Cooperative Catalyst-Enabled Regio- and Stereodivergent Synthesis of &#945;-Quaternary &#945;-Amino Acids via Asymmetric Allylic Alkylation of Aldimine Esters with Racemic Allylic Alcohols.

Xiao, Lu; Chang, Xin; Xu, Hui; Xiong, Qi; Dang, Yanfeng; Wang, Chun-Jiang

Cooperative Catalyst-Enabled Regio- and Stereodivergent Synthesis of α-Quaternary α-Amino Acids via Asymmetric Allylic Alkylation of Aldimine Esters with Racemic Allylic Alcohols.

Xiao, Lu; Chang, Xin; Xu, Hui; Xiong, Qi; Dang, Yanfeng; Wang, Chun-Jiang.

Afiliação

Xiao L; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China.
Chang X; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, 230021, China.
Xu H; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China.
Xiong Q; Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Tianjin University, Tianjin, 300072, China.
Dang Y; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China.
Wang CJ; Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Tianjin University, Tianjin, 300072, China.

Angew Chem Int Ed Engl ; 61(46): e202212948, 2022 11 14.

Article em En | MEDLINE | ID: mdl-36161447

Assuntos

Compostos Alílicos; Ésteres; Estereoisomerismo; Compostos Alílicos/química; Estrutura Molecular; Alquilação; Catálise; Aminoácidos/química

Palavras-chave

Allylic Alcohol; Asymmetric Catalysis; Stereodivergent; Synergistic Catalysis; α-Amino Acid

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Compostos Alílicos / Ésteres Idioma: En Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China

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