Gapped and Rotated Grain Boundary Revealed in Ultra-small Au Nanoparticles for Enhancing Electrochemical CO2 Reduction.
Angew Chem Int Ed Engl
; : e202410109, 2024 Sep 05.
Article
em En
| MEDLINE
| ID: mdl-39234799
ABSTRACT
Although gapped grain boundaries have often been observed in bulk and nanosized materials, and their crucial roles in some physical and chemical processes have been confirmed, their acquisition at ultrasmall nanoscale presents a significant challenge. To date, they had not been reported in metal nanoparticles smaller than 2 nm owing to the difficulty in characterization and the high instability of grain boundary (GB) atoms. Herein, we have successfully developed a synthesis method for producing a novel chiral nanocluster Au78(TBBT)40 (TBBT = 4-tert-butylphenylthiol) with a 26-atom gapped and rotated GB. This nanocluster was precisely characterized using single-crystal X-ray crystallography and mass spectrometry. Additionally, an offset atomic defect linked to the peripheral Au(TBBT)2 staple was found in the structure. Comparing it to similarly face-centered cubic-structured Au36(TBBT)24, Au44(TBBT)28, Au52(TBBT)32, Au92(TBBT)44, and ~5 nm nanocrystals, the bridging Au78(TBBT)40 nanocluster exhibits higher catalytic activity in the reduction of CO2 to CO. This enhanced activity is well interpreted using density functional theory calculations and X-ray photoelectron spectroscopy analysis, highlighting the influence of GBs and point defects on the properties of metal nanoclusters.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China