On-Device Pressure-Tunable Moving Schottky Contacts.

Contact engineering enhances electronic device performance and functions but often involves costly, inconvenient fabrication and material replacement processes. We develop an in situ, reversible, full-device-scale approach to reconfigurable 2D van der Waals contacts. Ideal p-type Schottky contacts free from surface dangling bonds and Fermi-level pinning are constructed at structurally superlubric graphite-MoS2 interfaces. Pressure control is introduced, beyond a threshold of which tunneling across the contact can be activated and amplified at higher loads. Record-high figures of merits such an ideality factor nearing 1 and an off-state current of 10-11 A were reported. The concept of on-device moving contacts is demonstrated through a wearless Schottky generator, operating with an optimized overall efficiency of 50% in converting weak, random external stimuli into electricity. The device combines generator and pressure-sensor functions, achieving a high current density of 31 A/m2 and withstanding over 120,000 cycles, making it ideal for neuromorphic computing and mechanosensing applications.

Uniform and Persistent Jumping Detachment of Condensed Nanodroplets.

Realizing jumping detachment of condensed droplets from solid surfaces at the smallest sizes possible is vital for applications such as antifogging/frosting and heat transfer. For instance, if droplets uniformly jump at sizes smaller than visible light wavelengths of 400-720 nm, antifogging issues could be resolved. In comparison, the smallest droplets experimentally observed so far to jump uniformly were around 16 µm in radius. Here, we show molecular dynamics (MD) simulations of persistent droplet jumping with a uniform radius down to only 3.6 nm on superhydrophobic thin-walled lattice (TWL) nanostructures integrated with superhydrophilic nanospots. The size cutoff is attributed to the preferential cross-lattice coalescence of island droplets. As an application, the MD results exhibit a 10× boost in the heat transfer coefficient (HTC), showing a -1 scaling law with the maximum droplet radius. We provide phase diagrams for jumping and wetting behaviors to guide the design of lattice structures with advanced antidew performance.

Positive-Negative Tunable Coefficients of Friction in Superlubric Contacts.

In conventional systems, the coefficient of friction (COF) is typically positive, signifying a direct relationship between frictional and normal forces. Contrary to this, we observe that the load dependence of friction exhibits a unique bell-shaped curve when studying the frictional properties between graphite and α-Al_{2}O_{3} surfaces. As the applied normal force increases, the friction initially rises and then decreases. Finite element simulations reveal this behavior is due to edge detachment at the graphite/α-Al_{2}O_{3} interface as the normal force approaches a critical value. Because friction in superlubric contacts predominantly arises from edges, their detachment leads to a decrease in overall friction. We empirically validate these findings by varying the radii of curvature of the tips and the thicknesses of graphite flakes. This unprecedented observation offers a new paradigm for tuning COF in superlubric applications, enabling transitions from positive to negative values.

Ultrahigh Critical Current Density across Sliding Electrical Contacts in Structural Superlubric State.

In conventional sliding electrical contacts (SECs), large critical current density (CCD) requires a high ratio between actual and apparent contact area, while low friction and wear require the opposites. Structural superlubricity (SSL) has the characteristics of zero wear, near zero friction, and all-atoms in real contact between the contacting surfaces. Here, we show a measured current density up to 17.5 GA/m^{2} between microscale graphite contact surfaces while sliding under ambient conditions. This value is nearly 146 times higher than the maximum CCD of other SECs reported in literatures (0.12 GA/m^{2}). Meanwhile, the coefficient of friction for the graphite contact is less than 0.01 and the sliding interface is wear-free according to the Raman characterization, indicating the presence of the SSL state. Furthermore, we estimate the intrinsic CCD of single crystalline graphite to be 6.69 GA/m^{2} by measuring the scaling relation of CCD. Theoretical analysis reveals that the CCD is limited by thermal effect due to the Joule heat. Our results show the great potential of the SSL contacts to be used as SECs, such as micro- or nanocontact switches, conductive slip rings, or pantographs.

Structural superlubricity and ultralow friction across the length scales.

Structural superlubricity, a state of ultralow friction and wear between crystalline surfaces, is a fundamental phenomenon in modern tribology that defines a new approach to lubrication. Early measurements involved nanometre-scale contacts between layered materials, but recent experimental advances have extended its applicability to the micrometre scale. This is an important step towards practical utilization of structural superlubricity in future technological applications, such as durable nano- and micro-electromechanical devices, hard drives, mobile frictionless connectors, and mechanical bearings operating under extreme conditions. Here we provide an overview of the field, including its birth and main achievements, the current state of the art and the challenges to fulfilling its potential.

Load-induced dynamical transitions at graphene interfaces.

The structural superlubricity (SSL), a state of near-zero friction between two contacted solid surfaces, has been attracting rapidly increasing research interest since it was realized in microscale graphite in 2012. An obvious question concerns the implications of SSL for micro- and nanoscale devices such as actuators. The simplest actuators are based on the application of a normal load; here we show that this leads to remarkable dynamical phenomena in microscale graphite mesas. Under an increasing normal load, we observe mechanical instabilities leading to dynamical states, the first where the loaded mesa suddenly ejects a thin flake and the second characterized by peculiar oscillations, during which a flake repeatedly pops out of the mesa and retracts back. The measured ejection speeds are extraordinarily high (maximum of 294 m/s), and correspond to ultrahigh accelerations (maximum of 1.1×1010 m/s2). These observations are rationalized using a simple model, which takes into account SSL of graphite contacts and sample microstructure and considers a competition between the elastic and interfacial energies that defines the dynamical phase diagram of the system. Analyzing the observed flake ejection and oscillations, we conclude that our system exhibits a high speed in SSL, a low friction coefficient of 3.6×10-6, and a high quality factor of 1.3×107 compared with what has been reported in literature. Our experimental discoveries and theoretical findings suggest a route for development of SSL-based devices such as high-frequency oscillators with ultrahigh quality factors and optomechanical switches, where retractable or oscillating mirrors are required.

General orientation transform for the estimation of fiber orientations in white matter tissues.

PURPOSE: The orientation distribution function (ODF), which is obtained from the radial integral of the probability density function weighted by rn$$ {r}^n $$ ( r$$ r $$ is the radial length), has been used to estimate fiber orientations of white matter tissues. Currently, there is no general expression of the ODF that is suitable for any n value in the HARDI methods. THEORY AND METHODS: A novel methodology is proposed to calculate the ODF for any n>-1$$ n>-1 $$ through the Taylor series expansion and a generalized expression for -1

Anisotropic Fracture of Graphene Revealed by Surface Steps on Graphite.

The anisotropic fracture toughness G(θ) is an intrinsic feature of graphene and is fundamental for fabrication, functioning, and robustness of graphene-based devices. However, existing results show significant discrepancies on the anisotropic factor, i.e., the ratio between zigzag (ZZ) and armchair (AC) directions, G_{ZZ}/G_{AC}, both qualitatively and quantitatively. Here, we investigate the anisotropic fracture of graphene by atomic steps on cleaved graphite surfaces. Depending on the relation between the peeling direction and local lattice orientation, two categories of steps with different structures and behaviors are observed. In one category are straight steps well aligned with local ZZ directions, while in the other are steps consisting of nanoscale ZZ and AC segments. Combined with an analysis on fracture mechanics, the microscale morphology of steps and statistics of their directions provides a measurement on the anisotropic factor of G_{ZZ}/G_{AC}=0.971, suggesting that the ZZ direction has a slightly lower fracture toughness. The results provide an experimental benchmark for the widely scattered existing results, and offer constraints on future models of graphene fracture.

Structural Superlubricity Based on Crystalline Materials.

Herein, structural superlubricity, a fascinating phenomenon where the friction is ultralow due to the lateral interaction cancellation resulted from incommensurate contact crystalline surfaces, is reviewed. Various kinds of nano- and microscale materials such as 2D materials, metals, and compounds are used for the fabrication. For homogeneous frictional pairs, superlow friction forces exist in most relative orientations with incommensurate configuration. Heterojunctions bear no resemblance to homogeneous contact, since the lattice constants are naturally mismatched which leads to a robust structural superlubricity with any orientation of the two different surfaces. A discussion on the perspectives of this field is also provided to meet the existing challenges and chart the future.

Characterization of a Microscale Superlubric Graphite Interface.

Direct characterizations of the two component surfaces of a solid-solid interface are essential for understanding its various interfacial mechanical, physical, and electrical behaviors. Particularly, the fascinating phenomenon termed structural superlubricity, a state of nearly zero friction and wear, is sensitively dependent on the interface structure. Here we report a controllable pick-and-flip technique to separate a microscale contact pair for the characterization of its two component surfaces for van der Waals layered materials. With this technique, the interface of a graphite superlubric contact is characterized with resolution from microscale down to the atomic level. Imaging of the graphite lattice provides direct proof that this superlubric interface consists of two monocrystalline surfaces incommensurate with each other. More importantly, the structure-property relationship for this contact is investigated. Friction measurements combined with fully atomistic molecular dynamics reveal that internal structures [internals steps, pits, and bulges buried underneath the topmost graphene sheet(s)] have negligible contribution to the total friction; in contrast, external defects lead to a high friction. These results help us to better understand the structure of highly oriented pyrolytic graphite and the fundamental mechanisms of structural superlubricity, as well as to guide the design of superlubricity-based devices.

Origin of Friction in Superlubric Graphite Contacts.

More than thirty years ago, it was theoretically predicted that friction for incommensurate contacts between atomically smooth, infinite, crystalline materials (e.g., graphite, MoS_{2}) is vanishing in the low speed limit, and this corresponding state was called structural superlubricity (SSL). However, experimental validation of this prediction has met challenges, since real contacts always have a finite size, and the overall friction arises not only from the atoms located within the contact area, but also from those at the contact edges which can contribute a finite amount of friction even when the incommensurate area does not. Here, we report, using a novel method, the decoupling of these contributions for the first time. The results obtained from nanoscale to microscale incommensurate contacts of graphite under ambient conditions verify that the average frictional contribution of an inner atom is no more than 10^{-4} that of an atom at the edge. Correspondingly, the total friction force is dominated by friction between the contact edges for contacts up to 10 µm in lateral size. We discuss the physical mechanisms of friction observed in SSL contacts, and provide guidelines for the rational design of large-scale SSL contacts.

Temperature-regulated adhesion of impacting drops on nano/microtextured monostable superrepellent surfaces.

The monostable Cassie state is a favorable wetting state for superhydrophobic materials, in which water drops can automatically transfer from the Wenzel wetting state to the Cassie wetting state, such that as a consequence the water repellency can be maintained. Drop impact phenomena are ubiquitous in nature and of critical importance in industry, and previous works show that the efficiency of self-cleaning and dropwise condensation could benefit from drop impact on monostable surfaces. However, whether such a feature is sufficiently robust remains unclear when the temperature of the surface is taken into consideration. Here, we report that there exists a lower bound of the temperature of the surface, under which a transition from the Cassie wetting state to the Wenzel wetting state arises. By varying the temperature of the surface, it is found that the solid-liquid wetting region could be regulated. Based on thermodynamics, we propose a model to predict the controllable wetting region, and we show that the gradual transition of the wetting state is a result of the accumulation of droplets on the nanoscale. Connections between the dynamics occurring at the solid-liquid interfaces on the microscale and the condensation occurring in the nanotextures are constructed. These results deepen our understanding of the breakdown of superhydrophobicity under dynamic impinging in high humidity. Moreover, this study will shed new light on the applications for controllable liquid deposition and surface decoration, such as catalysts on the superhydrophobic surfaces.

Monostable superrepellent materials.

Superrepellency is an extreme situation where liquids stay at the tops of rough surfaces, in the so-called Cassie state. Owing to the dramatic reduction of solid/liquid contact, such states lead to many applications, such as antifouling, droplet manipulation, hydrodynamic slip, and self-cleaning. However, superrepellency is often destroyed by impalement transitions triggered by environmental disturbances whereas inverse transitions are not observed without energy input. Here we show through controlled experiments the existence of a "monostable" region in the phase space of surface chemistry and roughness, where transitions from Cassie to (impaled) Wenzel states become spontaneously reversible. We establish the condition for observing monostability, which might guide further design and engineering of robust superrepellent materials.

Generalized Scaling Law of Structural Superlubricity.

Structural superlubricity, which promises an ultralow sliding friction due to the cancellation of the lateral force between two incommensurate interfaces, is a fundamental phenomenon in modern tribology. Achieving macroscale superlubricity is critical to its practical application, and the key is understanding how friction scales with real contact area, that is, the scaling law, especially for kinetic friction which accounts for most of the energy dissipation during sliding. Here, inspired by extensive molecular dynamics simulations we introduce an analytical general theory for the scaling law of structural superlubricity, which could well explain existing experimental measurements on the nanoscale. On the microscale, the scaling law is validated by measuring the friction of several microscale superlubric graphite/hexagonal boron nitride heterojunctions. The proposed theory predicts a characteristic size D = O(100 nm) above which the scaling transits from sublinear to linear. Our results provide insights in the origin of friction for structural superlubricity and benefit its application on macroscale.

Robust microscale superlubricity in graphite/hexagonal boron nitride layered heterojunctions.

Structural superlubricity is a fascinating tribological phenomenon, in which the lateral interactions between two incommensurate contacting surfaces are effectively cancelled resulting in ultralow sliding friction. Here we report the experimental realization of robust superlubricity in microscale monocrystalline heterojunctions, which constitutes an important step towards the macroscopic scale-up of superlubricity. The results for interfaces between graphite and hexagonal boron nitride clearly demonstrate that structural superlubricity persists even when the aligned contact sustains external loads under ambient conditions. The observed frictional anisotropy in the heterojunctions is found to be orders of magnitude smaller than that measured for their homogeneous counterparts. Atomistic simulations reveal that the underlying frictional mechanisms in the two cases originate from completely different dynamical regimes. Our results are expected to be of a general nature and should be applicable to other van der Waals heterostructures.

Rotational Instability in Superlubric Joints.

Surface and interfacial energies play important roles in a number of instability phenomena in liquids and soft matter, but rarely have similar effects in solids. Here, a mechanical instability is reported which is controlled by surface and interfacial energies and is valid for a large class of materials, in particular two-dimensional layered materials. When sliding a top flake cleaved from a square microscale graphite mesa by using a probe acting on the flake through a point contact, it was observed that the flake moved unrotationally for a certain distance before it suddenly transferred to a rotating-moving state. The theoretical analysis was consistent with the experimental observation and revealed that this mechanical instability was an interesting effect of the structural superlubricity (a state of nearly zero friction). Further analysis showed that this type of instability was applicable generally for various sliding joints on different scales, as long as the friction was ultralow. Thus, the uncovered mechanism provides useful knowledge for manipulating and controlling these sliding joints, and can guide the design of future superlubricity-based devices.

Microfluidic DNA combing for parallel single-molecule analysis.

DNA combing is a widely used method for stretching and immobilising DNA molecules on a surface. Fluorescent labelling of genomic information enables high-resolution optical analysis of DNA at the single-molecule level. Despite its simplicity, the application of DNA combing in diagnostic workflows is still limited, mainly due to difficulties in analysing multiple small-volume DNA samples in parallel. Here, we report a simple and versatile microfluidic DNA combing technology (µDC), which allows manipulating, stretching and imaging of multiple, microliter scale DNA samples by employing a manifold of parallel microfluidic channels. Using DNA molecules with repetitive units as molecular rulers, we demonstrate that the µDC technology allows uniform stretching of DNA molecules. The stretching ratio remains consistent along individual molecules as well as between different molecules in the various channels, allowing simultaneous quantitative analysis of different samples loaded into parallel channels. Furthermore, we demonstrate the application of µDC to characterise UVB-induced DNA damage levels in human embryonic kidney cells and the spatial correlation between DNA damage sites. Our results point out the potential application of µDC for quantitative and comparative single-molecule studies of genomic features. The extremely simple design of µDC makes it suitable for integration into other microfluidic platforms to facilitate high-throughput DNA analysis in biological research and medical point-of-care applications.

Error Analysis and Modeling for an Absolute Capacitive Displacement Measuring System with High Accuracy and Long Range.

We proposed a novel kind of absolute capacitive grating displacement measuring system with both high accuracy and long range in a previous article. The measuring system includes both a MOVER and a STATOR, the contact surfaces of which are coated by a thin layer of dielectric film with a low friction coefficient and high hardness. The measuring system works in contact mode to minimize the gap changes. This paper presents a theoretical analysis of the influence of some factors, including fabrication errors, installation errors, and environment disturbance, on measurement signals. The measuring signal model was modified according to the analysis. The signal processing methods were investigated to improve the signal sensitivity and signal-to-noise ratio (SNR). The displacement calculation model shows that the design of orthogonal signals can solve the dead-zone problem. Absolute displacement was obtained by a simple method using two coarse signals and highly accurate displacement was further obtained while using two fine signals with the help of absolute information. According to the displacement calculation model and error analysis, the error in fine calculation functions mainly determines the model's accuracy and is locally affected by coarse calculation functions. It was also determined that amplitude differences, non-orthogonality, and signal offsets are not related to the accuracy of the displacement calculation model. The experiments were carried out to confirm the abovementioned theoretical analysis. The experimental results show that the displacement resolution and error in the displacement calculation model reach ±4.8 nm and ±34 nm, respectively, in the displacement range of 5 mm. The experiments and the theoretical analyses both indicate that our proposed measuring system has great potential for achieving an accuracy of tens of nanometers and a range of hundreds of millimeters.

A Hybrid Two-Axis Force Sensor for the Mesoscopic Structural Superlubricity Studies.

Structural superlubricity (SSL) is a state of nearly zero friction and zero wear between two directly contacted solid surfaces. Recently, SSL was achieved in mesoscale and thus opened the SSL technology which promises great applications in Micro-electromechanical Systems (MEMS), sensors, storage technologies, etc. However, load issues in current mesoscale SSL studies are still not clear. The great challenge is to simultaneously measure both the ultralow shear forces and the much larger normal forces, although the widely used frictional force microscopes (FFM) and micro tribometers can satisfy the shear forces and normal forces requirements, respectively. Here we propose a hybrid two-axis force sensor that can well fill the blank between the capabilities of FFM and micro tribometers for the mesoscopic SSL studies. The proposed sensor can afford 1mN normal load with 10 nN lateral resolution. Moreover, the probe of the sensor is designed at the edge of the structure for the convenience of real-time optical observation. Calibrations and preliminary experiments are conducted to validate the performance of the design.

Modelling DNA extension and fragmentation in contractive microfluidic devices: a Brownian dynamics and computational fluid dynamics approach.

Fragmenting DNA into short pieces is an essential manipulation in many biological studies, ranging from genome sequencing to molecular diagnosis. Among various DNA fragmentation methods, microfluidic hydrodynamic DNA fragmentation has huge advantages especially in terms of handling small-volume samples and being integrated into automatic and all-in-one DNA analysis equipment. Despite the fast progress in experimental studies and applications, a systematic understanding of how DNA molecules are distributed, stretched and fragmented in a confined microfluidic field is still lacking. In this work, we investigate the extension and fragmentation of DNA in a typical contractive microfluidic field, which consists of a shear flow-dominated area and an elongational flow-dominated area, using the Brownian dynamics-computational fluid dynamics method. Our results show that the shear flow at the straight part of the microfluidic channel and the elongational flow at the contractive bottleneck together determine the performance of DNA fragmentation. The average fragment size of DNA decreases with the increase of the strain rate of the elongational flow, and the upstream shear flow can significantly precondition the conformation of DNA to produce shorter and more uniform fragments. A systematic study of the dynamics of DNA fragmentation shows that DNA tends to break at the mid-point when the strain rate of elongational flow is small, and the breakage point largely deviates from the midpoint as the strain rate increases. Our simulation of the thorough DNA fragmentation process in a realistic microfluidic field agrees well with experimental results. We expect that our study can shed new light on the development of future microfluidic devices for DNA fragmentation and integrated DNA analysis devices.