Confined migration of induced hot electrons in Ag/graphene/TiO2 composite nanorods for plasmonic photocatalytic reaction.

Confined migration of hot electrons is presented in nanorods of layered Ag/graphene/TiO2 structure for highly efficient plasmonic photocatalytic water treatment. The light-illuminating titanium dioxide (TiO2) nanorods provide a large amount of high-energy hot electrons for the generation of highly-active superoxide radical (*O2 -) that leads to the degradation of organics in water. Comparison between photocatalytic processing efficiency by photocatalysts with various composite materials were presented based on the preferred propagation path of induced hot electrons that leads to generation of *O2 -. The best results done by Ag/graphene/TiO2 nanorods showed that the sandwiched layer of graphene on TiO2 nanorods collects the induced hot electrons and results in high efficiency photocatalytic reaction.

Optimization of Piezoresistive Strain Sensors Based on Gold Nanoparticle Deposits on PDMS Substrates for Highly Sensitive Human Pulse Sensing.

In this study, highly-sensitive piezoresistive strain sensors based on gold nanoparticle thin films deposited on a stretchable PDMS substrate by centrifugation were developed to measure arterial pulse waveform. By controlling carbon chain length of surfactants, pH value and particle density of the colloidal solutions, the gauge factors of nanoparticle thin film sensors can be optimized up to 677 in tensile mode and 338 in compressive mode, and the pressure sensitivity up to 350. Low pH and thin nanoparticle films produce positive influences to superior gauge factors. It has been demonstrated that nanoparticle thin film sensors on PDMS substrates were successfully applied to sense arterial pulses in different body positions, including wrist, elbow crease, neck, and chest.

Gas ionization sensors with carbon nanotube/nickel field emitters.

Gas ionization sensors based on the field emission properties of the carbon nanotube/nickel (CNT/Ni) field emitters were first developed in this work. It is found that the breakdown electric field (E(b)) slightly decreases from 2.2 V/microm to 1.9 V/microm as the pressure of H2 gas increases from 0.5 Torr to 100 Torr. On the contrary, E(b) obviously increases from 2.9 V/microm to 6.5 V/microm as O2 gas pressure increases from 0.5 Torr to 100 Torr. This may be explained by the depression of the electron emission that caused by the adsorption of the O2 gas on the CNT emitters. The Raman spectra of the CNT/Ni emitters also show that more defects were generated on the CNTs after O2 gas sensing. The Joule heating effect under high current density as performing H2 sensing was also observed. These effects may contribute the pressure dependence on the breakdown electric field of the CNT/Ni gas ionization sensors.

Ultralow-Threshold Continuous-Wave Room-Temperature Crystal-Fiber/Nanoperovskite Hybrid Lasers for All-Optical Photonic Integration.

Continuous-wave (CW) room-temperature (RT) laser operation with low energy consumption is an ultimate goal for electrically driven lasers. A monolithically integrated perovskite laser in a chip-level fiber scheme is ideal. However, because of the well-recognized air and thermal instabilities of perovskites, laser action in a perovskite has mostly been limited to either pulsed or cryogenic-temperature operations. Most CW laser operations at RT have had poor durability. Here, crystal fibers that have robust and high-heat-load nature are shown to be the key to enabling the first demonstration of ultralow-threshold CW RT laser action in a compact, monolithic, and inexpensive crystal fiber/nanoperovskite hybrid architecture that is directly pumped with a 405 nm diode laser. Purcell-enhanced light-matter coupling between the atomically smooth fiber microcavity and the perovskite nanocrystallites gain medium enables a high Q (≈1500) and a high ß (0.31). This 762 nm laser outperforms previously reported structures with a record-low threshold of 132 nW and an optical-to-optical slope conversion efficiency of 2.93%, and it delivers a stable output for CW and RT operation. These results represent a significant advancement toward monolithic all-optical integration.

Local modification of self-assembled monolayers by a photocatalytic probe.

We demonstrate a novel nanolithography method based on the photocatalytic decomposition of the self-assembled monolayer (SAM) near a TiO2-coated probe. The TiO2 film was deposited on Ti-Pt coated Si probes by plasma sputtering. After annealing at 500 degrees C in air for 2 hr, the film was in the anatase phase, according to examination by Raman and X-ray diffraction spectra. Island-structured octadecyltrichlorosilane (OTS) partial monolayers on glass were used as the substrates. When the photocatalytic probe was illuminated by ultra-violet light, the modification occurred on the near OTS SAM islands. No change was observed on the exposed oxide surface between OTS islands. Without UV illumination, no modification occurred on OTS. Thus, the modification of the OTS surface is related to the photocatalytic reaction. A line width as small as 60 nm was achieved and observed by lateral force microscopy (LFM). The diffusion of reactive oxygen species were also observed from the remote photodecomposition of the OTS monolayer. These results should be beneficial to the development of hierarchically constructed nanolithography.

Fabrication of carbon nanotubes field emission cathode by composite plating.

Carbon nanotubes (CNTs) have high aspect ratio and have great potential to be applied as the field emission cathode because of its large field enhancement factor. In this work, a high performance carbon nanotube field emission cathode (CNTFC) was fabricated by using a composite plating method. The CNTs were purified by acid solutions and then dispersed in electrobath with nickel ions at temperatures of 60, 70, or 80 degrees C for the electroless plating process on glass substrate. The resulting CNT-Ni composite film has strong adhesion on the glass substrate. The degree of graphitization and the microstructure of the CNTFCs were studied by Raman spectroscopy and scanning electron microscopy. The field emission properties of the CNTFCs show a low turn-on electric field E(on) of about 1.2 V/microm, and a low threshold electric field E(th) of about 1.9 V/microm. Such a composite plating method could be applied to the fabrication of large area CNT field-emission displays.

Tunable plasmonic response from alkanethiolate-stabilized gold nanoparticle superlattices: evidence of near-field coupling.

We report on the self-assembly of large-area, highly ordered 2D superlattices of alkanethiolate-stabilized gold nanoparticles ( approximately 10.5 nm in core diameter) onto quartz substrates with varying lattice constants, which can be controlled by the alkyl chain lengths, ranging from C12 (1-dodecanethiolate), C14 (1-tetradecanethiolate), C16 (1-hexadecanethiolate), to C18 (1-octadecanethiolate). These 2D nanoparticle superlattices exhibit strong collective surface plasmon resonance that is tunable via the near-field coupling of adjacent nanoparticles. The approach presented here provides a unique and viable means of building artificial "plasmonic crystals" with precisely designed optical properties, which can be useful for the emerging fields of plasmonics, such as subwavelength integrated optics.

Anderson Insulators in Self-Assembled Gold Nanoparticles Thin Films: Single Electron Hopping between Charge Puddles Originated from Disorder.

The Anderson insulating states in Au nanoparticle assembly are identified and studied under the application of magnetic fields and gate voltages. When the inter-nanoparticle tunneling resistance is smaller than the quantum resistance, the system showing zero Mott gap can be insulating at very low temperature. In contrast to Mott insulators, Anderson insulators exhibit great negative magnetoresistance, inferring charge delocalization in a strong magnetic field. When probed by the electrodes spaced by ~200 nm, they also exhibit interesting gate-modulated current similar to the multi-dot single electron transistors. These results reveal the formation of charge puddles due to the interplay of disorder and quantum interference at low temperatures.

Nearly isotropic piezoresistive response due to charge detour conduction in nanoparticle thin films.

Piezoresistive responses of nanoparticle thin-film strain sensors on flexible polyimide substrates were studied. Disordered interparticle tunneling introduces microscopic detour of charge conduction so as to reduce gauge factors. The disorder also results in large resistance change when current flows in the direction perpendicular to a unidirectional strain, reducing response anisotropy. For practical usages, stability and endurance of these strain sensors are confirmed with 7 × 10(4) bending cycles. Cracks form in devices under prolonged cyclic bending and slightly reduce gauge factor.

The n-type Ge photodetectors with gold nanoparticles deposited to enhance the responsivity.

Gold nanoparticles (AuNPs) have been deposited on n-type Ge photodetectors to improve the responsivity. Two different coverage ratios, including 10.5 and 30.3% of AuNPs have been prepared, and the fabricated photodetectors are compared with the control sample. The 1,310-nm responsivities at -2 V of the control, 10.5% AuNPs, and 30.3% AuNPs samples are 465, 556, and 623 mA/W, respectively. The AuNPs could increase the responsivities due to the plasmon resonance. The reflectance spectra of these samples have been measured to verify that plasmon resonance contributes to the forward scattering of incident light. The reflectance decreases with AuNP deposition, and a denser coverage results in a smaller reflectance. The smaller reflectance indicates more light could penetrate into the Ge active layer, and it results in a larger responsivity.

Identification of Mott insulators and Anderson insulators in self-assembled gold nanoparticles thin films.

How the interparticle tunnelling affects the charge conduction of self-assembled gold nanoparticles is studied by three means: tuning the tunnel barrier width by different molecule modification and by substrate bending, and tuning the barrier height by high-dose electron beam exposure. All approaches indicate that the metal-Mott insulator transition is governed predominantly by the interparticle coupling strength, which can be quantified by the room temperature sheet resistance. The Hubbard gap, following the prediction of quantum fluctuation theory, reduces to zero rapidly as the sheet resistance decreases to the quantum resistance. At very low temperature, the fate of devices near the Mott transition depends on the strength of disorder. The charge conduction is from nearest-neighbour hopping to co-tunnelling between nanoparticles in Mott insulators whereas it is from variable-range hopping through charge puddles in Anderson insulators. When the two-dimensional nanoparticle network is under a unidirectional strain, the interparticle coupling becomes anisotropic so the average sheet resistance is required to describe the charge conduction.

Electrostatic assembly of gold colloidal nanoparticles on organosilane monolayers patterned by microcontact electrochemical conversion.

A new approach is introduced for electrostatically guided adsorption of colloidal nanoparticles onto a patterned self-assembled monolayer (SAM) with feature sizes ranging from nm to mm. Patterning of the adsorption templates is realized by electric-field-induced anodic oxidation of aminosilane SAM using an ink-free method. In this versatile method, both "positive" and "negative" type pattern transfers are possible. The chemically converted patterns are induced by localized electrical fields on the microcontacted areas, and the patterning resolution is insensitive to the diffusion of oxidizing agents because of the self-limiting oxidation kinetics, thereby enabling high-resolution, large-scale parallel patterning.