Silicon Nanowire Array Weaved by Carbon Chains for Stretchable Lithium-Ion Battery Anode.

To manufacture flexible batteries, it can be a challenge for silicon base anode materials to maintain structural integrity and electrical connectivity under bending and torsion conditions. In this work, 1D silicon nanowire array structures combined with flexible carbon chains consisting of short carbon nanofibers (CNFs) and long carbon nanotubes (CNTs) are proposed. The CNFs and CNTs serve as chain joints and separate chain units, respectively, weaving the well-ordered Si nanowire array into a robust and integrated configuration. The prepared flexible and stretchable silicon array anode exhibits excellent electrochemical performance during dynamic operation. A high initial specific capacity of 2856 mAh g-1 is achieved. After 1000 cycles, a capacity retention of 60% (1602 mAh g-1) is maintained. Additionally, the capacity attenuation is less than 1% after 100 bending cycles. This excellent cycling stability is obtained with a high Si loading of 6.92 mg cm-2. This novel approach offers great promise for the development of high-loading flexible energy-storage devices.

Solid-State Lithium Batteries with Ultrastable Cyclability: An Internal-External Modification Strategy.

A commonly used strategy to tackle the unstable interfacial problem between Li1.3Al0.3Ti1.7(PO4)3 (LATP) and lithium (Li) is to introduce an interlayer. However, this strategy has a limited effect on stabilizing LATP during long-term cycling or under high current density, which is due in part to the negative impact of its internal defects (e.g., gaps between grains (GBs)) that are usually neglected. Here, control experiments and theoretical calculations show clearly that the GBs of LATP have higher electronic conductivity, which significantly accelerates its side reactions with Li. Thus, a simple LiCl solution immersion method is demonstrated to modify the GBs and their electronic states, thereby stabilizing LATP. In addition to LiCl filling, composite solid polymer electrolyte (CSPE) interlayering is concurrently introduced at the Li/LATP interface to realize the internal-external dual modifications for LATP. As a result, electron leakage in LATP can be strictly inhibited from its interior (by LiCl) and exterior (by CSPE), and such dual modifications can well protect the Li/LATP interface from side reactions and Li dendrite penetration. Notably, thus-modified Li symmetrical cells can achieve ultrastable cycling for more than 3500 h at 0.4 mA cm-2 and 1500 h at 0.6 mA cm-2, among the best cycling performance to date.