1.
Chemistry
; 27(60): 14846-14850, 2021 Oct 25.
Article
in English
| MEDLINE
| ID: mdl-34611939
ABSTRACT
Alkyne aminopalladation reactions starting from tosylamides are reported. The emerging vinylic Pd species are converted either in an intramolecular Heck reaction with olefinic units or in an intermolecular Suzuki reaction by using boronic acids exhibiting broad functional group tolerance. Tetra(hetero)substituted tosylated enamines are obtained in a simple one-pot process.