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1.
Sensors (Basel) ; 24(5)2024 Mar 06.
Article in English | MEDLINE | ID: mdl-38475236

ABSTRACT

The Multi-Point Relay (MPR) is one of the core technologies for Optimizing Link State Routing (OLSR) protocols, offering significant advantages in reducing network overhead, enhancing throughput, maintaining network scalability, and adaptability. However, due to the restriction that only MPR nodes can forward control messages in the network, the current evaluation criteria for selecting MPR nodes are relatively limited, making it challenging to flexibly choose MPR nodes based on current link states in dynamic networks. Therefore, the selection of MPR nodes is crucial in dynamic networks. To address issues such as unstable links, poor transmission accuracy, and lack of real-time performance caused by mobility in dynamic networks, we propose a comprehensive evaluation algorithm of MPR based on link-state awareness. This algorithm defines five state evaluation parameters from the perspectives of node mobility and load. Subsequently, we use the entropy weight method to determine weight coefficients and employing the method of Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) for comprehensive evaluation to select MPR nodes. Finally, the Comprehensive Evaluation based on Link-state awareness of OLSR (CEL-OLSR) protocol is proposed, and simulated experiments are conducted using NS-3. The results indicate that, compared to PM-OLSR, ML-OLSR, LD-OLSR, and OLSR, CEL-OLSR significantly improves network performance in terms of packet delivery rate, average end-to-end delay, network throughput, and control overhead.

2.
Opt Express ; 31(20): 33064-33076, 2023 Sep 25.
Article in English | MEDLINE | ID: mdl-37859094

ABSTRACT

In this paper, we studied a series of high-speed photodetectors (PD) with different super-lattice interlayer periods and the scale of the effective area to examine their communication performance. The mini-PDs are designed with a single 1 mm × 1 mm effective area. The mini-PDs have three different super-lattice (SL) periods in the interlayer: 8, 15, and 32. The micro-PD sample has multiple 50um by 50um photosensitive areas that form a 4 × 4 receiver array, which shares a common N electrode. Its SL period is 26. The experiment shows that mini-PDs have the advantages such as better tolerance to beam spot deviation, larger field of view (FoV), higher responsibility, and wider peak width in spectral response. But micro-LED samples outperform the others in communication capacity and wavelength selectivity. The 8, 15, and 32 SL mini-PD samples achieve 6.6, 7.3, and 8.8 Gb/s data rates, respectively. The micro-PD gains the maximum data rate of 14.38Gb/s without applying waveform level post-equalization, and 15.26Gb/s after using an NN-based post-equalizer. This experiment shows that with proper DSP, GaN-based PD would be suitable for high-speed VLC systems, especially for the short wavelength spectrum in visible light.

3.
Lasers Med Sci ; 38(1): 157, 2023 Jul 05.
Article in English | MEDLINE | ID: mdl-37407742

ABSTRACT

This study aimed to explore the safety and clinical efficacy of light emitting diode (LED) golden light combined with acyclovir in treating herpes zoster (HZ). According to the random number table, 54 inpatients with HZ were divided into control group, golden-light group, and red-light group, with 18 cases in each group. The control group received acyclovir intravenous drip, while the patients in the red-light group received acyclovir intravenous drip and red-light LED phototherapy, and the golden-light group received acyclovir intravenous drip and golden-light LED phototherapy. Primary assessments included herpes stopping time, incrustation time, decrustation time, pain visual analog scale scores (VAS), and incidence of postherpetic neuralgia (PHN) on the 30th and 90th days. Golden-light group and red-light group showed a shorter herpes stopping time, incrustation time, and decrustation time (P < 0.05) compared to the control group (P < 0.05), while the golden-light group showed a shorter incrustation time and decrustation time than the red light group (all P < 0.05). After treatment VAS scores, the golden-light group showed a significant improvement compared to the control group. The golden-light group showed a better PHN incidence than the control group at 30 days follow-up. Compared with the comprehensive curative effect, the total effective rates of the golden-light group, red-light group, and control group were 88.89%, 77.78%, and 72.22%, respectively, and the efficacy of the golden-light group was better than that of the control group and red-light group. Golden light combined with acyclovir can shorten the course of HZ, relieve pain, and reduce the occurrence of PHN, and the effect is better than that of the red-light group and the control group.


Subject(s)
Herpes Zoster , Neuralgia, Postherpetic , Humans , Acyclovir/therapeutic use , Prospective Studies , Herpes Zoster/drug therapy , Herpes Zoster/epidemiology , Neuralgia, Postherpetic/drug therapy , Treatment Outcome
4.
Opt Express ; 30(18): 33337-33352, 2022 Aug 29.
Article in English | MEDLINE | ID: mdl-36242375

ABSTRACT

Recently, visible light communication (VLC) has emerged as a promising communication method in 6G. To achieve 6G high-speed transmission, wavelength division multiplexing (WDM) based VLC systems are a highly promising candidate. However, the "yellow and green gap" greatly limits the yellow light efficiency of InGaN-based LEDs and also restricts the transmission rate of yellow LEDs. In addition, pre-equalization and post-equalization also have an important impact on high-speed communication. In this paper, we propose to employ a vertical InGaN-based Si-substrate yellow LED with bit-power loading discrete multitone (DMT) modulation and a novel cascaded pre-equalizer network to achieve a high-speed yellow-light VLC system. The proposed cascaded pre-equalizer network is based on a digital Zobel network and a partial nonlinear pre-equalizer (DZNPN). The microscopic time-domain transient response of the high-speed and large-amplitude signal is also investigated to show a severe impairment. Utilizing the DZNPN cascaded pre-equalizer network based on the third-order Volterra series, a record-breaking data rate of 3.764Gbps over 1.2 m free space and 3.808Gbps over 0.7 m are experimentally demonstrated under the hard decision-forward error correction (HD-FEC) threshold of 3.8 × 10-3. The rate can be improved from 2.818Gbps to 3.764Gbps with 650Mbaud compared to the un-preprocessed signal. This is the highest data rate ever reported for yellow-light VLC systems based on a single LED to the best of our knowledge.

5.
Opt Express ; 29(23): 37418-37428, 2021 Nov 08.
Article in English | MEDLINE | ID: mdl-34808813

ABSTRACT

In this paper, we propose an optofluidic lenticular lens array (OLLA) for a two-dimensional/three-dimensional (2D/3D) switchable display. The OLLA includes a bottom substrate layer with lenticular lens structure, a microfluidic layer with microchannels, and a top substrate layer with inlets as well as outlets. A micro gap is formed between the lenticular lens of the bottom substrate layer and the top substrate layer. When air is in the micro gap, the OLLA behaves as a lenticular lens array, which can realize 3D display. When fluid is filled in the micro gap, because the refractive index of the fluid is the same with the lenticular lens structure, the OLLA equivalents to a transparent flat panel, which can realize a 2D display. Experiments verify that a switchable 2D/3D display prototype based on this OLLA and a smartphone achieves both high-resolution 2D display and high-quality 3D display.

6.
Opt Express ; 28(6): 8974-8984, 2020 Mar 16.
Article in English | MEDLINE | ID: mdl-32225512

ABSTRACT

In this paper, a liquid optical switch is proposed, and the 1550 nm infrared/visible switching function based on hydraulic control can be realized. An infrared light switch cavity, a visible light cavity and a liquid control cavity are stacked to form the main framework of the device. The glycerol, dyed liquid, and transparent liquid are filled in the cavities, respectively. Two elastic films are fabricated between the cavities for controlling the liquid volume of the cavities. With such a structure, in the initial state, the 1550 nm infrared light and visible light are absorbed by the glycerol and dyed liquid, respectively. The device shows infrared light-off and visible light-off states. When the elastic film is actuated by the liquid pressure, the shape of the elastic film can be changed. Once the elastic film touches to the substrate, a light channel can be formed so that the infrared light or visible light can pass through it. It shows infrared light-on or visible light-on states. In this way, the device can be worked as an infrared light and visible light switchable optical switch. The experiments show that the device can obtain the optical attenuation from ∼1.02 dB to ∼18.24 dB for 1550 nm infrared light optical switch and ∼0.66 dB to ∼8.70 dB @ λ=450 nm; ∼0.62 dB to ∼8.74 dB @ λ=532 nm; ∼0.77 dB to ∼9.00 dB @ λ=633 nm for visible light optical switch. The device has potential applications in the fields of optical fiber communications, variable optical attenuators, and light shutters.

7.
J Chem Phys ; 152(24): 244707, 2020 Jun 28.
Article in English | MEDLINE | ID: mdl-32610948

ABSTRACT

Engineering the interface and surface structures of semiconductor-based photoelectrodes for improved charge transfer dynamics and promoted water redox reaction kinetics is essential to achieve efficient photoelectrochemical (PEC) water splitting. In this work, α-Fe2O3 nanorods, successively coated with TiO2 and CoOx thin layers, were reported as the photoanode for solar-driven water oxidation. The obtained α-Fe2O3/TiO2/CoOx photoanode exhibits superior PEC performance as compared to bare α-Fe2O3, with a 3.3-time improvement in photocurrent density at 1.23 V vs reversible hydrogen electrode. This significant enhancement results from the formed heterojunction between α-Fe2O3 and TiO2 for the accelerated photogenerated charge separation and transfer as well as the passivated surface defects by the TiO2 overlayer for reduced charge recombination. Additionally, the existence of CoOx as the oxygen evolution catalyst significantly facilitates the surface reaction kinetics and thus reduces the overpotential for water oxidation. This study demonstrates a collaborative strategy of interface and surface engineering to design novel structures of α-Fe2O3 based photoanodes for highly efficient solar water oxidation.

8.
Soft Matter ; 15(44): 9150-9156, 2019 Nov 28.
Article in English | MEDLINE | ID: mdl-31674620

ABSTRACT

Microlens arrays (MLAs), as one of the key features in the optoelectronics field, have attracted a lot of attention recently. Unfortunately, existing fabrication methods of MLAs have many disadvantages, such as complex fabrication procedures and difficult morphology control. This paper presents a low-cost and tunable fabrication approach for concave MLAs on ultraviolet (UV) polymer surfaces. We used condensed water droplets, formed by initiative cooling, as the template for the formation of concave MLAs in this approach. A sacrificial layer of polymer material was introduced to fabricate concave MLAs with different morphology parameters. The three most important parameters of MLAs, i.e. diameter, cross-sectional profile, and packing distance, can be tuned by the proposed novel fabrication approach. By controlling the condensation time of water droplets, we can control the diameter of the concave MLAs. Moreover, the cross-sectional profile can be controlled by replacing the sacrificial layer material to change the interaction among the water droplets, sacrificial polymers, and UV polymers. In addition, the packing distance of the MLAs can also be adjusted by introducing the lateral flow of the sacrificial polymer, which was driven by the additional sacrificial polymer dispensed on the substrate. Furthermore, the UV polymer film with MLAs on its surface was applied for the packaging of high power green LEDs. Consequently, the optical output power of green LED modules is enhanced by 11.4% when using the MLAs at the driving current of 500 mA.

9.
Article in English | MEDLINE | ID: mdl-36901266

ABSTRACT

BACKGROUND: Preschool children are in a period of rapid physical and psychological development, and improving their level of physical fitness is important for their health. To better develop the physical fitness of preschool children, it is very important to understand the behavioral attributes that promote the physical fitness of preschool children. This study aimed to determine the effectiveness of and the differences between different physical exercise programs in improving preschool children's physical fitness. METHODS: A total of 309 preschool children aged 4-5 years were recruited from 5 kindergartens to participate in the experiment. They were cluster-randomly allocated into five groups: basic movements (BM) group, rhythm activities (RA) group, ball games (BG) group, multiple activities (MA) group, and control (CG) group. The intervention groups received designed physical exercise programs with a duration of 30 min 3 times per week for 16 weeks. The CG group received unorganized physical activity (PA) with no interventions. The physical fitness of preschool children was measured using the PREFIT battery before and after the interventions. One-way analysis of variance, a nonparametric test; generalized linear models (GLM); and generalized linear mixed models (GLMM) were used to examine differences during the pre-experimental stage among groups and to assess the differential effects of the intervention conditions on all outcome indicators. The intervention condition models were adjusted for potential confounders (baseline test results, age, gender, height, weight, and body mass index) explaining the main outcome variance. RESULTS: The final sample consisted of 253 participants (girls 46.3%) with an average age of 4.55 ± 0.28 years: the BG group (n = 55), the RA group (n = 52), the BM group (n = 45), the MA group (n = 44), and the CG group (n = 57). The results of the generalized linear mixed model and generalized linear model analyses indicated significant differences for all physical fitness tests between groups, except for the 20 m shuttle run test and the sit-and-reach test after the interventions. Grip strength was significantly higher in the BG and MA groups than in the BM group. The scores for standing long jump were significantly higher in the MA group than in the other groups. The scores for the 10 m shuttle run test were significantly lower in the BG and MA groups than in the CG, BM, and RA groups. The scores for skip jump were significantly lower in the BG and MA groups than in the RA group. The scores for balance beam were significantly lower in the BG and MA groups than in the RA group and significantly lower in the BG group than in the BM group. The scores for standing on one foot were significantly higher in the BG and MA groups than in the CG and RA groups and significantly higher in the BM group than in the CG group. CONCLUSIONS: Physical exercise programs designed for preschool physical education have positive effects on the physical fitness of preschool children. Compared with the exercise programs with a single project and action form, the comprehensive exercise programs with multiple action forms can better improve the physical fitness of preschool children.


Subject(s)
Exercise Test , Muscle Strength , Female , Humans , Child, Preschool , Exercise Test/methods , Physical Fitness , Exercise , Exercise Therapy
10.
Article in English | MEDLINE | ID: mdl-35627867

ABSTRACT

Background: Evidence shows that physical exercise promotes preschoolers' fundamental movement skills (FMSs) and physical fitness (PF). However, studies that assess the effectiveness of different types of physical exercise interventions to improve FMSs and PF in preschool children remain scarce. To explore and compare the effectiveness of different physical exercise on FMSs and PF, interventions comprising ball games (BGs), rhythm activities (RAs), basic movements (BMs), and a combination of all related activities (multiple activities, MAs) will be conducted among preschoolers. Methods: A single-blind, five-arm, cluster-randomized trial will be conducted in kindergarten in Shanghai, China. In total, 300 healthy preschoolers, aged 4 to 5 years, will be randomized to four intervention groups (BG, RA, BM, or MA) and one control group (unorganized physical activities). Four intervention groups will receive three 30-min lessons weekly for 16 weeks. At the baseline, the end of the 16-week intervention, and the 6-month follow-up after the end of the intervention, the primary outcomes (FMSs and PF) and physical activity (PA), and sociodemographic and anthropometric data will be assessed. Discussion: This study will provide vital information regarding the effect of different physical exercise interventions on preschool children's FMSs and PF, PA, and the potential interactions between these domains. The most effective intervention strategy can be generalized to kindergarten and other preschool educational institutions in practice to promote preschoolers' development of FMSs and PF. Conclusions: This study protocol aims to provide a method to solve the problem of "how to arrange physical exercise and which kind of physical exercise program can promote FMS and PF better in preschool children".


Subject(s)
Exercise , Physical Fitness , Child, Preschool , China , Humans , Randomized Controlled Trials as Topic , Schools , Single-Blind Method
11.
Front Psychol ; 13: 932014, 2022.
Article in English | MEDLINE | ID: mdl-35910985

ABSTRACT

Background: Self-efficacy is an important component of the mental well-being of college students. This study aimed to evaluate the development and the correlation between physical fitness (PF), exercise behavior, and self-efficacy in college students. To examine whether PF in individual college students can predict self-efficacy, and whether exercise behavior mediates this relationship. Methods: This was an observational study of 1923 randomly selected college students (50.5% girl). Measures included the Physical Activity Rating Scale, the Self-Efficacy Scale, and PF testing. Results: Self-efficacy was weakly correlated to both PF (r = 0.240) and exercise behavior (r = 0.248). In regression analysis, PF explained 24.7% of the variance in self-efficacy, increasing to 29.4% when exercise behavior was considered. Therefore, the predictive effect of PF on self-efficacy is partially realized through healthy exercise behavior. Conclusion: Physical fitness can predict self-efficacy among college students, with exercise behavior being an important mediation of this relationship. Strategies to improve positive exercise behaviors and PF could improve students' self-efficacy and overall mental health.

12.
Article in English | MEDLINE | ID: mdl-36011976

ABSTRACT

BACKGROUND: In the period of the COVID-19 pandemic, the level of college students' physical exercise, the detection rate of negative emotions, and their correlation should attract extensive attention. Therefore, this study aimed to explore the correlation between college students' physical exercise and negative emotions. METHODS: Data were collected via a web-based cross-sectional survey. A questionnaire survey was conducted among 3118 college students from five universities in Shanghai in March 2022. In addition to sociodemographic information, measures included Physical Activity Rating Scale (PARS-3) and Depression Anxiety Stress Scale (DASS). The chi-squared test and logistic regression were used to analyze the differences and test the relative risk of negative emotions caused by different amounts of physical exercise. RESULTS: Most students (66.1%) performed a small amount of physical exercise. Male students' physical-exercise level was higher than female students', and the detection rate of negative emotions was lower than that of female students. Moderate and low physical-exercise levels were associated with a higher risk of depression (beta of 0.289 and 0.345, respectively) and anxiety (beta of 0.301 and 0.418) symptoms than high physical-exercise level. CONCLUSIONS: The anxiety symptoms of college students were significant during the COVID-19 pandemic period. The physical-exercise behavior of college students was closely related to negative emotions, and the weakening of physical-exercise behavior was one of the factors that induced negative emotions in college students.


Subject(s)
COVID-19 , Anxiety/epidemiology , Anxiety/psychology , COVID-19/epidemiology , China/epidemiology , Cross-Sectional Studies , Disease Outbreaks , Exercise , Female , Humans , Male , Mental Health , Pandemics , SARS-CoV-2 , Students/psychology
13.
Front Public Health ; 10: 1046326, 2022.
Article in English | MEDLINE | ID: mdl-36530687

ABSTRACT

Objective: We investigated the effects of COVID-19 fear on negative moods among college students, and assessed the efficacy of physical exercise behavior as a moderator variable. Methods: This was a cross-sectional study. Students from three colleges and universities in Shangqiu City, Henan Province and Yangzhou City, Jiangsu Province were enrolled in this study, which was performed during the COVID-19 pandemic using an online questionnaire. A total of 3,133 college students completed the questionnaire. Measurement tools included the COVID-19 Phobia Scale (C19P-S), Depression-Anxiety-Stress Self-Rating Scale (DASS), and the Physical Activity Behavior Scale (PARS-3). Results: During the COVID-19 pandemic, the rates of depression, anxiety, and stressful negative moods among college students were 35.5, 65.5, and 10.95%, respectively; there was a positive correlation between COVID-19 fear and negative moods among college students (r = 0.479, p < 0.001), which was negatively correlated with physical exercise behavior (r = -0.4, p < 0.001); the regulating effects of physical exercise behavior were significant (ΔR2 = 0.04, p < 0.001). Conclusion: The rate of negative moods among college students is high, and the fear for COVID-19 is one of the key factors that lead to negative moods. Physical exercise can modulate the impact of COVID-19 fear among college students on negative moods. Studies should elucidate on mental health issues among different populations during the COVID-19 pandemic.


Subject(s)
COVID-19 , Phobic Disorders , Humans , COVID-19/epidemiology , Pandemics , SARS-CoV-2 , Cross-Sectional Studies , East Asian People , Mental Health , Students/psychology , Exercise
14.
Article in English | MEDLINE | ID: mdl-36142020

ABSTRACT

OBJECTIVE: Negative moods in college students have caused frequent extreme behaviors. This study analyzed the current status and correlation between physical activity and negative moods in college students. METHODS: A cross-sectional study design was used in the present research. Data on college students' physical activity and negative moods were collected using the Sports Questionnaire Star software. The questionnaires were administered to college students in five colleges and universities in Henan and Jiangsu Provinces, China, and a total of 3711 correctly completed questionnaires were returned. Data on sociological and demographic information, the International Physical Activity Questionnaire Short Form (IPAQ-SF), and the Depression Anxiety and Stress Scale (DASS) were collected. The research was conducted in December 2021. RESULTS: The low-intensity physical activity rate among college students was 55.56%, while depression, anxiety, and stress symptoms were detected in 35.14%, 65.29%, and 10.99%of the college students, respectively. Depression (K = 35.58, p < 0.001) and anxiety (K = 15.56, p < 0.001) rates were significantly different among the different physical activity intensity groups. The proportion of students who perform high-intensity physical activities was lower than those who perform low- and moderate-intensity physical activities. CONCLUSION: Low physical activity and high anxiety are evident among college students, and prolonged moderate-to-low-intensity physical activity (including static behavior) induces depression and anxiety. In the future, further studies can be conducted on improving the physical activity intensity of college students, improving the mental health monitoring and intervention systems of college students, and exploring the dose-effect relationship between physical activity and negative moods.


Subject(s)
Exercise , Students , Anxiety/epidemiology , Anxiety/psychology , Cross-Sectional Studies , Depression/epidemiology , Depression/psychology , Humans , Students/psychology , Universities
15.
Sports Med Health Sci ; 3(1): 54-57, 2021 Mar.
Article in English | MEDLINE | ID: mdl-35782674

ABSTRACT

Insufficient physical activity (PA), prolonged sedentary behavior (SB) and inadequate sleep (SLP) are detrimental factors to population health. To address health issues caused by insufficient PA, excessive SB and poor SLP, the World Health Organization (WHO) updated PA and SB guidelines for all populations aged from 5 years to 65 years and older in 2020. For children under 5 years old, the WHO issued the first global guidelines for PA, SB and SLP (collectively refer to movement behaviors) in April 2019. The guidelines applied a holistic approach to promote health behaviors, filling the gap of no comprehensive global movement guidelines for young children. Although the guidelines for young children offer guidance for health promotion, some research and practice implications and other issues should be mentioned. This commentary includes considerations for the importance of the WHO guidelines for younger children, critical analysis of evidence for developing the guidelines, and recommendations for future research and practice. The aim of this paper is to further advance health research in younger populations.

16.
Animals (Basel) ; 11(9)2021 Sep 16.
Article in English | MEDLINE | ID: mdl-34573675

ABSTRACT

Crustacean farming is a fast-growing sector and has contributed to improving incomes. Many studies have focused on how to improve crustacean production. Information about crustacean behavior is important in this respect. Manual methods of detecting crustacean behavior are usually infectible, time-consuming, and imprecise. Therefore, automatic growth situation monitoring according to changes in behavior has gained more attention, including acoustic technology, machine vision, and sensors. This article reviews the development of these automatic behavior monitoring methods over the past three decades and summarizes their domains of application, as well as their advantages and disadvantages. Furthermore, the challenges of individual sensitivity and aquaculture environment for future research on the behavior of crustaceans are also highlighted. Studies show that feeding behavior, movement rhythms, and reproduction behavior are the three most important behaviors of crustaceans, and the applications of information technology such as advanced machine vision technology have great significance to accelerate the development of new means and techniques for more effective automatic monitoring. However, the accuracy and intelligence still need to be improved to meet intensive aquaculture requirements. Our purpose is to provide researchers and practitioners with a better understanding of the state of the art of automatic monitoring of crustacean behaviors, pursuant of supporting the implementation of smart crustacean farming applications.

17.
Animals (Basel) ; 11(10)2021 Sep 23.
Article in English | MEDLINE | ID: mdl-34679796

ABSTRACT

The rapid and precise recognition of fish behavior is critical in perceiving health and welfare by allowing farmers to make informed management decisions on recirculating aquaculture systems while reducing labor. The conventional recognition methods are to obtain movement information by implanting sensors on the skin or in the body of the fish, which can affect the normal behavior and welfare of the fish. We present a novel nondestructive method with spatiotemporal and motion information based on deep learning for real-time recognition of fish schools' behavior. In this work, a dual-stream 3D convolutional neural network (DSC3D) was proposed for the recognition of five behavior states of fish schools, including feeding, hypoxia, hypothermia, frightening and normal behavior. This DSC3D combines spatiotemporal features and motion features by using FlowNet2 and 3D convolutional neural networks and shows significant results suitable for industrial applications in automatic monitoring of fish behavior, with an average accuracy rate of 95.79%. The model evaluation results on the test dataset further demonstrated that our proposed method could be used as an effective tool for the intelligent perception of fish health status.

18.
J Nanosci Nanotechnol ; 21(1): 750-764, 2021 01 01.
Article in English | MEDLINE | ID: mdl-33213676

ABSTRACT

To investigate the pore structure of shale oil reservoirs, seven organic-rich shales from the Shahejie Formation in the Dongying Depression were studied by rock pyrolysis analysis, X-ray diffraction analysis and scanning electron microscopy with argon ion beam polishing. The proportions of the different types of pores at different scales, the statistical relationships between the mineral contents and pore development, and the development of pores in the mineral laminae combination were discussed. The results demonstrated that the nanometer to micron pore structures were divided into intraparticle pores, interparticle pores, intercrystalline pores, organic pores, microfissures and diagenetic contraction fractures. Interparticle pores and intraparticle pores are both essential components of the sample pores. The original residual pores are mainly small pores and mesopores, while the secondary dissolution pores are primarily mesopores and macropores. For different pore sizes, there are small surface pore contributions of diagenetic contraction fractures, microfissures, intercrystalline pores, and organic pores. The carbonate minerals content controls the oil storage capacity of shale by dominating the development of the various pore types, while the clay mineral bands content can affect the permeability of shale by influencing the development of large-scale microfissures. In the laminae development sample, surface pore development is closely related to the sedimentary mineral microcircle, which consists of a falling semicycle and a rising semicircle. The total surface porosity, including microfissures, diagenetic contraction fractures, interparticle pores and intraparticle pores, mainly developed at the intersection of the rising semicircle and the falling semicircle, and this development corresponds to the highest level of a cycle. In summary, interparticle pores and intraparticle pores are the main components of pores developed in low thermal maturity shale and shale laminae where their heterogeneity is influenced by mineral composition and laminae microcircles.

19.
J Phys Chem Lett ; 10(9): 2278-2285, 2019 May 02.
Article in English | MEDLINE | ID: mdl-31002523

ABSTRACT

Interfaces with multifunctions for promoted solid/solid interfacial charge-transfer dynamics and accelerated solid/electrolyte interfacial water redox reaction kinetics are determinative for the photoelectrodes achieving high performances for photoelectrochemical (PEC) water splitting. In this work, well-designed cascading interfaces are introduced in the n-Si photoanode, which is effectively protected by an atomic layer-deposited CoO x thin layer for stabilizing the n-Si photoanode and then coated with an earth-abundant NiCuO x layer for catalyzing the water oxidation reaction. Furthermore, the formed n-Si/CoO x/NiCuO x triple junction could generate a large band bending to provide a considerable photovoltage for promoting the photoinduced charge-transfer and separation processes at the n-Si/CoO x/NiCuO x cascading interfaces. Moreover, at the NiCuO x/electrolyte interface, an in situ electrochemically formed NiCu(OH) x/NiOOH active layer facilitates the water oxidation reaction kinetics. This study demonstrates an alternative approach to stabilize and catalyze n-Si-based photoanodes with cascading interfaces for efficient solar water oxidation.

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