Corrosion Behavior of As-Cast and Heat-Treated Al-Co Alloys in 3.5 wt% NaCl.

The present work evaluates the effect of Co content on the microstructure and corrosion performance of Al-Co alloys of various compositions (2-32 wt% Co), fabricated by flux-assisted stir casting. A preliminary investigation on the effect of heat treatment (600 °C, up to 72 h) on the microstructure and corrosion behavior of Al-20 wt% Co and Al-32 wt% Co was also conducted. The Al- (2-10) wt% Co alloys were composed of acicular Al9Co2 particles uniformly dispersed in an Al matrix. The Al-20 wt% Co and Al-32 wt% Co alloys additionally contained Al13Co4 blades enveloped in Al9Co2 wedges. Heat treatment of Al-20 wt% Co and Al-32 wt% Co led to a significant reduction in the volume fraction of Al13Co4 and a decrease in hardness. Al-Co alloys with high Co content (10-32 wt% Co) exhibited greater resistance to localized corrosion in 3.5 wt% NaCl, but lower resistance to general corrosion compared to the (0-5 wt% Co) alloys. Heat treatment led to a slight increase in the corrosion resistance of the Al-Co alloys. The microstructure of the produced alloys was analyzed and correlated with the corrosion performance. Finally, corrosion mechanisms were formulated.

Development and Physicochemical Characterization of Edible Chitosan-Casein Hydrogel Membranes for Potential Use in Food Packaging.

The increasing global concern over plastic waste and its environmental impact has led to a growing interest in the development of sustainable packaging alternatives. This study focuses on the innovative use of expired dairy products as a potential resource for producing edible packaging materials. Expired milk and yogurt were selected as the primary raw materials due to their protein and carbohydrate content. The extracted casein was combined with various concentrations of chitosan, glycerol, and squid ink, leading to the studied samples. Chitosan was chosen due to its appealing characteristics, including biodegradability, and film-forming properties, and casein was utilized for its superior barrier and film-forming properties, as well as its biodegradability and non-toxic nature. Glycerol was used to further improve the flexibility of the materials. The prepared hydrogels were characterized using various instrumental methods, and the findings reveal that the expired dairy-based edible packaging materials exhibited promising mechanical properties comparable to conventional plastic packaging and improved barrier properties with zero-oxygen permeability of the hydrogel membranes, indicating that these materials have the potential to effectively protect food products from external factors that could compromise quality and shelf life.

Hydrogel Membranes from Chitosan-Fish Gelatin-Glycerol for Biomedical Applications: Chondroitin Sulfate Incorporation Effect in Membrane Properties.

Chondroitin sulfate (ChS), chitosan (Chi), and fish gelatin (FG), which are byproducts of a fish-treatment small enterprise, were incorporated with glycerol (Gly) to obtain dense hydrogel membranes with reduced brittleness, candidates for dressing in wound healing applications. The mechanical properties of all samples were studied via Dynamic Mechanical Analysis (DMA) and tensile tests while their internal structure was characterized using Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) and X-ray Diffraction (XRD) instruments. Their surface morphology was analyzed by ThermoGravimetric Analysis (TGA) method, while their water permeability was estimated via Water Vapor Transmission Rate (WVTR) measurements. Wettability and degradation rate measurements were also carried out. Characterization results indicated that secondary interactions between the natural polymers and the plasticizer create the hydrogel membranes. The samples were amorphous due to the high concentration of plasticizer and the amorphous nature of the natural polymers. The integration of ChS led to decreased decomposition temperature in comparison with the glycerol-free sample, and all the materials had dense structures. Finally, the in vitro endothelial cell attachment studies indicate that the hydrogel membranes successfully support the attachment and survival of primary on the hydrogel membranes and could be appropriate for external application in wound healing applications as dressings.

Capsule-Based Self-Healing and Self-Sensing Composites with Enhanced Mechanical and Electrical Restoration.

In this work, we report for the first time the manufacturing and characterization of smart multifunctional, capsule-based self-healing and self-sensing composites. In detail, neat and nanomodified UF microcapsules were synthesized and incorporated into composites with a nanomodified epoxy matrix for the restoration of the mechanical and electrical properties. The electrical properties were evaluated with the use of the impedance spectroscopy method. The self-healing composites were subjected to mode-II fracture toughness tests. Additionally, the lap strap geometry that can simulate the mechanical behavior of a stiffened panel was used. The introduction of the nanomodified self-healing system improved the initial mechanical properties in the mode-II fracture toughness by +29%, while the values after the healing process exceeded the initial one. At lap strap geometry, the incorporation of the self-healing system did not affect the initial mechanical properties that were fully recovered after the healing process.

Advanced Glass Fiber Polymer Composite Laminate Operating as a Thermoelectric Generator: A Structural Device for Micropower Generation and Potential Large-Scale Thermal Energy Harvesting.

This study demonstrates for the first time a structural glass fiber-reinforced polymer (GFRP) composite laminate with efficient thermal energy harvesting properties as a thermoelectric generator (TEG). This TEG laminate was fabricated by stacking unidirectional glass fiber (GF) laminae coated with p- and n-type single-wall carbon nanotube (SWCNT) inks via a blade coating technique. According to their thermoelectric (TE) response, the p- and n-type GF-SWCNT fabrics exhibited Seebeck coefficients of +23 and -29 µV/K with 60 and 118 µW/m·K2 power factor values, respectively. The in-series p-n interconnection of the TE-enabled GF-SWCNT fabrics and their subsequent impregnation with epoxy resin effectively generated an electrical power output of 2.2 µW directly from a 16-ply GFRP TEG laminate exposed to a temperature difference (ΔT) of 100 K. Both experimental and modeling work validated the TE performance. The structural integrity of the multifunctional GFRP was tested by three-point bending coupled with online monitoring of the steady-state TE current (Isc) at a ΔΤ of 80 K. Isc was found to closely follow all transitions and discontinuities related to structural damage in the stress/strain curve, thus showing its potential to serve the functions of power generation and damage monitoring.

Development of Effective Lipase-Hybrid Nanoflowers Enriched with Carbon and Magnetic Nanomaterials for Biocatalytic Transformations.

In the present study, hybrid nanoflowers (HNFs) based on copper (II) or manganese (II) ions were prepared by a simple method and used as nanosupports for the development of effective nanobiocatalysts through the immobilization of lipase B from Pseudozyma antarctica. The hybrid nanobiocatalysts were characterized by various techniques including scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), X-ray diffraction (XRD), Raman spectroscopy, and Fourier transform infrared spectroscopy (FTIR). The effect of the addition of carbon-based nanomaterials, namely graphene oxide and carbon nanotubes, as well as magnetic nanoparticles such as maghemite, on the structure, catalytic activity, and operational stability of the hybrid nanobiocatalysts was also investigated. In all cases, the addition of nanomaterials during the preparation of HNFs increased the catalytic activity and the operational stability of the immobilized biocatalyst. Lipase-based magnetic nanoflowers were effectively applied for the synthesis of tyrosol esters in non-aqueous media, such as organic solvents, ionic liquids, and environmental friendly deep eutectic solvents. In such media, the immobilized lipase preserved almost 100% of its initial activity after eight successive catalytic cycles, indicating that these hybrid magnetic nanoflowers can be applied for the development of efficient nanobiocatalytic systems.

Production of hierarchical all graphitic structures: A systematic study.

We report the production of hierarchical all graphitic structures through a systematic study involving the use of wet chemical treatments for dip coating of carbon fibers (CFs) for surface grafting with multiwalled carbon nanotubes (CNTs). Realization of a thin homogeneous veil of CNTs onto the CF surface was achieved through an extensive parametric survey. Optimization of aqueous dispersions of CNTs eliminated the need for oxidation of the CF surface. The effects of chemical processes onto the surface and structural characteristics of the involved graphitic species were evaluated via thermogravimetric analysis, and X-ray photoelectron, infrared and Raman spectroscopies. The dielectric properties of the produced CNT aqueous dispersions were monitored via electrochemical impedance spectroscopy. A final assessment of the produced hierarchical CFs was performed through scanning electron microscopy.