Bioinspired nanocomposites film with highly-aligned silicon carbide nanowires and polyvinyl alcohol for mechanical and thermal anisotropy.

This work reports a bioinspired anisotropic nanocomposite by polar solution assisted mechanical stretching method, consisting of polyvinyl alcohol (PVA) and silicon carbide nanowires (SiCNWs) with aligned morphology in one direction. Inspired by the structural mimicry of myofibers, in which the uniaxial mechanical property of materials can be improved evidently, highly-aligned SiCNWs and PVA chains that interact using intermolecular force can be obtained. Hysteresis is observed and reversible deformation occurs while tensile-relaxation cycles are applied to the 100% stretched SiCNWs/PVA nanocomposites. The nanocomposites exhibit excellent properties and the tensile strength of 100% stretched SiCNWs/PVA nanocomposites is 188.30 ± 4.2 MPa and elastic modulus is 6.95 GPa, which are increased by 421.90% and 581.37% compared with pure PVA. Finite element simulation of fracture mechanism shows good agreement with the experimental results. An improvement of thermal conductivity is also achieved in well-aligned SiCNWs/PVA. The work imitates the structure of mammal muscle and also has great potential for the macroscopic application of one-dimensional nanomaterials as super flexible heat dissipation materials.

Novel Graphene Planar Architecture with Ultrahigh Stretchability and Sensitivity.

Graphene has attracted increasing attention for strain sensing due to its unique electrical and mechanical properties by tailoring and assembling functional macrostructures with a well-defined configuration. Here a novel graphene-based planar network (GPN) with highly stretchable strain sensing is developed by direct ink writing. The integrated and regulated structure of GPN indicates an excellent response sensitivity and cyclic stability to various strain modes compared with the traditional graphene-based woven fabric (GWF) structure. An equivalent resistance network is introduced to analyze the resistance change mechanism and fracture failure mode of the network structures, in which the difference can be mainly attributed to the interfacial resistance at the crosspoints of the crossed ribbons. The tunable and interconnected GPN shows a significant difference in the response sensitivity under stretching strain in different directions, and the relative resistance change is up to 20 and 3 in horizontal and vertical directions after 1000 cycles for a 20% stretching strain, respectively, which can be explained by the transformation of the stretching mode from macro-structural stretching to micromaterial stretching. The controllable fabrication of GPN can be utilized not only for the detection of full-range human activities but monitoring external stress distribution in real-time by integration.