ABSTRACT
Transition metals and related compounds are known to exhibit high catalytic activities in various electrochemical reactions thanks to their intriguing electronic structures. What is lesser known is their unique role in storing and transferring electrons in battery electrodes which undergo additional solid-state conversion reactions and exhibit substantially large extra capacities. Here, a full dynamic picture depicting the generation and evolution of electrochemical interfaces in the presence of metallic nanoparticles is revealed in a model CoCO3/Li battery via an in situ magnetometry technique. Beyond the conventional reduction to a Li2CO3/Co mixture under battery operation, further decomposition of Li2CO3 is realized by releasing interfacially stored electrons from its adjacent Co nanoparticles, whose subtle variation in the electronic structure during this charge transfer process has been monitored in real time. The findings in this work may not only inspire future development of advanced electrode materials for next-generation energy storage devices but also open up opportunities in achieving in situ monitoring of important electrocatalytic processes in many energy conversion and storage systems.
ABSTRACT
Li and Na metals with high energy density are promising in application in rechargeable batteries but suffer from degradation in the ambient atmosphere. The phenomenon that in terms of kinetics, Li is stable but Na is unstable in dry air has not been fully understood. Here, we use in situ environmental transmission electron microscopy combined with theoretical simulations and reveal that the different stabilities in dry air for Li and Na are reflected by the formation of compact Li2O layers on Li metal, while porous and rough Na2O/Na2O2 layers on Na metal are a consequence of the different thermodynamic and kinetics in O2. It is shown that a preformed carbonate layer can change the kinetics of Na toward an anticorrosive behavior. Our study provides a deeper understanding of the often-overlooked chemical reactions with environmental gases and enhances the electrochemical performance of Li and Na by controlling interfacial stability.
ABSTRACT
The electrical response of hybrid perovskite devices carries a significant signature from mobile ionic defects, pointing to both opportunities and threats when it comes to functionality, performance and stability of these devices. Despite its importance, the interpretation of polarization effects due to the mixed ionic-electronic conducting nature of these materials and the quantification of their ionic conductivities still poses conceptual and practical challenges, even for the equilibrium situation. In this study, we address these questions and investigate the electrical response of horizontal devices based on methylammonium lead iodide (MAPI) close to equilibrium conditions. We discuss the interpretation of DC polarization and impedance spectroscopy measurements in the dark, based on calculated and fitted impedance spectra obtained using equivalent circuit models that account for the mixed conductivity of the perovskite and for the effect of device geometry. Our results show that, for horizontal structures with a gap width between the metal electrodes in the order of tens of microns, the polarization behavior of MAPI is well described by the charging of the mixed conductor/metal interface, suggesting a Debye length in the perovskite close to 1 nm. We highlight a signature in the impedance response at intermediate frequencies, which we assign to ionic diffusion in the plane parallel to the MAPI/contact interface. By comparing the experimental impedance results with calculated spectra for different circuit models, we discuss the potential role of multiple mobile ionic species and rule out a significant contribution from iodine exchange with the gas phase in the electrical response of MAPI close to equilibrium. This study helps to clarify the measurement and interpretation of mixed conductivity and polarization effects in hybrid perovskites with immediate relevance to the characterization and development of transistors, memristors and solar cells based on this class of materials as well as other mixed conductors.
ABSTRACT
Halide perovskites (HPs) are promising candidates for optoelectronic devices, such as solar cells or light-emitting diodes. Despite recent progress in performance optimization and low-cost manufacturing, their commercialization remains hindered due to structural instabilities. While essential to the development of the technology, the relation between the microscopic properties of HPs and the relevant degradation mechanisms is still not well understood. The sensitivity of HPs toward electron-beam irradiation poses significant challenges for transmission electron microscopy (TEM) investigations of structure and degradation mechanisms at the atomic scale. However, technological advances and the development of direct electron cameras (DECs) have opened up a completely new field of electron microscopy: four-dimensional scanning TEM (4D-STEM). From a 4D-STEM dataset, it is possible to extract not only the intensity signal for any STEM detector geometry but also the phase information of the specimen. This work aims to show the potential of 4D-STEM, in particular, electron exit-wave phase reconstructions via focused probe ptychography as a low-dose and dose-efficient technique to image the atomic structure of beam-sensitive HPs. The damage mechanism under conventional irradiation is described and atomically resolved almost aberration-free phase images of three all-inorganic HPs, CsPbBr3, CsPbIBr2, and CsPbI3, are presented with a resolution down to the aperture-constrained diffraction limit.
ABSTRACT
The discrete model of space charge zones in solids reveals and remedies a variety of problems with the classic continuous Gouy-Chapman solution that occur for pronounced space charge potentials. Besides inherent problems of internal consistency, it is essentially the extremely steep profile close to the interface which makes this continuum approach questionable. Not only is quasi-1D discrete modeling a sensible approach for large space charge effects, it can also favorably be combined with the continuum description. A particularly useful application is the explicit implementation of crystallographic details and non-idealities close to the interface. This enables us to consider elastic, structural or saturation effects as well as permittivity variations in a simple but realistic way. We address details of the charge carrier profiles, but also overall properties such as space charge capacitance and space charge resistance. In the latter case the difference in the total charge (at identical concentration) is of importance, in the first case it is the inherent difference in the centroid of charge (at identical total charge) that is remarkable. The model is equally applicable for ionic charge carriers and small polarons.
ABSTRACT
In lithium thiocyanate Li(SCN), the temperature regime below the melting point (274 °C) is characterized by excess conductivities over the usual Arrhenius behavior (premelting regime). Here, the Schottky defect pair concentration is high, and the point defect chemistry can no longer be considered as dilute. Coulomb interactions of Schottky pairs are expected to occur lowering the formation energy of new carriers and hence leading avalanche-like to a transition into a fully defective superionic state. The respective non-linear behavior is investigated using the cube-root law approach characterized by a defect interaction parameter J, which is a measure of the effective defect-lattice energy. In the case of Li(SCN), the rather pronounced volume expansion is to be included in the model. A literature comparison with other materials emphasizes to what degree defect formation as well as defect interactions depend not only on the dominant mobile defect, but also on the respective sublattice. Overall, a quantitative description of the defect chemistry of Li(SCN) in the premelting regime is derived.
ABSTRACT
Specific aspects of the Li+ cation conductivity of anhydrous Li(SCN) are investigated, in particular the high migration enthalpy of lithium vacancies. Close inspection of impedance spectra and conductivity data reveals two bulk relaxation processes, with comparatively fast ion transport at high frequencies and slow ion migration at low frequencies. The impedance results are supported by solid state nuclear magnetic resonance (ssNMR), and pair distribution function (PDF) analysis. This behavior reflects a frequency dependent conductivity, which is related to the extremely slow thiocyanate (SCN)- anion lattice relaxation that occurs when a Li+ cation jumps to the next available site. Two possible migration models are proposed: the first model considers an asymmetric energy landscape for Li+ cation hopping, while the second model is connected to the jump relaxation model and allows for 180° rotational disorder of the (SCN)- anion. A complete kinetic analysis for the hopping of Li+ cations is presented, which reveals new fundamental insights into the ion transport mechanism of materials with complex anions.
ABSTRACT
This work reports on the ion transport properties and defect chemistry in anhydrous lithium thiocyanate Li(SCN), which is a pseudo-halide Li+ cation conductor. An extensive doping study was conducted, employing magnesium, zinc and cobalt thiocyanate as donor dopants to systematically vary the conductivity and derive a defect model. The investigations are based on impedance measurements and supported by other analytical techniques such as X-ray powder diffraction (XRPD), infrared (IR) spectroscopy, and density functional theory (DFT) calculations. The material was identified as Schottky disordered with lithium vacancies being the majority mobile charge carriers. In the case of Mg2+ as dopant, defect association with lithium vacancies was observed at low temperatures. Despite a comparably low Schottky defect formation enthalpy of (0.6 ± 0.3) eV, the unexpectedly high lithium vacancy migration enthalpy of (0.89 ± 0.08) eV distinguishes Li(SCN) from the chemically related lithium halides. A detailed defect model of Li(SCN) is presented and respective thermodynamic and kinetic data are given. The thiocyanate anion (SCN)- has a significant impact on ion mobility due to its anisotropic structure and bifunctionality in forming both Li-N and Li-S bonds. More details about the impact on ion dynamics at local and global scale, and on the defect chemical analysis of the premelting regime at high temperatures are given in separate publications (Part II and Part III).
ABSTRACT
Mixed conductors-single phases that conduct electronically and ionically-enable stoichiometric variations in a material and, therefore, mass storage and redistribution, for example, in battery electrodes. We have considered how such properties may be achieved synergistically in solid two-phase systems, forming artificial mixed conductors. Previously investigated composites suffered from poor kinetics and did not allow for a clear determination of such stoichiometric variations. Here we show, using electrochemical and chemical methods, that a melt-processed composite of the 'super-ionic' conductor RbAg4I5 and the electronic conductor graphite exhibits both a remarkable silver excess and a silver deficiency, similar to those found in single-phase mixed conductors, even though such behaviour is not possible in the individual phases. Furthermore, the kinetics of silver uptake and release is very fast. Evaluating the upper limit of the relaxation time [corrected] set by interfacial ambipolar diffusion reveals chemical diffusion coefficients that are even higher than those achieved for sodium chloride in bulk liquid water. These results could potentially stimulate systematic research into powerful, even mesoscopic, artificial mixed conductors.
ABSTRACT
Commercial lithium-ion (Li-ion) batteries suffer from low energy density and do not meet the growing demands of the energy storage market. Therefore, building next-generation rechargeable Li and Li-ion batteries with higher energy densities, better safety characteristics, lower cost and longer cycle life is of outmost importance. To achieve smaller and lighter next-generation rechargeable Li and Li-ion batteries that can outperform commercial Li-ion batteries, several new energy storage chemistries are being extensively studied. In this review, we summarize the current trends and provide guidelines towards achieving this goal, by addressing batteries using high-voltage cathodes, metal fluoride electrodes, chalcogen electrodes, Li metal anodes, high-capacity anodes as well as useful electrolyte solutions. We discuss the choice of active materials, practically achievable energy densities and challenges faced by the respective battery systems. Furthermore, strategies to overcome remaining challenges for achieving energy characteristics are addressed in the hope of providing a useful and balanced assessment of current status and perspectives of rechargeable Li and Li-ion batteries.
ABSTRACT
Lead halide perovskites are considered to be most promising photovoltaic materials. Highest efficiency and improved stability of perovskite solar cells have been achieved by using cation and anion mixtures. Experimental information on electronic and ionic charge carriers is key to evaluate device performance, as well as processes of photo-decomposition and photo-demixing which are observed in these materials. Here, we measure ionic and electronic transport properties and investigate various cation and anion substitutions with a special eye on their photo-ionic effect, following our previous study on CH3 NH3 PbI3 , where we found that light enhances not only electronic but also ionic conductivities. We find that this phenomenon is very sensitive to the nature of the halide, while the cationic substitutions are less relevant. Based on the observation that the ionic conductivity enhancement found for iodide perovskites is significantly weakened by bromide substitution, we provide a chemical rationale for the photo-demixing in mixed halide compositions.
ABSTRACT
The formation of a stable solid electrolyte interphase (SEI) is a prerogative for functional lithium metal batteries. Herein, the formation and evolution of such SEI in contact with glyme-based electrolytes is investigated under open circuit voltage and several constant current cycles. An important conclusion of the study is that Lix Sy species are nonbeneficial SEI components, compared to the Li3 N counterpart. In addition, chemical (X-ray photoelectron spectroscopy, XPS) and electrochemical (impedance spectroscopy) evolution of SEI under galvanostatic conditions are comprehensively tracked.
ABSTRACT
Many exciting "anomalies" affecting long-time and low-frequency phenomena in the photoactive halide perovskites that are presently in the focus of the field of photovoltaics turn out to be rather expected from the point of view of solid-state ionics. This Perspective discusses such issues based on the mixed conducting nature of these materials and indicates how the solid-state ionics toolbox can be used to condition and potentially improve these solids. In addition to equilibrium bulk properties, interfacial effects and light effects on the mixed conductivity are considered.
ABSTRACT
In the same way as electron transport is crucial for information technology, ion transport is a key phenomenon in the context of energy research. To be able to tune ion conduction by light would open up opportunities for a wide realm of new applications, but it has been challenging to provide clear evidence for such an effect. Here we show through various techniques, such as transference-number measurements, permeation studies, stoichiometric variations, Hall effect experiments and the use of blocking electrodes, that light excitation enhances by several orders of magnitude the ionic conductivity of methylammonium lead iodide, the archetypal metal halide photovoltaic material. We provide a rationale for this unexpected phenomenon and show that it straightforwardly leads to a hitherto unconsidered photodecomposition path of the perovskite.
ABSTRACT
We present here first principles hybrid functional calculations of the atomic and electronic structure of several iodine-related point defects in CsPbI3, a material relevant for photovoltaic applications. We show that the presence of neutral interstitial I atoms or electron holes leads to the formation of di-halide dumbbells of I2- (analogous to the well-known situation in alkali halides). Their formation and one-electron energies in the band gap are determined. The formation energy of the Frenkel defect pair (I vacancies and neutral interstitial I atoms) is found to be â¼1 eV, and as such is smaller than the band gap. We conclude that both iodine dumbbells and iodine vacancies could be, in principle, easily produced by interband optical excitation.
ABSTRACT
SrFeO3-δ is a mixed ionic-electronic conductor with a complex magnetic structure that reveals a colossal magnetoresistance effect. This material and its solid solutions are attractive for various spintronic, catalytic and electrochemical applications, including cathodes for solid oxide fuel cells and permeation membranes. Its properties strongly depend on oxygen non-stoichiometry. Ab initio hybrid functional approach was applied herein to study the thermodynamic stability of a series of SrFeO3-δ compositions with several non-stoichiometries δ, ranging from 0 to 0.5 (SrFeO3-SrFeO2.875-SrFeO2.75-SrFeO2.5) as a function of temperature and oxygen pressure. The results obtained by two approaches, in which either (i) all electrons at Fe atoms explicitly described or (ii) inner core electrons at Fe atoms are replaced by effective core potential, are compared. Based on our calculations, phase diagrams were constructed, allowing the determination of environmental conditions for the existence of stable phases. It is shown that (within an employed model) only the SrFeO2.5 phase appears to be stable. The stability region for this phase was re-drawn on the contour map of oxygen chemical potential, presented as a function of temperature and oxygen partial pressure. A similar analysis was also performed using experimental Gibbs energies of perovskite formation from the elements. The present modelling strongly suggest a significant attraction between neutral oxygen vacancies. These vacancies are created during a series of the abovementioned SrFeO3-δ mutual transformations accompanied by oxygen release.
ABSTRACT
The development of suitable anode materials is far from satisfactory and is a major scientific challenge for a competitive sodium-ion battery technology. Metal sulfides have demonstrated encouraging results, but still suffer from sluggish kinetics and severe capacity decay associated with the phase change. Herein we show that rational electrode design, that is, building efficient electron/ion mixed-conducting networks, can overcome the problems resulting from conversion reactions. A general strategy for the preparation of hierarchical carbon-coated metal sulfide (MSâC) spheres through thermal sulfurization of metal glycerate has been developed. We demonstrate the concept by synthesizing highly uniform hierarchical carbon coated vanadium sulfide (V2 S3 âC) spheres, which exhibit a highly reversibly sodium storage capacity of 777â mAh g-1 at 100â mA g-1 , excellent rate capability (410â mAh g-1 at 4000â mA g-1 ), and impressive cycling ability.
ABSTRACT
Production and secretion of pro-metastatic proteins is a feature of many tumor cells. The FAM3C interleukin-like epithelial-to-mesenchymal-transition (EMT) inducer (ILEI) has been shown to be strongly up-regulated in several cancers and to be essential for tumor formation and metastasis in epithelial cells, correlating with a significant decrease in overall survival in colon and breast cancer patients. ILEI has been seen to interact with the γ-secretase presenilin 1 subunit (PS1). However, not much is known about the mechanism-of-action or the detailed ILEI structure. We present here the crystal structures of FAM3C ILEI and show that it exists as monomers but also as covalent dimers. The observed ILEI ß-ß-α fold confirmed previous indications that the FAM3C proteins do not form classical four-helix-bundle structures as was initially predicted. This provides the first experimental evidence that the interleukin-like EMT inducers are not evolutionarily related to the interleukins. However, more surprisingly, the ILEI dimer structure was found to feature a trans-linked domain swap, converting an intramolecular disulfide to intermolecular. Interestingly, dimeric but not monomeric ILEI was subsequently found to cause a dose-dependent increase in EpRas cell invasiveness comparable with TGF-ß, indicating that the dimer might be the active ILEI species. This is in line with a parallel study showing that covalent oligomerization of ILEI is essential for EMT and tumor progression in vivo The structures and the activity data give some first insight into the relationship between dimerization and ILEI function as well as indicate an intriguing link between ILEI, the PS1-protease, TGF-ß, and the TGF-ß receptor 1.
Subject(s)
Cytokines/metabolism , Models, Molecular , Neoplasm Proteins/metabolism , Amino Acid Substitution , Animals , Cell Line, Transformed , Cell Movement , Crystallography, X-Ray , Cysteine/chemistry , Cystine/chemistry , Cytokines/chemistry , Cytokines/genetics , Dimerization , Humans , Interleukins/chemistry , Interleukins/metabolism , Mice , Neoplasm Proteins/chemistry , Neoplasm Proteins/genetics , Peptide Fragments/chemistry , Peptide Fragments/genetics , Peptide Fragments/metabolism , Point Mutation , Protein Conformation , Protein Interaction Domains and Motifs , Protein Stability , Recombinant Fusion Proteins/chemistry , Recombinant Fusion Proteins/metabolism , Structural Homology, ProteinABSTRACT
Proline is prevalent in intrinsically disordered proteins (IDPs). NMR assignment of proline-rich IDPs is a challenge due to low dispersion of chemical shifts. We propose here new sensitivity-enhanced 4D NMR experiments that correlate two pairs of amide resonances that are either consecutive (NH i-1, NH i) or flanking a proline at position i-1 (NH i-2, NH i). The maximum 2-fold enhancement of sensitivity is achieved by employing two coherence order-selective (COS) transfers incorporated unconventionally into the pulse sequence. Each COS transfer confers an enhancement over amplitude-modulated transfer by a factor of â2 specifically when transverse relaxation is slow. The experiments connect amide resonances over a long fragment of sequence interspersed with proline. When this method was applied to the proline-rich region of B cell adaptor protein SLP-65 (pH 6.0) and α-synuclein (pH 7.4), which contain a total of 52 and 5 prolines, respectively, 99% and 92% of their nonprolyl amide resonances have been successfully assigned, demonstrating its robustness to address the assignment problem in large proline-rich IDPs.
Subject(s)
Adaptor Proteins, Signal Transducing/chemistry , Amides/chemistry , Nuclear Magnetic Resonance, Biomolecular , Proline/chemistry , alpha-Synuclein/chemistry , HumansABSTRACT
The kinetics of storing mass in a battery electrode are typically limited by slow diffusion in storage particles. The diffusion timescale can be made faster by decreasing the size of the particles, but then it becomes more difficult to efficiently contact each particle with ionic and electronic current collectors, e.g., electrolyte and carbon. To achieve an optimal balance, the dimensions of the various phases in the electrode architecture should be tuned to the transport properties of the storage phase. Here we quantify this strategy by modeling the kinetics of galvanostatic charging for several particle geometries using the Nernst-Planck formalism and assuming mass storage via a solid solution. We show that when ions and electrons are inserted at separate contact surfaces, in general the storage kinetics depend on two length scales - the ionic and electronic wiring lengths - that characterize the transport distances within the storage material to the respective current collectors. Quantitative guidelines for the optimal wiring lengths are derived for two model geometries, and the dependence on transport parameters, particle shape, and contact geometry is discussed. These results can guide the optimization of various aspects of the architecture of a battery electrode, including the size and shape of individual particles and the configuration of the electrolyte and current collector networks.