Incorporating Trigonal-Prismatic Cobalt(II) Blocks into an Exchange-Coupled [Co2Cu] System.
Inorg Chem
; 59(15): 10389-10394, 2020 Aug 03.
Article
em En
| MEDLINE
| ID: mdl-32700532
ABSTRACT
Taking advantage of a rigid tetradentate ligand of bis(pyrazoly)(3-pyrazolypyridinyl)methane (PyPz3) and the [CuII(opba)]2- unit [opba4- = o-phenylenebis(oxamato)], the trinuclear complex [{CoII(PyPz3)}2CuII(opba)][ClO4]2·5MeCN·MeOH (1) was constructed, in which the CoII centers adopt a trigonal-prismatic geometry, while considerable intramolecular magnetic coupling was successfully introduced through the oxamido bridges, representing another very first example of single-molecule magnets marrying both selected coordination geometry and magnetic exchanges.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
China