1.
Angew Chem Int Ed Engl
; 52(9): 2435-9, 2013 Feb 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23341324
RESUMO
A new dimension: The doping of amorphous poly(triazine imide) (PTI) through ionothermal copolymerization of dicyandiamide with 4-amino-2,6-dihydroxypyrimidine (4AP) results in triazine-based carbon nitrides with increased photoactivity for water splitting compared to crystalline poly(triazine imide) (PTI/Li(+)Cl(-), see picture) and melon-type carbon nitrides. This family of carbon nitride semiconductors has potential as low-cost, environmentally clean photocatalysts for solar fuel production.