One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt2(micro-S2O2H)(PPh3)4]+.
Chem Commun (Camb)
; (23): 3416-8, 2009 Jun 21.
Article
em En
| MEDLINE
| ID: mdl-19503889
ABSTRACT
One-pot oxidation and protonation of the sulfide bridging complex [Pt(2)(micro-S)(2)(PPh(3))(4)] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt(2)(micro-S(2)O(2)H)(PPh(3))(4)](+); crystallographic elucidation confirmed sulfide mono-oxygenation without S-S bonding to give formally [SO](2-) in the form of an [SOHOS](3-) overhead bridge.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2009
Tipo de documento:
Article
País de afiliação:
Singapura