Recent development of end-of-life strategies for plastic in industry and academia: bridging their gap for future deployment.

Plastics have advanced society as a lightweight, inexpensive material of choice, and consequently over 400 million metric tons of plastics are produced each year. The difficulty with their reuse, due to varying chemical structures and properties, is leading to one of the major global challenges of the 21st century-plastic waste management. While mechanical recycling has been proven successful for certain types of plastic waste, most of these technologies can only recycle single types of plastics at a time. Since most recycling collection streams today have a mixture of different plastic types, additional sorting is required before the plastic waste can be processed by recyclers. To combat this problem, academics have devoted their efforts to developing technologies such as selective deconstruction catalysts or compatibilizer for commodity plastics and new types of upcycled plastics. In this review, the strengths and challenges of current commercial recycling processes are discussed, followed by examples of the advancement in academic research. Bridging a gap to integrate new recycling materials and processes into current industrial practices will improve commercial recycling and plastic waste management, as well as create new economies. Furthermore, establishing closed-loop circularity of plastics by the combined efforts of academia and industry will contribute toward establishing a net zero carbon society by significant reduction of carbon and energy footprints. This review serves as a guide to understand the gap and help to create a path for new discovery in academic research to be integrated into industrial practices.

Synthesis and Characterization of a High Flux Nanocellulose-Cellulose Acetate Nanocomposite Membrane.

Despite the advantages of membrane processes, their high energy requirement remains a major challenge. Fabrication of nanocomposite membranes by incorporating various nanomaterials in the polymer matrix has shown promise for enhancing membrane flux. In this study, we embed functionalized cellulose nanofibers (CNFs) with high aspect ratios in the polymer matrix to create hydrophilic nanochannels that reduce membrane resistance and facilitate the facile transport of water molecules through the membrane. The results showed that the incorporation of 0.1 wt % CNF into the polymer matrix did not change the membrane flux (~15 L · m - 2 · h - 1 ) and Bovine Serum Albumin (BSA) Fraction V rejection, while increasing the CNF content to 0.3 wt % significantly enhanced the flux by seven times to ~100 L · m - 2 · h - 1 , but the rejection was decreased to 60-70%. Such a change in membrane performance was due to the formation of hydrophilic nanochannels by the incorporation of CNF (corroborated by the SEM images), decreasing the membrane resistance, and thus enhancing the flux. When the concentration of the CNF in the membrane matrix was further increased to 0.6 wt %, no further increase in the membrane flux was observed, however, the BSA rejection was found to increase to 85%. Such an increase in the rejection was related to the electrostatic repulsion between the negatively-charged CNF-loaded nanochannels and the BSA, as demonstrated by zeta potential measurements. SEM images showed the bridging effect of the CNF in the nanochannels with high CNF contents.