Construction of the [7-5-5] Tricyclic Core of Daphniphyllum Alkaloids via a Cationic Cascade Reaction.
Org Lett
; 24(51): 9520-9524, 2022 12 30.
Article
em En
| MEDLINE
| ID: mdl-36524720
ABSTRACT
The [7-5-5] tricyclic core of daphniphyllum alkaloids, containing contiguous stereogenic centers at C14 and C15 and a tetrasubstituted alkene moiety between C9 and C10, was constructed via a cascade reaction that involved an electrocyclic reaction of a pentadienyl cation and intramolecular interception of the resultant cyclopentenyl cation.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Alcaloides
/
Daphniphyllum
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
Japão