Your browser doesn't support javascript.
loading
Photoexcited NiII-Aryl Complex-Mediated Giese Reaction of Aryl Bromides.
He, Xian-Chen; Li, Ke-Rong; Gao, Jie; Guan, Jian-Ping; Chen, Hong-Bin; Xiang, Hao-Yue; Chen, Kai; Yang, Hua.
Afiliação
  • He XC; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Li KR; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Gao J; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Guan JP; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Chen HB; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Xiang HY; Jiangxi Time Chemical Company, Ltd., Fuzhou 344800, P. R. China.
  • Chen K; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
  • Yang H; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China.
Org Lett ; 25(22): 4056-4060, 2023 Jun 09.
Article em En | MEDLINE | ID: mdl-37255226
ABSTRACT
A Giese reaction of aryl bromides with electron-deficient alkenes was developed, enabled by a dual catalyst system containing NiII complex and IrIII photocatalyst. This protocol could accommodate a variety of aryl bromides and electron-deficient alkenes, delivering the conjugate adducts in up to 97% yield. The utilization of photoexcited (dtbbpy)NiII(aryl)Br intermediate as an aryl radical source allows this novel transformation of aryl halides, thus expanding the chemical space of excited nickel catalysis.
Assuntos
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Brometos / Alcenos Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Brometos / Alcenos Idioma: En Ano de publicação: 2023 Tipo de documento: Article