Modulation of Charge Recombination in CsPbBr3 Perovskite Films with Electrochemical Bias.
J Am Chem Soc
; 140(1): 86-89, 2018 01 10.
Article
em En
| MEDLINE
| ID: mdl-29129051
ABSTRACT
The charging of a mesoscopic TiO2 layer in a metal halide perovskite solar cell can influence the overall power conversion efficiency. By employing CsPbBr3 films deposited on a mesoscopic TiO2 film, we have succeeded in probing the influence of electrochemical bias on the charge carrier recombination process. The transient absorption spectroscopy experiments conducted at different applied potentials indicate a decrease in the charge carrier lifetimes of CsPbBr3 as we increase the potential from -0.6 to +0.6 V vs Ag/AgCl. The charge carrier lifetime increased upon reversing the applied bias, thus indicating the reversibility of the photoresponse to charging effects. The ultrafast spectroelectrochemical experiments described here offer a convenient approach to probe the charging effects in perovskite solar cells.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Estados Unidos