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Chem Commun (Camb) ; 50(72): 10406-8, 2014 Sep 18.
Article in English | MEDLINE | ID: mdl-25069061

ABSTRACT

A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst and supported colloidal-based Pd as well.


Subject(s)
Alkenes/chemistry , Ionic Liquids/chemistry , Palladium/chemistry , Catalysis , Hydrogenation , Isomerism , Lead/chemistry , Silicon Dioxide/chemistry
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