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Assembly of Discrete Chalcogenolate Clusters into a One-Dimensional Coordination Polymer with Enhanced Photocatalytic Activity and Stability.
Wang, Ze-Kun; Sheng, Ming-Ming; Qin, Shun-Shun; Shi, Hua-Tian; Strømme, Maria; Zhang, Qian-Feng; Xu, Chao.
Afiliação
  • Wang ZK; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan , Anhui 243002 , P. R. China.
  • Sheng MM; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan , Anhui 243002 , P. R. China.
  • Qin SS; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan , Anhui 243002 , P. R. China.
  • Shi HT; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan , Anhui 243002 , P. R. China.
  • Strømme M; Ångström Laboratory, Department of Materials Science and Engineering, Division of Nanotechnology and Functional Materials , Uppsala University , Uppsala SE-75121 , Sweden.
  • Zhang QF; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan , Anhui 243002 , P. R. China.
  • Xu C; Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma'anshan , Anhui 243002 , P. R. China.
Inorg Chem ; 59(4): 2121-2126, 2020 Feb 17.
Article em En | MEDLINE | ID: mdl-31999108
ABSTRACT
Interlinking discrete supertetrahedral chalcogenolate clusters with conjugated bipyridine linkers form a one-dimensional coordination polymer, [Cd6Ag4(SPh)16(DMF)(H2O)(bpe)]n (1a), displaying a broader visible-light absorption and a narrower band gap than those of the discrete cluster. More importantly, the coordination polymer demonstrates enhanced activity and stability for the photocatalytic degradation of organic dye in water.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article