Multiscale assessment of artificial aging treatment of polysaccharides from tonewood species.

In the acoustics of musical instruments with a resonator body, the aging of the wood leads to the improvement of the acoustic properties due to increasing the crystallinity of wood. This phenomenon could be explained by the fact that wood is a complex product based on three-dimensional polymer chains of carbohydrates, its aging being closely related to covalent cross-linking and scission of polymer chains. The aim of this study was to evaluate at a multiscale the changes produced artificial aging of tone wood by measuring the acoustic, mechanical and chemical parameters. The spruce and maple wood samples were investigated before and after exposure to ultraviolet (UV) radiation, through the tensile test, the time-of-flight method (TOF), the analysis of the wood color and the determination of the chemical fingerprint through Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The obtained results showed that the effects of artificial aging are manifested at the chemical level where the crystallinity increases up to the acoustic level, depending on the wood species and their quality class. These results are relevant for musical instrument manufacturers to find treatments that lead to superior acoustic properties.

Analysis of the Anisotropy of Sound Propagation Velocity in Thin Wooden Plates Using Lamb Waves.

The objective of the study was to analyze the influence of coating treatments on sound propagation speeds in thin boards, along the longitudinal and radial directions of resonance wood. The samples studied were thin boards made of spruce and maple wood with dimensions of 240 mm × 80 mm × 4 mm (length × width × thickness) subjected to different coating treatments (oil-based varnish and alcohol varnish) as well as unvarnished samples, exposed to radiation UV, and specimens treated in the saline fog. The test method consisted of evaluating the propagation speeds of Lamb waves applied to thin plates, according to a semicircular test model, so that the results highlighted both the acoustic response in the longitudinal and radial directions as well as the variation in the anisotropy of the samples with the change in the sound propagation direction relative to wood fibers. Based on the statistical analysis, sound propagation speed profiles were obtained in each of the 38 directions analyzed for all wood samples. The results highlighted that the oil-based varnish led to a decrease in the speed of propagation in the radial direction, compared to the alcoholic varnish, whose major effect was in the longitudinal direction, on the spruce wood. On maple wood, increasing the number of varnish layers, regardless of the type of varnish, led to a decrease in the anisotropy ratio between the longitudinal and radial directions.

Aging of Wood for Musical Instruments: Analysis of Changes in Color, Surface Morphology, Chemical, and Physical-Acoustical Properties during UV and Thermal Exposure.

The acoustic features of old resonance wood in violins exhibit a superior quality when compared to those from new resonance wood. This study focuses on an assessment of the sound quality of two types of wood for musical instruments, spruce and maple (class A and D), before and after aging via thermal and UV exposure. The samples were characterized before and after UV aging in terms of color change (using a Chroma meter), surface morphology (using a MarSurf XT20 instrument), chemical changes (monitored by FTIR spectroscopy), and sound propagation speed (using an ultrasound device). After UV treatment, the wavier surface increased the area of exposure and degradation. Also, the color changes were found to be more accentuated in the case of spruce compared to sycamore maple. The FTIR results indicated more advanced aging processes for spruce when compared to maple under the same experimental conditions. This difference resulted mostly from the increased formation of carbonyl-containing chromophores via oxidative processes in spruce rather than in maple, which is in agreement with the color change findings. Exposure of both species to thermal and UV radiation led to an increase in sound propagation speed, both longitudinally and radially, and to a greater extent in wood quality class A when compared to quality class D.

Influence of the Grain Orientation of Wood upon Its Sound Absorption Properties.

The purpose of the study was to analyze the influence of the quality class and the orthotropy of wood upon the sound absorption coefficient, the reflection and the impedance ratio of two species widely used for stringed musical instruments, namely spruce (Picea abies L. Karst) and maple (Acer pseudoplatanus L.). An impedance tube for the frequency range 100-6400 Hz was used in these experimental determinations. Knowing the influence of porosity and tortuosity on the acoustic absorption, these properties were also determined, as well as the sound reduction coefficient and the maximum values of the acoustic absorption coefficients in relation to frequency. The main results highlighted the differences between the anatomical quality class of the wood within each species, but also concerning the sound direction relative to the three main sections of wood, as an orthotropic material. The article highlights the acoustic performance parameters related to the frequency of the wooden material and its relationship to density, porosity and quality class. The results represent useful information for musical instruments manufacturers and more.

Complementary Methods for the Assessment of the Porosity of Laser Additive-Manufactured Titanium Alloy.

The method of making parts through additive manufacturing (AM) is becoming more and more widespread due to the possibility of the direct manufacturing of components with complex geometries. However, the technology's capacity is limited by the appearance of micro-cracks/discontinuities during the layer-by-layer thermal process. The ultrasonic (US) method is often applied to detect and estimate the location and size of discontinuities in the metallic parts obtained by AM as well as to identify local deterioration in structures. The Ti6Al4V (Ti64) alloy prepared by AM needed to acquire a high-quality densification if remarkable mechanical properties were to be pursued. Ultrasonic instruments employ a different type of scanning for the studied samples, resulting in extremely detailed images comparable to X-rays. Automated non-destructive testing with special algorithms is widely used in the industry today. In general, this means that there is a trend towards automation and data sharing in various technological and production sectors, including the use of intelligent systems at the initial stage of production that can exclude defective construction materials, prevent the spread of defective products, and identify the causes of certain instances of damage. Placing the non-destructive testing on a completely new basis will create the possibility for a broader analysis of the primary data and thus will contribute to the improvement of both inspection reliability and consistency of the results. The paper aims to present the C-scan method, using ultrasonic images in amplitude or time-of-flight to emphasize discontinuities of Ti64 samples realized by laser powder-bed fusion (L-PBF) technology. The analysis of US maps offers the possibility of information correlation, mainly as to flaws in certain areas, as well as distribution of a specific flaw in the volume of the sample (flaws and pores). Final users can import C-scan results as ASCII files for further processing and comparison with other methods of analysis (e.g., non-linear elastic wave spectroscopy (NEWS), multi-frequency eddy current, and computer tomography), leading to specific results. The precision of the flight time measurement ensures the possibility of estimating the types of discontinuities, including volumetric ones, offering immediate results of the inspection. In situ monitoring allows the detection, characterization, and prediction of defects, which is suitable for robotics. Detailing the level of discontinuities at a certain location is extremely valuable for making maintenance and management decisions.

Prediction of the Damage Effect on Fiberglass-Reinforced Polymer Matrix Composites for Wind Turbine Blades.

The structure of wind turbine blades (WTBs) is characterized by complex geometry and materials that must resist various loading over a long period. Because of the components' exposure to highly aggressive environmental conditions, the blade material suffers cracks, delamination, or even ruptures. The prediction of the damage effects on the mechanical behavior of WTBs, using finite element analysis, is very useful for design optimization, manufacturing processes, and for monitoring the health integrity of WTBs. This paper focuses on the sensitivity analysis of the effects of the delamination degree of fiberglass-reinforced polymer composites in the structure of wind turbine blades. Using finite element analysis, the composite was modeled as a laminated structure with five plies (0/45/90/45/0) and investigated regarding the stress states around the damaged areas. Thus, the normal and shear stresses corresponding to each element of delaminated areas were extracted from each ply of the composites. It was observed that the maximum values of normal and shear stresses occurred in relation to the orientation of the composite layer. Tensile stresses were developed along the WTB with maximum values in the upper and lower plies (Ply 1 and Ply 5), while the maximum tensile stresses were reached in the perpendicular direction (on the thickness of the composite), in the median area of the thickness, compared to the outer layers where compression stresses were obtained. Taking into account the delamination cases, there was a sinuous-type fluctuation of the shear stress distribution in relation to the thickness of the composite and the orientation of the layer.

Mechanical and Acoustic Properties of Alloys Used for Musical Instruments.

Music should be integrated into our daily activities due to its great effects on human holistic health, through its characteristics of melody, rhythm and harmony. Music orchestras use different instruments, with strings, bow, percussion, wind, keyboards, etc. Musical triangles, although not so well known by the general public, are appreciated for their crystalline and percussive sound. Even if it is a seemingly simple instrument being made of a bent metal bar, the problem of the dynamics of the musical triangle is complex. The novelty of the paper consists in the ways of investigating the elastic and dynamic properties of the two types of materials used for musical triangles. Thus, to determine the mechanical properties, samples of material from the two types of triangles were obtained and tested by the tensile test. The validation of the results was carried out by means of another method, based on the modal analysis of a ternary system; by applying the intrinsic transfer matrix, the difference between the obtained values was less than 5%. As the two materials behaved differently at rupture, one having a ductile character and the other brittle, the morphology of the fracture surface and the elementary chemical composition were investigated by scanning electron microscopy (SEM) and analysis by X-ray spectroscopy with dispersion energy (EDX). The results were further transferred to the finite element modal analysis in order to obtain the frequency spectrum and vibration modes of the musical triangles. The modal analysis indicated that the first eigenfrequency differs by about 5.17% from one material to another. The first mode of vibration takes place in the plane of the triangle (transverse mode), at a frequency of 156 Hz and the second mode at 162 Hz, which occurs due to vibrations of the free sides of the triangle outside the plane, called the torsion mode. The highest dominant frequency of 1876 Hz and the sound speed of 5089 m/s were recorded for the aluminum sample with the ductile fracture in comparison with the dominant frequency of 1637 Hz and the sound speed of 4889 m/s in the case of the stainless steel sample, characterized by brittle fracture.

Multi-Criteria Evaluation of the Failure of CFRP Laminates for Frames in the Automotive Industry.

Methods to predict the fracture of thin carbon fibre-reinforced polymers (CFRPs) under load are of great interest in the automotive industry. The manufacturing of composites involves a high risk of defect occurrence, and the identification of those that lead to failure increases the functional reliability and decreases costs. The performance of CFRPs can be significantly reduced in assembled structures containing stress concentrators. This paper presents a hybrid experimental-numerical method based on the Tsai-Hill criterion for behavior of thin CFRPs at complex loadings that can emphasize the threshold of stress by tracing the σ-τ envelope. Modified butterfly samples were made for shearing, traction, or shearing-with-traction tests in the weakened section by changing the angle of force application α. ANSYS simulations were used to determine the zones of maximum stress concentration. For thin CFRP samples tested with stacking sequences [0]8 and [(45/0)2]s, the main mechanical characteristics have been determined using a Dynamic Mechanical Analyzer (DMA) and ultrasound tests. A modified Arcan device (AD) was used to generate data in a biaxial stress state, leading to the characterization of the material as a whole. The generated failure envelope allows for the prediction of failure for other combinations of normal and shear stress, depending on the thickness of the laminations, the stacking order, the pretension of the fasteners, and the method used to produce the laminations. The experimental data using AD and the application of the Tsai-Hill criterion serve to the increase the safety of CFRP components.

Mechanical Properties of GFRPs Exposed to Tensile, Compression and Tensile-Tensile Cyclic Tests.

Currently there are many applications for the use of composites reinforced with fiberglass mat and fabrics with polyester resin: automotive, aerospace, construction of wind turbines blades, sanitary ware, furniture, etc. The structures made of composites have a complex geometry, can be simultaneously subjected to tensile-compression, shear, bending and torsion. In this paper we analyzed the mechanical properties of a polyester composite material reinforced with glass fiber (denoted GFRP) of which were carried out two types of samples: The former contains four layers of plain fabric (GFRP-RT500) and the second type contains three layers of chopped strand mat (GFRP-MAT450). The samples were subjected to tensile, compression and tensile-tensile cyclic loading. The results highlight the differences between the two types of GFRP in terms of initial elastic modulus, post yield stiffness and viscoelastic behavior under cyclic loading. Thus, it was observed that the value of the modulus of elasticity and the value of ultimate tensile stress are approximately twice higher in the case of GFRP-RT500 than for the composite reinforced with short fibers type GFRP-MAT450. The tensile-tensile cyclic test highlights that the short glass fiber-reinforced composite broke after the first stress cycle, compared to the fabric-reinforced composite in which rupture occurred after 15 stress cycles. The elasticity modulus of GFRP-RT500 decreased by 13% for the applied loading with the speed of 1 mm/min and by 15% for a loading speed of 20 mm/min.

Design of Thermal Insulation Materials with Different Geometries of Channels.

Investigating the large number of various materials now available, some materials scientists promoted a method of combining existing materials with geometric features. By studying natural materials, the performance of simple constituent materials is improved by manipulating their internal geometry; as such, any base material can be used by performing millimeter-scale air channels. The porous structure obtained utilizes the low thermal conductivity of the gas in the pores. At the same time, heat radiation and gas convection is hindered by the solid structure. The solution that was proposed in this research for obtaining a material with porous structure consisted in perforating extruded polystyrene (XPS) panels, as base material. Perforation was performed horizontally and at an angle of 45 degrees related to the face panel. The method is simple and cost-effective. Perforated and simple XPS panels were subjected to three different temperature regimes in order to measure the thermal conductivity. There was an increase in thermal conductivity with the increase in average temperature in all studied cases. The presence of air channels reduced the thermal conductivity of the perforated panels. The reduction was more significant at the panels with inclined channels. The differences between the thermal conductivity of simple XPS and perforated XPS panels are small, but the latter can be improved by increasing the number of channels and the air channels' diameter. Additionally, the higher the thermal conductivity of the base material, the more significant is the presence of the channels, reducing the effective thermal conductivity. A base material with low emissivity may also reduce the thermal conductivity.

X-ray Imaging and Computed Tomography for the Identification of Geometry and Construction Elements in the Structure of Old Violins.

Numerous studies on heritage violins have shown that there are a number of factors that contribute to the acoustic quality of old violins. Among them are the geometric shape of the violin, the thickness of the tiles, the arching of the tiles, the dimensions and position of the bass bar, the size and position of the acoustic holes. Thus, the paper aims to compare the structural and constructive elements of old violins made in various famous violin workshops (Stainer, Klotz, Leeb, Babos Bela), using nondestructive and noncontact techniques based on image analysis. The violins that were studied date from 1716 to 1920, being in good condition, most of them being used by artists from the Brașov Philharmonic of Romania. In the first stage of the study, the violins were optically analyzed and scanned to identify the structure of the resonant wood, using the WinDENDRO Density 2007 program. X-ray imaging and computed tomography (CT) were also used. Combining the types of analyses, capitalizing on the expertise of violin producers and the knowledge of researchers in the field, valuable data on the geometric and constructive characteristics of old violins were extracted.

Physical and Mechanical Properties of Ammonia-Treated Black Locust Wood.

Because of the uneven colour of black locust wood, different technologies are used to change the colour, the bestknown being chemical and thermal treatments. Some of them affect the mechanical properties of wood, such as elasticity modulus, strength, durability. This study aims to compare the physical and mechanical properties of black locust wood control samples and treated wood samples with ammonia hydroxide, in terms of density profile, colour values (CIE L*, a*, b*), mechanical properties of samples subjected to static bending, viscous-elastic properties (storage modulus (E'), loss modulus (E") and damping (tan)).Two types of ammonia-fuming treatment were applied on samples: first treatment T1-5% concentration of ammonia hydroxide for 30 days; second treatment T2-10% concentration for 60 days. The results highlighted the following aspects: the overall colour change in the case of the second treatment is 27% in comparison with 7% recorded for the control samples; the lightness and yellowness values are the most affected by the second ammonia treatment of black locust wood. The density increased with almost 20% due to ammonium fuming (10% concentration/60 days); in case of static bending, the elastic modulus (MOE) tends to decrease with increasing the exposure time to ammonium, but the modulus of rupture (MOR) increases with almost 17% and the breaking force increases too, with almost 41%. In the case of dynamic mechanical analysis, the temperature leads to different viscous-elastic behaviour of each type of samples.