonstrate metamaterial effects. Here, positive and negative refraction and reflection are observed simultaneously due to the presence of Umklapp scattering of sound at the surface of PnC and square-like equifrequency contours (EFCs). It is found that a shift in the EFC of the third transmission band away from the center of the Brillouin zone results in an effectively inverted EFC. The overlap of the EFC of the second and third band produce quasimomentum-matching conditions that lead to multi-refringence phenomena from a single incident beam without the introduction of defects into the lattice. Additionally, the coupling of a near-normal incident wave to a propagating almost perpendicular Bloch mode is shown to lead to strong right-angle redirection and collimation of the incident acoustic beam. Each effect is demonstrated both numerically and experimentally for scattering of ultrasound at a 10-period PnC slab in water environment.

Analyzing growth kinematics and fractal dimensions of molybdenum disulfide films.

Though the positive role of alkali halides in realizing large area growth of transition metal dichalcogenide layers has been validated, the film-growth kinematics has not yet been fully established. This work presents a systematic analysis of the MoS2morphology for films grown under various pre-treatment conditions of the substrate with sodium chloride (NaCl). At an optimum NaCl concentration, the domain size of the monolayer increased by almost two orders of magnitude compared to alkali-free growth of MoS2. The results show an inverse relationship between fractal dimension and areal coverage of the substrate with monolayers and multi-layers, respectively. Using the Fact-Sage software, the role of NaCl in determining the partial pressures of Mo- and S-based compounds in gaseous phase at the growth temperature is elucidated. The presence of alkali salts is shown to affect the domain size and film morphology by affecting the Mo and S partial pressures. Compared to alkali-free synthesis under the same growth conditions, MoS2film growth assisted by NaCl results in ≈81% of the substrate covered by monolayers. Under ideal growth conditions, at an optimum NaCl concentration, nucleation was suppressed, and domains enlarged, resulting in large area growth of MoS2monolayers. No evidence of alkali or halogen atoms were found in the composition analysis of the films. On the basis of Raman spectroscopy and photoluminescence measurements, the MoS2films were found to be of good crystalline quality.

Ultrasound Imaging by Thermally Tunable Phononic Crystal Lens.

This work demonstrates the detections and mappings of a solid object using a thermally tunable solid-state phononic crystal lens at low frequency for potential use in future long-distance detection. The phononic crystal lens is infiltrated with a polyvinyl alcohol-based poly n-isopropyl acrylamide (PVA-PNIPAm) bulk hydrogel polymer. The hydrogel undergoes a volumetric phase transition due to a temperature change leading to a temperature-dependent sound velocity and density. The temperature variation from 20 °C to 39 °C changes the focal length of the tunable solid-state lens by 1 cm in the axial direction. This thermo-reversible tunable focal length lens was used in a monostatic setup for one- and two-dimensional mapping scans in both frequency domain echo-intensity and temporal domain time-of-flight modes. The experimental results illustrated 1.03 ± 0.15λ and 2.35 ± 0.28λ on the lateral and axial minimum detectable object size. The experiments using the tunable lens demonstrate the capability to detect objects by changing the temperature in water without translating an object, source, or detector. The time-of-flight mode modality using the tunable solid-state phononic lens increases the signal-to-noise ratio compared to a conventional phononic crystal lens.

Enhanced photoluminescence emission from anthracene-doped polyphenylsiloxane glass.

Anthracene-doped polyphenylsiloxane (PPS) glass containing silver nanoparticles (AgNPs) of appropriate size was synthesized in a form of solid thin films for modifying light emission characteristics. The photoluminescence (PL) emission from the anthracene molecules at ~2.95 eV was resonantly coupled to the localized surface plasmon (LSP) polariton modes that were induced by the excitation of ~30 nm sized AgNPs. The increase in absorption of incident photons within a highly scattering medium, energy transfer from the localized excitons to the LSP modes, and the electrostatic Coulomb effects of the excitons in the presence of metal NPs all resulted in a significant enhancement of PL emission. The PL enhancement is dependent on the concentration of the anthracene molecules. The integrated PL intensity enhancement at the optimum concentration of anthracene molecules in the PPS glass with AgNPs is found to exceed 50.

Acoustic Attenuation and Dispersion in Fatty Tissues and Tissue Phantoms Influencing Ultrasound Biomedical Imaging.

The development of ultrasonic imaging techniques is optimized using artificial tissue phantoms before the practical applications. However, due to the strong attenuation and dispersion, accumulated fatty tissues can significantly impact the resolution and even feasibility of certain ultrasonic imaging modalities. An appropriate characterization of the acoustic properties on fatty phantoms can help the community to overcome the limitations. Some of the existing methods heavily overestimate attenuation coefficients by including the reflection loss and dispersion effects. Hence, in this study, we use numerical simulation-based comparison between two major attenuation measurement configurations. We further pointed out the pulse dispersion in viscoelastic tissue phantoms by simulations, which barely attracted attention in the existing studies. Using the selected attenuation and dispersion testing methods that were selected from the numerical simulation, we experimentally characterized the acoustic properties of common fatty tissue phantoms and compared the acoustic properties with the natural porcine fatty tissue samples. Furthermore, we selected one of the tissue phantoms to construct ultrasound imaging samples with some biomasses. With the known attenuation and dispersion of the tissue phantom, we showed the clarity enhancement of ultrasound imaging by signal post-processing to weaken the attenuation and dispersion effects.

Plasmon-Induced Enhanced Light Emission and Ultrafast Carrier Dynamics in a Tunable Molybdenum Disulfide-Gallium Nitride Heterostructure.

The effect of localized plasmon on the photoemission and absorption in hybrid molybdenum disulfide-Gallium nitride (MoS2-GaN) heterostructure has been studied. Localized plasmon induced by platinum nanoparticles was resonantly coupled to the bandedge states of GaN to enhance the UV emission from the hybrid semiconductor system. The presence of the platinum nanoparticles also increases the effective absorption and the transient gain of the excitonic absorption in MoS2. Localized plasmons were also resonantly coupled to the defect states of GaN and the exciton states using gold nanoparticles. The transfer of hot carriers from Au plasmons to the conduction band of MoS2 and the trapping of excited carriers in MoS2 within GaN defects results in transient plasmon-induced transparency at ~1.28 ps. Selective optical excitation of the specific resonances in the presence of the localized plasmons can be used to tune the absorption or emission properties of this layered 2D-3D semiconductor material system.

Acoustic Metasurface-Aided Broadband Noise Reduction in Automobile Induced by Tire-Pavement Interaction.

The primary noise sources of the vehicle are the engine, exhaust, aeroacoustic noise, and tire-pavement interaction. Noise generated by the first three factors can be reduced by replacing the combustion engine with an electric motor and optimizing aerodynamic design. Currently, a dominant noise within automobiles occurs from the tire-pavement interaction over a speed of 70-80 km/h. Most noise suppression efforts aim to use sound absorbers and cavity resonators to narrow the bandwidth of acoustic frequencies using foams. We demonstrate a technique utilizing acoustic metasurfaces (AMSes) with high reflective characteristics using relatively lightweight materials for noise reduction without any change in mechanical strength or weight of the tire. A simple technique is demonstrated that utilizes acoustic metalayers with high reflective characteristics using relatively lightweight materials for noise reduction without any change in mechanical strength or weight of the tire. The proposed design can significantly reduce the noise arising from tire-pavement interaction over a broadband of acoustic frequencies under 1000 Hz and over a wide range of vehicle speeds using a negative effective dynamic mass density approach. The experiment demonstrated that the sound transmission loss of AMSes is 2-5 dB larger than the acoustic foam near the cavity mode, at 200-300 Hz. The proposed approach can be extended to the generalized area of acoustic and vibration isolation.

Thermally Tunable Acoustic Beam Splitter Based on Poly(vinyl alcohol) Poly(N-isopropylacrylamide) Hydrogel.

In this study, we demonstrated a thermally tunable acoustic beam splitter using a poly(vinyl alcohol) poly(N-isopropylacrylamide) hydrogel (PVA-pNIPAM). The nature of PVA-pNIPAM hydrogel offers exceptional temperature-dependent physical properties due to its phase transition around its lower critical solution temperature. The acoustic impedance of the hydrogel can be tuned below, above, or matched to that of water by changing the environmental temperature. An acoustic wave propagating in water can be split into transmitted and reflected components by the PVA-pNIPAM hydrogel slab on varying its angle of incidence. The intensity ratio between the reflected and the transmitted componence can be adjusted by tuning the temperature of the medium. The acoustic beam can be entirely reflected at a temperature corresponding to the matched impedance between hydrogel and water. The beam-splitting behavior was observed for acoustic waves from both a monochromatic wave and broadband pulse source. In addition, the phase of beam split pulses can be reversed by selecting the hydrogel's operating temperature.

A Review of Diagnostics Methodologies for Metal Additive Manufacturing Processes and Products.

Additive manufacturing technologies based on metal are evolving into an essential advanced manufacturing tool for constructing prototypes and parts that can lead to complex structures, dissimilar metal-based structures that cannot be constructed using conventional metallurgical techniques. Unlike traditional manufacturing processes, the metal AM processes are unreliable due to variable process parameters and a lack of conventionally acceptable evaluation methods. A thorough understanding of various diagnostic techniques is essential to improve the quality of additively manufactured products and provide reliable feedback on the manufacturing processes for improving the quality of the products. This review summarizes and discusses various ex-situ inspections and in-situ monitoring methods, including electron-based methods, thermal methods, acoustic methods, laser breakdown, and mechanical methods, for metal additive manufacturing.

Crystallographic texture dependent bulk anisotropic elastic response of additively manufactured Ti6Al4V.

Rapid thermokinetics associated with laser-based additive manufacturing produces strong bulk crystallographic texture in the printed component. The present study identifies such a bulk texture effect on elastic anisotropy in laser powder bed fused Ti6Al4V by employing an effective bulk modulus elastography technique coupled with ultrasound shear wave velocity measurement at a frequency of 20 MHz inside the material. The combined technique identified significant attenuation of shear velocity from 3322 ± 20.12 to 3240 ± 21.01 m/s at 45[Formula: see text] and 90[Formula: see text] orientations of shear wave plane with respect to the build plane of printed block of Ti6Al4V. Correspondingly, the reduction in shear modulus from 48.46 ± 0.82 to 46.40 ± 0.88 GPa was obtained at these orientations. Such attenuation is rationalized based on the orientations of [Formula: see text] crystallographic variants within prior columnar [Formula: see text] grains in additively manufactured Ti6Al4V.

Hybrid zinc oxide nanoparticles for biophotonics.

A novel Zinc oxide (ZnO)-Hydrogel fluorescent colloidal semiconductor nanomaterials system is presented for potential bio-medical applications such as cell and tissue imaging. ZnO nanoparticles (NPs) synthesized using arc discharge technique has been conjugated to bio-compatible Poly N-isopropylacrylamide (PNIPAM) based hydrogel polymer matrix. The stability and fluorescence of ZnO nanoparticles are significantly enhanced using hydrogel colloidal dispersion. Photoluminescence spectroscopy indicates approximately 10 times enhancement in fluorescence in ZnO-Hydrogel colloidal system compared to ZnO-Water system, confirming the surface modification of ZnO nanoparticles by hydrogel polymer matrix. Femtosecond time resolved fluorescence measurement demonstrates that the fluorescence is due to the enhancement in absorption by the ZnO nanoparticles due to scattering by PNIPAM nanospheres.

Sub-wavelength lateral detection of tissue-approximating masses using an ultrasonic metamaterial lens.

Practically applied techniques for ultrasonic biomedical imaging employ delay-and-sum (DAS) beamforming which can resolve two objects down to 2.1λ within the acoustic Fresnel zone. Here, we demonstrate a phononic metamaterial lens (ML) for detection of laterally subwavelength object features in tissue-like phantoms beyond the phononic crystal evanescent zone and Fresnel zone of the emitter. The ML produces metamaterial collimation that spreads 8x less than the emitting transducer. Utilizing collimation, 3.6x greater lateral resolution beyond the Fresnel zone limit was achieved. Both hard objects and tissue approximating masses were examined in gelatin tissue phantoms near the Fresnel zone limit. Lateral dimensions and separation were resolved down to 0.50λ for hard objects, with tissue approximating masses slightly higher at 0.73λ. The work represents the application of a metamaterial for spatial characterization, and subwavelength resolution in a biosystem beyond the Fresnel zone limit.

Spatial Decomposition of a Broadband Pulse Caused by Strong Frequency Dispersion of Sound in Acoustic Metamaterial Superlattice.

An acoustic metamaterial superlattice is used for the spatial and spectral deconvolution of a broadband acoustic pulse into narrowband signals with different central frequencies. The operating frequency range is located on the second transmission band of the superlattice. The decomposition of the broadband pulse was achieved by the frequency-dependent refraction angle in the superlattice. The refracted angle within the acoustic superlattice was larger at higher operating frequency and verified by numerical calculated and experimental mapped sound fields between the layers. The spatial dispersion and the spectral decomposition of a broadband pulse were studied using lateral position-dependent frequency spectra experimentally with and without the superlattice structure along the direction of the propagating acoustic wave. In the absence of the superlattice, the acoustic propagation was influenced by the usual divergence of the beam, and the frequency spectrum was unaffected. The decomposition of the broadband wave in the superlattice's presence was measured by two-dimensional spatial mapping of the acoustic spectra along the superlattice's in-plane direction to characterize the propagation of the beam through the crystal. About 80% of the frequency range of the second transmission band showed exceptional performance on decomposition.

Thermally Tunable Dynamic and Static Elastic Properties of Hydrogel Due to Volumetric Phase Transition.

The temperature dependence of the mechanical properties of polyvinyl alcohol-based poly n-isopropyl acrylamide (PVA-PNIPAm) hydrogel was studied from the static and dynamic bulk modulus of the material. The effect of the temperature-induced volumetric phase transition on Young's Modulus, Poisson's ratio, and the density of PVA-PNIPAm was experimentally measured and compared with a non-thermo-responsive Alginate hydrogel as a reference. An increase in the temperature from 27.5 to 32 °C results in the conventional temperature-dependent de-swelling of the PVA-PNIPAm hydrogel volume of up to 70% at the lower critical solution temperature (LCST). However, with the increase in temperature, the PVA-PNIPAm hydrogel showed a drastic increase in Young's Modulus and density of PVA-PNIPAm and a corresponding decrease in the Poisson's ratio and the static bulk modulus around the LCST temperature. The dynamic bulk modulus of the PVA-PNIPAm hydrogel is highly frequency-dependent before the LCST and highly temperature-sensitive after the LCST. The dynamic elastic properties of the thermo-responsive PVA-PNIPAm hydrogel were compared and observed to be significantly different from the thermally insensitive Alginate hydrogel.

Enhanced Instantaneous Elastography in Tissues and Hard Materials Using Bulk Modulus and Density Determined Without Externally Applied Material Deformation.

Ultrasound is a continually developing technology that is broadly used for fast, non-destructive mechanical property detection of hard and soft materials in applications ranging from manufacturing to biomedical. In this study, a novel monostatic longitudinal ultrasonic pulsing elastography imaging method is introduced. The existing elastography methods require an acoustic radiational or dynamic compressive externally applied force to determine the effective bulk modulus or density. This new, passive M-mode imaging technique does not require an external stress and can be effectively used for both soft and hard materials. Strain map imaging and shear wave elastography are two current categories of M-mode imaging that show both relative and absolute elasticity information. The new technique is applied to hard materials and soft material tissue phantoms for demonstrating effective bulk modulus and effective density mapping. When compared with standard techniques, the effective parameters fall within 10% of standard characterization methods for both hard and soft materials. As neither the standard A-mode imaging technique nor the presented technique require an external applied force, the techniques are applied to composite heterostructures and the findings presented for comparison. The presented passive M-mode technique is found to have enhanced resolution over standard A-mode modalities.

Novel 2D Dynamic Elasticity Maps for Inspection of Anisotropic Properties in Fused Deposition Modeling Objects.

In this study, a novel ultrasonic non-destructive and non-invasive elastography method was introduced and demonstrated to evaluate the mechanical properties of fused deposition modeling 3D printed objects using two-dimensional dynamical elasticity mapping. Based on the recently investigated dynamic bulk modulus and effective density imaging technique, an angle-dependent dynamic shear modulus measurement was performed to extract the dynamic Young's modulus distribution of the FDM structures. The elastographic image analysis demonstrated the presence of anisotropic dynamic shear modulus and dynamic Young's modulus existing in the fused deposition modeling 3D printed objects. The non-destructive method also differentiated samples with high contrast property zones from that of low contrast property regions. The angle-dependent elasticity contrast behavior from the ultrasonic method was compared with conventional and static tensile tests characterization. A good correlation between the nondestructive technique and the tensile test measurements was observed.