Reducing the Influence of Environmental Factors on Performance of a Diffusion-Based Personal Exposure Kit.

Sensor technology has enabled the development of portable low-cost monitoring kits that might supplement many applications in conventional monitoring stations. Despite the sensitivity of electrochemical gas sensors to environmental change, they are increasingly important in monitoring polluted microenvironments. The performance of a compact diffusion-based Personal Exposure Kit (PEK) was assessed for real-time gaseous pollutant measurement (CO, O3, and NO2) under typical environmental conditions encountered in the subtropical city of Hong Kong. A dynamic baseline tracking method and a range of calibration protocols to address system performance were explored under practical scenarios to assess the performance of the PEK in reducing the impact of rapid changes in the ambient environment in personal exposure assessment applications. The results show that the accuracy and stability of the ppb level gas measurement is enhanced even in heterogeneous environments, thus avoiding the need for data post-processing with mathematical algorithms, such as multi-linear regression. This establishes the potential for use in personal exposure monitoring, which has been difficult in the past, and for reporting more accurate and reliable data in real-time to support personal exposure assessment and portable air quality monitoring applications.

Assessing the spatial distribution of odor at an urban waterfront using AERMOD coupled with sensor measurements.

Impressions of a place are partly formed by smell. The urban waterfronts often leave a rather poor impression due to odor pollution, resulting in recurring complaints. The nature of such complaints can be subjective and vague, so there is a growing interest in quantitative measurements of emissions to explore the causes of malodorous influence. In the present work, an air quality monitor with an H2S sensor was employed to continuously measure emissions of malodors at 1-min resolution. H2S is often considered to be the predominant odorous substance from sludge and water bodies as it is readily perceptible. The integrated means of concentration from in situ measurements were combined with the AERMOD dispersion model to reveal the spatial distribution of odor concentrations and estimate the extent of odor-prone areas at a daily time step. Year-long observations showed that the diurnal profile exhibits a positively skewed distribution. Meteorology plays a vital role in odor dispersion; the degree of dispersion was explored on a case-by-case basis. There is a greater likelihood of capturing the concentration peaks at night (21:00 to 6:00) as the air is more stable then with less tendency for vertical mixing but favors a horizontal spread. This study indicates that malodors are changeable in time and space and establishes a new approach to using H2S sensor data and resolves a long-standing question about odor in Hong Kong.Implications: this study establishes a new approach combining dispersion model with novel H2S sensor data to understand the characteristics and pattern of odor emanated from the urban waterfront in Hong Kong. The sensor has dynamic concentration range to detect the episodic level of H2S and low level at background conditions. It provides more complete information in relation to odor annoyance, as well as quantitative information useful for odor regulation.

Designing function-oriented artificial nanomaterials and membranes via electrospinning and electrospraying techniques.

The sister technologies, electrospinning and electrospraying provide a facile and universal synthesis method for the continuous preparation of nanostructured materials. Through adjusting the synthesis parameters, rich electrospun and electrosprayed nanomaterials, scaffolds, membranes with tunable composition (inorganic, polymeric, hybrid, etc.), shape (sphere, films, scaffold, etc.), morphology and inner structure (solid, hollow, core-shell, co-axial, etc.) can be selectively elaborated. This review provides an overview of the design of functional nanostructured materials, porous scaffolds and membranes by electrospinning and electrospraying techniques. Key experimental parameters and synthesis strategy are emphasized to reveal the synthesis-component-structure-property relationship and eventually realize the targeted functions through predictable synthesis. Potential applications in tissue engineering, medicine, membrane filtration and lithium battery are highlighted.