Atomically Dispersed CoN3 C1 -TeN1 C3 Diatomic Sites Anchored in N-Doped Carbon as Efficient Bifunctional Catalyst for Synergistic Electrocatalytic Hydrogen Evolution and Oxygen Reduction.

A encapsulation-adsorption-pyrolysis strategy for the construction of atomically dispersed Co-Te diatomic sites (DASs) that are anchored in N-doped carbon is reported as an efficient bifunctional catalyst for electrocatalytic hydrogen evolution reaction (HER) and oxygen reduction reaction (ORR). The as-constructed catalyst shows the stable CoN3 C1 -TeN1 C3 coordination structure before and after HER and ORR. The *OOH/*H intermediate species are captured by in situ Raman and in situ attenuated total reflectance-surface enhanced infrared absorption spectroscopy, indicating that the reactant O2 /H2 O molecule has a strong interaction with the Co site, revealing that Coδ+ is an effective active site. Theoretical calculations show that the Coδ+ has adsorption-activation function and the neighboring Teδ+ acts as an electron donor adjusting the electronic structure of Coδ+ , promoting the dissociation of H2 O molecules and the adsorption of H and oxygen-containing intermediates in HER and ORR. In the meanwhile, the nearest C atom around Co also profoundly affects the adsorption of H atoms. This results in the weakening of the OH adsorption and enhancement of H adsorption, as well as the more stable water molecule dissociation transition state, thus significantly boosting ORR and HER performance.

Method of fiber transfer delay measurement based on phase quantization and delay synthesis.

A novel method, to the best of our knowledge, of fiber transfer delay (FTD) measurement based on phase quantization and delay synthesis is proposed and demonstrated. By detecting the differential phase shifts of a set of frequency-multiplied RF signals transmission through the fiber link with and without the FTD under the test, the ${2}\pi $2π phase ambiguity problem can be solved. To avoid the phase quantization error near the digital quantization boundary, a self-check and error-correction method is proposed so as to greatly improve the reliability of measurement. In the experiment, the measurement repeatability around 0.018 ps within a period of 80 s is achieved for a back-to-back fiber link, and a test resolution of 0.03 ps is proved with a motorized tunable delay line. The system is available for measurement of a large FTD range up to 100 µs with no dead zone.