1.
Angew Chem Int Ed Engl
; 61(18): e202200305, 2022 Apr 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35212128
RESUMO
Hydrocarbon-soluble ß-diketiminato phenylcalcium derivatives, which display various modes of Ca-µ2 -Ph-Ca bridging, are accessible from reactions of Ph2 Hg and [(BDI)CaH]2 . Although the resultant compounds are inert toward the C-H bonds of benzene, they yield selective and uncatalyzed biaryl formation when reacted with readily available aryl bromides.