Diaminotrehalose-capped ß-cyclodextrin, a new member of hemispherodextrins: synthesis, thermodynamic and spectroscopic characterization and its exploitation in chiral electrokinetic chromatography.
J Sep Sci
; 34(1): 70-6, 2011 Jan.
Article
em En
| MEDLINE
| ID: mdl-21171178
ABSTRACT
The diaminotrehalose-capped derivative of ß-CD, a new member of hemispherodextrins, was synthesized and characterized by NMR spectroscopy. Its protonation constants were determined by potentiometry, and the inclusion of both the enantiomers of dansyl-phenylalanine was investigated by NMR spectroscopy. Its stereoselective properties were exploited in electrokinetic chromatography by separating four enantiomeric pairs of dansyl derivatives of amino acids.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Trealose
/
Cromatografia Capilar Eletrocinética Micelar
/
Beta-Ciclodextrinas
Idioma:
En
Ano de publicação:
2011
Tipo de documento:
Article
País de afiliação:
Itália