Bidirectional Cascaded Superfluorescent Lasing in Air Enabled by Resonant Third Harmonic Photon Exchange from Nitrogen to Argon.

Cavity-free lasing in atmospheric air has stimulated intense research toward a fundamental understanding of underlying physical mechanisms. In this Letter, we identify a new mechanism-a third-harmonic photon mediated resonant energy transfer pathway leading to population inversion in argon via an initial three-photon excitation of nitrogen molecules irradiated by intense 261 nm pulses-that enables bidirectional two-color cascaded lasing in atmospheric air. By making pump-probe measurements, we conclusively show that such cascaded lasing results from superfluorescence rather than amplified spontaneous emission. Such cascaded lasing with the capability of producing bidirectional multicolor coherent pulses opens additional possibilities for remote sensing applications.

Progress in high-power continuous-wave quantum cascade lasers [Invited].

Multi-watt continuous-wave room temperature operation with efficiency exceeding 10% has been demonstrated for quantum cascade lasers essentially in the entire mid-wave and long-wave infrared spectral regions. Along with interband cascade lasers, these devices are the only room-temperature lasers that directly convert electrical power into mid- and long-infrared optical power. In this paper, we review the progress in high-power quantum cascade lasers made over the last 10 years. Specifically, an overview of the most important active region, waveguide, and thermal design techniques is presented, and various aspects of die packaging for high-power applications are discussed. Prospects of power scaling with lateral device dimensions for reaching optical power level in the range from 10 W to 20 W are also analyzed. Finally, coherent and spectral beam-combining techniques for very high-power infrared platforms are discussed.

Continuous wave operation of buried heterostructure 4.6 µm quantum cascade laser Y-junctions and tree arrays.

Room-temperature continuous-wave operation for buried heterostructure 4.6 µm quantum cascade laser Y-junctions and tree arrays, overgrown using hydride vapor phase epitaxy, has been demonstrated. Pulsed wall plug efficiency for the Y-junctions with bending radius of 5mm was measured to be very similar to that of single-emitter lasers from the same material, indicating low coupling losses. Comparison between model and experimental data showed that the in-phase mode was dominating for 10mm-long Y-junctions with 5 µm-wide 1mm-long stem and 5 µm-wide branches. Total optical power over 1.5 W was demonstrated for four-branch QCL tree array.

Multiwatt long wavelength quantum cascade lasers based on high strain composition with 70% injection efficiency.

A strain-balanced, AlInAs/InGaAs/InP quantum cascade laser structure, designed for light emission near 9 µm, was grown by molecular beam epitaxy. Laser devices were processed in buried heterostructure geometry. Maximum pulsed and continuous wave room temperature optical power of 4.5 and 2 W and wallplug efficiency of 16% and 10%, respectively, were demonstrated for a 3mm by 10 µm laser mounted epi-side down on an AlN/SiC composite submount. Pulsed laser characteristics were shown to be self-consistently described by a simple model based on rate equations using measured 70% injection efficiency for the upper laser level.

Tapered 4.7 µm quantum cascade lasers with highly strained active region composition delivering over 4.5 watts of continuous wave optical power.

A strain-balanced, Al0.7In0.22As/In0.72Ga0.28As/InP quantum cascade laser structure, designed for light emission at 4.7µm using the non-resonant extraction design approach, was grown by molecular beam epitaxy. Laser devices were processed in tapered buried heterostructure geometry and then mounted on AlN/SiC composite submounts using hard solder. A 10 mm long laser with 7.5µm-wide central section tapered up to 20µm at laser facets generated over 4.5W of single-ended CW/RT optical power at 283K. Maximum wallplug efficiency of 16.3% for this laser was reached at 4W level. Reliability of over 2,000h has been demonstrated for an air-cooled system delivering optical power of 3W in a collimated beam with overall system efficiency exceeding 10%.

λ~7.1 µm quantum cascade lasers with 19% wall-plug efficiency at room temperature.

Strain-balanced In0.6Ga0.4As/Al0.56In0.44As quantum cascade lasers emitting at a wavelength of 7.1 µm are reported. The active region is based on a three-phonon-resonance quantum design with a low voltage defect of 120 meV at injection resonance. A maximum wall-plug efficiency of 19% is demonstrated in pulsed mode at 293 K. Continuous-wave output power of 1.4 W and wall-plug efficiency of 10% are measured at the same temperature, as well as 1.2 W of average power in uncooled operation. A model for backfilling of the lower laser level which takes into account the number of subbands in the injector is presented and applied to determine the optimum value of the voltage defect to maximize wall-plug efficiency at room temperature, which is found to be ~100 meV, in good agreement with experimental results.

Activation energy study of electron transport in high performance short wavelengths quantum cascade lasers.

We present a method to study current paths through quantum cascade lasers (QCLs). The temperature dependence of the current is measured at a fixed voltage. At low temperatures we find activation energies that correspond to the energy difference between the injector ground state and the upper laser level. At higher temperatures additional paths with larger activation energies are found. Application of this method to high performance QCLs based on strained InGaAs/InAlAs quantum wells and barriers with different band-offsets allows us to identify individual parasitic current paths through the devices. The results give insight into the transport properties of quantum cascade lasers thus providing a useful tool for device optimization.

Standoff detection of explosive substances at distances of up to 150 m.

We report detection and identification of trace quantities of explosives at standoff distances up to 150 m with high sensitivity (signal-to-noise ratio of approximately 70) and high selectivity. The technique involves illuminating the target object with laser radiation at a wavelength that is strongly absorbed by the target. The resulting temperature rise is observed by remotely monitoring the increased blackbody radiation from the sample. An unambiguous determination of the target, TNT, in soil samples collected from an explosives test site in China Lake Naval Air Weapons Station is achieved through the use of a tunable CO(2) laser that scans over the absorption fingerprint of the target explosives. The theoretical analysis supports the observation and indicates that, with optimized detectors and data processing algorithms, the measurement capability can be improved significantly, permitting rapid standoff detection of explosives at distances approaching 1 km. The detection sensitivity varies as R(-2) and, thus, with the availability of high power, room-temperature, tunable mid-wave infrared and long-wave infrared quantum cascade lasers, this technology may play an important role in screening personnel and their belongings at short distances, such as in airports, for detecting and identifying explosives material residue on persons.

Optically multiplexed multi-gas detection using quantum cascade laser photoacoustic spectroscopy.

We report high-throughput, nondispersive optical multiplexing of laser beams using a scanning galvanometer. We have utilized this technique for multispecies trace-gas detection using multiple quantum cascade laser photoacoustic spectroscopy. We demonstrate switching from one laser to another in less than 1 s, a performance level needed for a comprehensive multispecies sensor, and a high signal-to-noise ratio detection of five gaseous components, NH(3), NO(2), dimethyl methyl phosphonate (DMMP, a simulant for nerve agents), acetone, and ethylene glycol, in a room air gas mixture containing approximately 3 ppb of NH(3), approximately 8 ppb of NO(2), approximately 20 ppb of DMMP, approximately 30 ppb of acetone, and approximately 40 ppb of ethylene glycol.

Sub-parts-per-billion level detection of dimethyl methyl phosphonate (DMMP) by quantum cascade laser photoacoustic spectroscopy.

The need for the detection of chemical warfare agents (CWAs) is no longer confined to battlefield environments because of at least one confirmed terrorist attack, the Tokyo Subway [Emerg. Infect. Dis. 5, 513 (1999)] in 1995, and a suspected, i.e., a false-alarm of a CWA in the Russell Senate Office Building [Washington Post, 9 February 2006, p. B01]. Therefore, detection of CWAs with high sensitivity and low false-alarm rates is considered an important priority for ensuring public safety. We report a minimum detection level for a CWA simulant, dimethyl methyl phosphonate (DMMP), of <0.5 ppb (parts in 10(9)) by use of a widely tunable external grating cavity quantum cascade laser and photoacoustic spectroscopy. With interferents present in Santa Monica, California street air, we demonstrate a false-alarm rate of 1:10(6) at a detection threshold of 1.6 ppb.

High-sensitivity detection of triacetone triperoxide (TATP) and its precursor acetone.

Triacetone triperoxide (C(9)H(18)O(6), molecular mass of 222.24 g/mol) (TATP) is a powerful explosive that is easy to synthesize using commonly available household chemicals, acetone, and hydrogen peroxide 1 2. Because of the simplicity of its synthesis, TATP is often the explosive of choice for terrorists, including suicide bombers. For providing safety to the population, early detection of TATP and isolation of such individuals are essential. We report unambiguous, high-sensitivity detection of TATP and its precursor, acetone, using room-temperature quantum cascade laser photoacoustic spectroscopy (QCL-PAS). The available sensitivity is such that TATP, carried on a person (at a nominal body temperature of 37 degrees C), should be detectable at some distance. The combination of demonstrated detection of TATP and acetone should be ideal for screening at airports and other public places for providing increased public safety.

Improved performance of quantum cascade lasers through a scalable, manufacturable epitaxial-side-down mounting process.

We report substantially improved performance of high-power quantum cascade lasers (QCLs) by using epitaxial-side-down mounting that provides superior heat dissipation properties. We used aluminum nitride as the heatsink material and gold-tin eutectic solder. We have obtained continuous wave power output of 450 mW at 20 degrees C from mid-IR QCLs. The improved thermal management achieved with epitaxial-side-down mounting combined with a highly manufacturable and scalable assembly process should permit incorporation of mid-IR QCLs in reliable instrumentation.

Sub-parts-per-billion level detection of NO2 using room-temperature quantum cascade lasers.

We report the sub-parts-per-billion-level detection of NO2 using tunable laser-based photoacoustic spectroscopy where the laser radiation is obtained from a room-temperature continuous-wave high-power quantum cascade laser operating in an external grating cavity configuration. The continuously tunable external grating cavity quantum cascade laser produces maximum single-frequency output of approximately 300 mW tunable over approximately 350 nm centered at 6.25 microm. We demonstrate minimum detection level of approximately 0.5 parts per billion of NO2 in the presence of humidified air.

High-sensitivity detection of TNT.

We report high-sensitivity detection of 2,4,6-trinitrotoluene (TNT) by using laser photoacoustic spectroscopy where the laser radiation is obtained from a continuous-wave room temperature high-power quantum cascade laser in an external grating cavity geometry. The external grating cavity quantum cascade laser is continuously tunable over approximately 400 nm around 7.3 microm and produces a maximum continuous-wave power of approximately 200 mW. The IR spectroscopic signature of TNT is sufficiently different from that of nitroglycerine so that unambiguous detection of TNT without false positives from traces of nitroglycerine is possible. We also report the results of spectroscopy of acetylene in the 7.3-microm region to demonstrate continuous tunability of the IR source.

Fiber-amplifier-enhanced photoacoustic spectroscopy with near-infrared tunable diode lasers.

A new approach to wavelength-modulation photoacoustic spectroscopy is reported, which incorporates diode lasers in the near infrared and optical fiber amplifiers to enhance sensitivity. We demonstrate the technique with ammonia detection, yielding a sensitivity limit less than 6 parts in 10(9), by interrogating a transition near 1532 nm with 500 mW of output power from the fiber amplifier, an optical pathlength of 18.4 cm, and an integration time constant of 10 s. This sensitivity is 15 times better than in prior published results for detecting ammonia with near-infrared diode lasers. The normalized minimum detectable fractional optical density, alphaminl, is 1.8 x 10(-8); the minimum detectable absorption coefficient, alphamin, is 9.5 x 10(-10) cm(-1); and the minimum detectable absorption coefficient normalized by power and bandwidth is 1.5 x 10(-9) W cm(-1)/square root Hz. These measurements represent what we believe to be the first use of fiber amplifiers to enhance photoacoustic spectroscopy, and this technique is applicable to all other species that fall within the gain curves of optical fiber amplifiers.