RESUMO
The physics of the superconducting state in two-dimensional (2D) electron systems is relevant to understanding the high-transition-temperature copper oxide superconductors and for the development of future superconductors based on interface electron systems. But it is not yet understood how fundamental superconducting parameters, such as the spectral density of states, change when these superconducting electron systems are depleted of charge carriers. Here we use tunnel spectroscopy with planar junctions to measure the behaviour of the electronic spectral density of states as a function of carrier density, clarifying this issue experimentally. We chose the conducting LaAlO3-SrTiO3 interface as the 2D superconductor, because this electron system can be tuned continuously with an electric gate field. We observed an energy gap of the order of 40 microelectronvolts in the density of states, whose shape is well described by the Bardeen-Cooper-Schrieffer superconducting gap function. In contrast to the dome-shaped dependence of the critical temperature, the gap increases with charge carrier depletion in both the underdoped region and the overdoped region. These results are analogous to the pseudogap behaviour of the high-transition-temperature copper oxide superconductors and imply that the smooth continuation of the superconducting gap into pseudogap-like behaviour could be a general property of 2D superconductivity.
RESUMO
The crystallization kinetics of amorphous 3 and 8 mol% yttria stabilized zirconia (3YSZ and 8YSZ) thin films grown by pulsed laser deposition (PLD), spray pyrolysis and dc-magnetron sputtering are explored. The deposited films were heat treated up to 1000 °C ex situ and in situ in an X-ray diffractometer. A minimum temperature of 275 °C was determined at which as-deposited amorphous PLD grown 3YSZ films fully crystallize within five hours. Above 325 °C these films transform nearly instantaneously with a high degree of micro-strain when crystallized below 500 °C. In these films the t'' phase crystallizes which transforms at T > 600 °C to the t' phase upon relaxation of the micro-strain. Furthermore, the crystallization of 8YSZ thin films grown by PLD, spray pyrolysis and dc-sputtering are characterized by in situ XRD measurements. At a constant heating rate of 2.4 K min(-1) crystallization is accomplished after reaching 800 °C, while PLD grown thin films were completely crystallized already at ca. 300 °C.
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Strain is a leading candidate for controlling magnetoelectric coupling in multiferroics. Here, we use x-ray diffraction to study the coupling between magnetic order and structural distortion in epitaxial films of the orthorhombic (o-) perovskite LuMnO(3). An antiferromagnetic spin canting in the E-type magnetic structure is shown to be related to the ferroelectrically induced structural distortion and to a change in the magnetic propagation vector. By comparing films of different orientations and thicknesses, these quantities are found to be controlled by b-axis strain. It is shown that compressive strain destabilizes the commensurate E-type structure and reduces its accompanying ferroelectric distortion.
RESUMO
We present fabrication and characterization of high-resolution and nearly amorphous Mo1 - xNx transmission gratings and their use as masks for extreme ultraviolet (EUV) interference lithography. During sputter deposition of Mo, nitrogen is incorporated into the film by addition of N2 to the Ar sputter gas, leading to suppression of Mo grain growth and resulting in smooth and homogeneous thin films with a negligible grain size. The obtained Mo0.8N0.2 thin films, as determined by x-ray photoelectron spectroscopy, are characterized to be nearly amorphous using x-ray diffraction. We demonstrate a greatly reduced Mo0.8N0.2 grating line edge roughness compared with pure Mo grating structures after e-beam lithography and plasma dry etching. The amorphous Mo0.8N0.2 thin films retain, to a large extent, the benefits of Mo as a phase grating material for EUV wavelengths, providing great advantages for fabrication of highly efficient diffraction gratings with extremely low roughness. Using these grating masks, well-resolved dense lines down to 8 nm half-pitch are fabricated with EUV interference lithography.
RESUMO
Single phase and strained LuMnO(3) thin films are discovered to display coexisting ferromagnetic and antiferromagnetic orders. A large moment ferromagnetism (≈1µ(B)), which is absent in bulk samples, is shown to display a magnetic moment distribution that is peaked at the highly strained substrate-film interface. We further show that the strain-induced ferromagnetism and the antiferromagnetic order are coupled via an exchange field, therefore demonstrating strained rare-earth manganite thin films as promising candidate systems for new multifunctional devices.
RESUMO
With ellipsometry, x-ray diffraction, and resistance measurements we investigated the electric-field effect on the confined electrons at the LaAlO3/SrTiO3 interface. We obtained evidence that the localization of the electrons at negative gate voltage is induced, or at least enhanced, by a polar phase transition in SrTiO3 which strongly reduces the lattice polarizability and the subsequent screening. In particular, we show that the charge localization and the polar order of SrTiO3 both develop below â¼50 K and exhibit similar, unipolar hysteresis loops as a function of the gate voltage.
RESUMO
The evolution of the atomic structure of LaAlO_{3} grown on SrTiO_{3} was investigated using surface x-ray diffraction in conjunction with model-independent, phase-retrieval algorithms between two and five monolayers film thickness. A depolarizing buckling is observed between cation and oxygen positions in response to the electric field of polar LaAlO_{3}, which decreases with increasing film thickness. We explain this in terms of competition between elastic strain energy, electrostatic energy, and electronic reconstructions. Based on these structures, the threshold for formation of a two-dimensional electron system at a film thickness of 4 monolayers is quantitatively explained. The findings are also qualitatively reproduced by density-functional-theory calculations.
Assuntos
Alumínio/química , Lantânio/química , Óxidos/química , Estrôncio/química , Titânio/química , Difração de Raios XRESUMO
Li x La y Sr z MnO3 thin films of various compositions (x,y,z) have been grown using pulsed laser deposition. The compositions of the films have been studied as a function of deposition temperature, target-to-substrate distance and deposition pressure with respect to different cation ratios of the targets by inductively coupled plasma mass spectrometry. When growing multi-elemental oxide thin films containing lithium (with its large mass difference to other elements), lithium loss is most probably inevitable. But the desired thin film composition can be achieved by selecting specific growth conditions and different target compositions. The experiments also elucidate some of the mechanisms behind the incongruent lithium transfer from the targets to thin films.
RESUMO
With infrared ellipsometry and transport measurements we investigated the electrons at the interface between LaAlO3 and SrTiO3. We obtained a sheet carrier concentration of N(s) approximately = 5-9x10(13) cm(-2), an effective mass of m*=3.2+/-0.4m(e), and a strongly frequency dependent mobility. The latter are similar as in bulk SrTi(1-x)Nb(x)O3 and therefore suggestive of polaronic correlations. We also determined the vertical concentration profile which has a strongly asymmetric shape with a rapid initial decay over the first 2 nm and a pronounced tail that extends to about 11 nm.
RESUMO
Experimental and theoretical investigations have demonstrated that a quasi-two-dimensional electron gas (q-2DEG) can form at the interface between two insulators: non-polar SrTiO3 and polar LaTiO3 (ref. 2), LaAlO3 (refs 3-5), KTaO3 (ref. 7) or LaVO3 (ref. 6). Electronically, the situation is analogous to the q-2DEGs formed in semiconductor heterostructures by modulation doping. LaAlO3/SrTiO3 heterostructures have recently been shown to exhibit a hysteretic electric-field-induced metal-insulator quantum phase transition for LaAlO3 thicknesses of 3 unit cells. Here, we report the creation and erasure of nanoscale conducting regions at the interface between two insulating oxides, LaAlO3 and SrTiO3. Using voltages applied by a conducting atomic force microscope (AFM) probe, the buried LaAlO3/SrTiO3 interface is locally and reversibly switched between insulating and conducting states. Persistent field effects are observed using the AFM probe as a gate. Patterning of conducting lines with widths of approximately 3 nm, as well as arrays of conducting islands with densities >10(14) inch(-2), is demonstrated. The patterned structures are stable for >24 h at room temperature.
RESUMO
UNLABELLED: Negative phototaxis (NP) was used to evaluate the recovery of vision in albino axolotl larvae with one eye discarded and the other transplanted either to the orbit (orthoclops) or to the top of the head (cyclops). NP was assessed at approximately 1, 2 and 3 months postoperatively, using an automated, infrared monitor. Some 88% of the orthoclopes and 64% of the cyclopes recovered NP. However, among the cyclopes that did recover, the quantitative aspects of NP were virtually the same as those of the orthoclopes. That the cyclopean eye can regenerate retinotectal pathways was established by anterograde tracing of horseradish peroxidase (HRP). But where previously uninjured animals transported HRP to the contralateral tectum, both the cyclopes and the orthoclopes distributed the enzyme to the left and right tectal halves. Heavy deposits of HRP were found in the tecta of some animals that lacked NP. To find out if an optic tectum is actually required for NP, a series of ablation experiments were performed, using Ambystoma punctatum larvae. Tectectomy had the same effect on NP as bilaterally extirpating the eyes or intracranially severing both optic nerves, i.e. removing the tectum abolished NP. THE RESULTS: (1) confirm the efficacy of the ectopic eye in the cyclops preparation; (2) show that the ectopic eye can regenerate retinotectal pathways; (3) indicate that retinotectal contact is a necessary but insufficient condition for NP.
Assuntos
Ambystoma/fisiologia , Aprendizagem da Esquiva/fisiologia , Luz , Retina/fisiologia , Colículos Superiores/fisiologia , Ambystoma/crescimento & desenvolvimento , Ambystoma/metabolismo , Animais , Transporte Biológico , Olho/transplante , Enucleação Ocular , Peroxidase do Rábano Silvestre/metabolismo , Larva , Regeneração Nervosa , Retina/metabolismo , Colículos Superiores/metabolismoRESUMO
Salamander larvae typically adapt their dermal melanophores to achieve camouflage, and it has been known for some time that removal of the eyes abolishes the response. Here we survey the contribution of the optic system to the bright and dark camouflage reactions and report that: the stimulus depends on an interaction between the direct and reflected light; an eye mounted atop the head and oriented vertically tended not to support camouflage, even though the animal responded to visual cues and learned a vision-dependent task; deviating the transplanted eye off the vertical axis enhanced the recovery of camouflage reactions; amputating or reorienting the telencephalon, epithalamus, pretectum or tectum did not abolish either camouflage reaction whereas lesions of the ventral optic pathway blocked brightening; transection near the midbrain-hindbrain junction--well posterior to known optic terminals--retarded the dark reaction; when the latter lesion was combined with disconnection of the telencephalon and epithalamus, contrary to predictions from the lesions executed separately, the animals lost the bright reaction; the hypophysis is necessary for darkening, but the organ supported this reaction even though detached, displaced or reoriented; and the pineal body was not essential for the grosser aspects of camouflage in Ambystoma larvae but may play an adjunctive role in fine tuning.
Assuntos
Ambystoma/fisiologia , Encéfalo/fisiologia , Olho/transplante , Pigmentação da Pele , Animais , Aprendizagem da Esquiva/fisiologia , Encéfalo/anatomia & histologia , Larva/fisiologia , Iluminação , Melanóforos/fisiologia , Microcirurgia , Nervo Óptico/fisiologia , Hipófise/fisiologia , Colículos Superiores/fisiologia , Vias Visuais/fisiologiaRESUMO
Amputation of the rostral half of the cerebrum induces a compulsion-like reaction in larval Ambystoma punctatum towards Enchytraeus protected within glass vials. Normal and craniotomized larvae are visually attracted to worm-containing vials, as revealed by time-lapse video taping but, after several unsuccessful attempts to get the prey, habituate and depart. The video tapes revealed that anteriorly decerebrated animals spent as much as 100 of 120 minutes at the worm-containing vial, repeatedly but futilely attacking the glass. The data indicate that the telencephalon plays an active negative role in the salamander larva's visually guided behavior.
Assuntos
Ambystoma/fisiologia , Estado de Descerebração , Habituação Psicofisiológica/fisiologia , Visão Ocular/fisiologia , Animais , Larva/fisiologia , Fenômenos Fisiológicos Oculares , Nervo Óptico/fisiologia , Gravação de VideoteipeRESUMO
In an Ambystoma larva with both natural eyes removed and one eye grafted atop the head (Cyclops preparation), vision-dependent behavior usually recovers from the enucleation inherent in the operation, but the optically activated skin blanching reaction reappears in a very small number of instances. In the present studies, while the latter trend continued for the conventional Cyclops preparation, tectectomy concurrent with the ectopic eye transplantation resulted in a several-fold increase in the recovery of blanching competency. Some 60 percent of the tectectomized Cyclops animals exhibited the same Hogben-Slome pigmentation indices as larvae with one natural eye intact (controls). As measured planimetrically with an image analyzer, the pigment spots (melanosome containing portions of dermal melanocytes) contracted to the same extent in the blanch-competent Cyclops animals as in controls with a single natural eye.
Assuntos
Ambystoma/fisiologia , Regeneração Nervosa/fisiologia , Nervo Óptico/fisiologia , Privação Sensorial/fisiologia , Colículos Superiores/fisiologia , Animais , Mapeamento Encefálico , Melanócitos/fisiologia , Pigmentação da Pele/fisiologia , Visão Ocular/fisiologia , Vias Visuais/fisiologiaRESUMO
A wide variety of visual functions show increases attributable to binocularity, and the question pursued here was whether a second eye enhances the visually stimulated skin blanching reaction of the larval salamander. Dermal melanin spots (produced by the aggregations of melanosomes within dermal melanophores and which contract or expand to lighten or darken the skin) were measured in eyeless (controls), one-eyed and two-eyed Ambystoma punctatum larvae after chronic adaptation of the subjects to a white background (i.e., stimulus conditions for maximum blanching). The eyeless subjects showed no blanching (thus remained dark) in white cups, and they exhibited melanin spots 7 or 8 times the size of those of the other two groups. All one-eyed or two-eyed subjects exhibited blanching reactions; planometric comparison revealed a significantly larger melanin spot area for one-eyed than for two-eyed animals; i.e., the binocular condition permitted greater contraction of the pigment spots than did the monocular condition. Analytical data compared favorably with independently ascertained pigmentation indices. The results indicate that a second eye quantitatively elevates the blanching maximum of a larval salamander.
Assuntos
Ambystoma/fisiologia , Percepção de Cores/fisiologia , Dominância Cerebral/fisiologia , Fenômenos Fisiológicos Oculares , Privação Sensorial/fisiologia , Pigmentação da Pele/fisiologia , Visão Binocular/fisiologia , Visão Monocular/fisiologia , Animais , Larva , Melaninas/metabolismoRESUMO
In this investigation, we describe two precise tests of visual function that integrate quasinatural situations with time-lapse video recording and infrared computerized monitoring of activity to assess movement detection and phototaxic tendencies, respectively. Four groups of larvae from A. punctatum, A. tigrinum, A. mexicanum, and a mutant albino axolotl were tested in an alley containing light and dark halves and lined with infrared sensors to monitor their phototaxic response. A. punctatum showed no phototaxic tendency, while the other three groups displayed a strong negative phototaxic response. Enucleation of the eyes in mutant albinos eliminated the negative phototaxis. Visual detection of motion was tested by videorecording the behavior of A. punctatum, A. mexicanum, and the mutant albino axolotl larvae while they explored a large bowl with 6 small vials on the perimeter, one of which contained white worms. A. punctatum rapidly approached the worm vial and engaged in intense predatory behavior. A. mexicanum responded to the presence of worms very slowly and rapidly lost interest. Albino axolotls displayed no visual recognition of the worms. The results indicate that visual function can be precisely determined in larval salamanders utilizing behavioral measures consistent with the animal's natural tendencies.
Assuntos
Comportamento Animal/fisiologia , Percepção de Movimento/fisiologia , Ambystoma , Ambystoma mexicanum , Animais , Enucleação Ocular , Larva , Luz , Comportamento Predatório/fisiologia , Especificidade da Espécie , Gravação de VideoteipeRESUMO
Free-moving mice from the high-alcohol preference C57BL/6J strain and low-preference DBA/2J strain were slowly fed [2-14C]ethanol intragastrically until anesthesia was achieved. Behavior was monitored in a Plexiglas metabolic chamber while 14CO2 was simultaneously trapped to determine the rate of ethanol metabolism. Average time to the loss of the righting reflex in the DBA/2J was 21.9 min and 27.9 min for the C57BL/6J strain (p less than 0.005). Elimination of 14CO2 was slightly higher (n.s.) in the DBA/2J strain for the entire monitoring period. Infusion of ethanol via the tail vein yielded identical results indicating that the slower elimination rate in the C57BL/6J strain could not be the result of slower absorption across the gut wall. Infusion via the tail vein with radioactive sodium bicarbonate indicated that the DBA/2J strain has a higher rate of CO2 expiration (n.s.). Consequently, the higher rate of 14CO2 expiration from ethanol oxidation may not reflect a higher rate of metabolism. These results are discussed in terms of the apparent differences between these strains in neural sensitivity to ethanol.
Assuntos
Consumo de Bebidas Alcoólicas , Comportamento Animal , Etanol/metabolismo , Animais , Dióxido de Carbono/fisiologia , Masculino , Camundongos , Camundongos Endogâmicos C57BL , Camundongos Endogâmicos DBA , RespiraçãoRESUMO
Mice from the high-ethanol preferring C57BL strain and low-ethanol preferring DBA strain were tested for their preference for butanediols. The C57BL strain showed a significantly higher preference for a 10% (v/v) solution of 1,3-butanediol than the DBA strain. The C57BL strain also showed a significantly greater consumption of 1,2- and 2,3-butanediol, but the separation between strains was much smaller than with 1,3-butanediol. Both strains uniformly avoided 1,4-butanediol. Tolerance for 1,3-butanediol was tested in an open-field monitor at 3 doses. At the lowest dose the DBA strain was hyperactive and the C57BL were unaffected. At the highest dose both strains were equally depressed. The specific activity of NAD reduction on incubation of liver extracts with 1,3-butanediol and ethanol as substrates was higher with both compounds in extracts from the C57BL strain.
Assuntos
Butileno Glicóis/farmacologia , Fígado/metabolismo , Atividade Motora/efeitos dos fármacos , NAD/metabolismo , Consumo de Bebidas Alcoólicas , Animais , Comportamento de Escolha/efeitos dos fármacos , Masculino , Camundongos , Camundongos Endogâmicos C57BL , Camundongos Endogâmicos DBA , Oxirredução , Especificidade da EspécieRESUMO
In vitro effects of ethanol on calcium taken up by synaptosomes were examined in two strains of mice, C57BL and DBA, that exhibit marked differences in alcohol sensitivity and preference. There were no significant strain differences in basal or depolarization-dependent synaptosomal calcium levels. Ethanol did not reduce the basal calcium level but instead reduced depolarization-dependent calcium levels with the same potency in both strains. These results do not support a role for changes of calcium levels as the basis for differences in ethanol sensitivity in these mouse strains.
Assuntos
Encéfalo/efeitos dos fármacos , Cálcio/metabolismo , Etanol/farmacologia , Animais , Potenciais da Membrana , Camundongos , Camundongos Endogâmicos C57BL , Camundongos Endogâmicos DBA , Especificidade da Espécie , Sinaptossomos/metabolismoRESUMO
Expired ethanol and acetaldehyde were measured after an oral injection of ethanol in C57BL/6J and DBA/2J mouse strains by a combination of several techniques in a sequence involving a method for trapping expired radioactive compounds, separation of compounds by gas chromatography, isolation of radioactive ethanol and acetaldehyde, and their quantitative analysis by liquid scintillation spectrophotometry. With the specific activities used in evaluation of the technique (0.1 Ci/mole, acetaldehyde; 1.1 Ci/mol, ethanol) the lower limit of sensitivity using 500 microliters from a 10 ml trap is 955 pmoles for acetaldehyde and 101 pmoles for ethanol. However, in the animal experiments, injected ethanol has a specific activity of 1.1 Ci/mol which would make the specific activity of expired metabolically formed acetaldehyde the same. This results in a lower limit of sensitivity for acetaldehyde of 80 pmoles. The two strains were monitored for 80 min following an oral injection of 3.8 g/Kg of (2-14C) ethanol. Comparing the two strains on the expiration of each compound the curves were identical.