Sulfated Alginate as an Effective Polymer Binder for High-Voltage LiNi0.5Mn1.5O4 Electrodes in Lithium-Ion Batteries.

Although the increasing demand for high-energy-density lithium-ion batteries (LIBs) has inspired extensive research on high-voltage cathode materials, such as LiNi0.5Mn1.5O4 (LNMO), their commercialization is hindered by problems associated with the decomposition of common carbonate solvent-based electrolytes at elevated voltages. To address these problems, we prepared high-voltage LNMO composite electrodes using five polymer binders (two sulfated and two nonsulfated alginate binders and a poly(vinylidene fluoride) conventional binder) and compared their electrochemical performances at ∼5 V vs Li/Li+. The effects of binder type on electrode performance were probed by analyzing cycled electrodes using soft/hard X-ray photoelectron spectroscopy and scanning transmission electron microscopy. The best-performing sulfated binder, sulfated alginate, uniformly covers the surface of LNMO and increased its affinity for the electrolyte. The electrolyte decomposition products generated in the initial charge-discharge cycle on the alginate-covered electrode participated in the formation of a protective passivation layer that suppressed further decomposition during subsequent cycles, resulting in enhanced cycling and rate performances. The results of this study provide a basis for the cost-effective and technically undemanding fabrication of high-energy-density LIBs.

Electronic detection of root canal constrictions.

The aim of this study was to investigate the possibility of detecting root canal constrictions by using an apex locator. Seventy impenetrable canals in extracted human teeth were used. Based on contact microradiographic findings, they were divided into three groups: group A (constricted within 3 mm of the radiographic apex, 23 canals), group B (nonconstricted within 3 mm of the radiographic apex, 28 canals), and group C (constricted more than 3-mm short of the radiographic apex, 19 canals). Electrical impedances at two different frequencies (8 kHz and 0.4 kHz), as well as the meter values of the Root ZX were recorded at the position where a file tip could reach. The impedance ratios (Z8kHZ:Z0.4kHz) and the meter values of the Root ZX showed a statistically significant difference between groups A and B. It was suggested that the Root ZX might be useful for detecting root canal constrictions.