Osmium-187 enrichment in some plumes: evidence for core-mantle interaction?

Calculations with data for asteroidal cores indicate that Earth's outer core may have a rhenium/osmium ratio at least 20 percent greater than that of the chondritic upper mantle, potentially leading to an outer core with an osmium-187/osmium-188 ratio at least 8 percent greater than that of chondrites. Because of the much greater abundance of osmium in the outer core relative to the mantle, even a small addition of metal to a plume ascending from the D" layer would transfer the enriched isotopic signature to the mixture. Sources of certain plume-derived systems seem to have osmium-187/osmium-l88 ratios 5 to 20 percent greater than that for chondrites, consistent with the ascent of a plume from the core-mantle boundary.

Rhenium-osmium isotope constraints on the age of iron meteorites.

Rhenium and osmium concentrations and the osmium isotopic compositions of iron meteorites were determined by negative thermal ionization mass spectrometry. Data for the IIA iron meteorites define an isochron with an uncertainty of approximately +/-31 million years for meteorites approximately 4500 million years old. Although an absolute rheniumosmium closure age for this iron group cannot be as precisely constrained because of uncertainty in the decay constant of (187)Re, an age of 4460 million years ago is the minimum permitted by combined uncertainties. These age constraints imply that the parent body of the IIAB magmatic irons melted and subsequently cooled within 100 million years after the formation of the oldest portions of chondrites. Other iron meteorites plot above the IIA isocbron, indicating that the planetary bodies represented by these iron groups may have cooled significantly later than the parent body of the IIA irons.

Heterogeneous accretion and the moderately volatile element budget of Earth.

Several models exist to describe the growth and evolution of Earth; however, variables such as the type of precursor materials, extent of mixing, and material loss during accretion are poorly constrained. High-precision palladium-silver isotope data show that Earth's mantle is similar in 107Ag/109Ag to primitive, volatile-rich chondrites, suggesting that Earth accreted a considerable amount of material with high contents of moderately volatile elements. Contradictory evidence from terrestrial chromium and strontium isotope data are reconciled by heterogeneous accretion, which includes a transition from dominantly volatile-depleted to volatile-rich materials with possibly high water contents. The Moon-forming giant impact probably involved the collision with a Mars-like protoplanet that had an oxidized mantle, enriched in moderately volatile elements.