[Water Quality Assessment and Spatial-temporal Variation Analysis in Yellow River Basin].

During the implementation of ecological protection in the Yellow River basin, understanding the water pollution status and spatio-temporal variation of water quality has become the most important thing for water safety in the basin. To analyze the water quality in recent years, the water quality data in the Yellow River basin from 2004 to 2018 were firstly collected from eight typical monitoring stations. Using a combination of multivariate data analysis methods including the Mann-Kendall (M-K) trend test, hierarchical clustering analysis (HCA), principal component analysis (PCA), and modified comprehensive water quality identification index (WQI), the spatio-temporal variation characteristics of the water quality were then explored in the Yellow River basin. The results indicated that in terms of time variation, the HCA from the water quality time series showed that the water quality of the Yellow River basin could be divided into the wet season, normal season, and dry season, being basically consistent with the hydrological period. Combined with the M-K trend test and WQI-based water quality assessment, the water quality of the Yellow River basin was improving gradually, with 2010 as the critical year. The water quality in the wet season was superior to that in the dry season. The pollution indicator NH4+-N and permanganate index were dominant in both the wet season and dry season. According to the spatial variation analysis, the water quality for all the studied stations improved significantly. Spatial clustering showed that the S6 (Shanxi Yuncheng Hejin Bridge) was obviously different from others, and further comparative study demonstrated that S6 was constantly seriously polluted. The S7 (Henan Jiyuan Xiaolangdi) exhibited different characteristics in the wet and dry season. In all stations, NH4+-N was considered to be the most common pollution indicator, whereas the permanganate index and DO were also relatively serious for S6. In different hydrological seasons, NH4+-N and the permanganate index showed different characteristics, and their variety was related to the fact that the former mainly came from domestic and industrial sources, whereas the latter was mainly derived from agricultural sources. The modified WQI showed obvious advantages over single-factor water quality assessment, and the findings from this study can provide scientific evidence for water pollution control and comprehensive water quality management in the Yellow River basin.

[Adsorption of Pb2+ onto chitosan-grafted-poly (acrylic acid )/sepiolite composite].

A composite adsorbent chitosan-grafted-poly(acrylic acid)/sepiolite was prepared, and its pH-dependence for removing Pb2+, as well as adsorption isotherm and kinetics were estimated. The results indicate that poly (acrylic acid) has been grafted onto the backbone of chitosan, forming an organic-inorganic composite adsorbent. As-prepared adsorbent shows a coarse, porous and accidented surface, which can contribute to its adsorption kinetics. Under the conditions of pH 6.00, contact time of 30 min, initial Pb2+ concentration of 0.02 mol x L(-1) and amount of adsorbent of 0.10 g, the adsorption capacity of developed adsorbent for Pb2+ is found to be 638.9 mg x g(-1), about three times than that of sepiolite. When five cycles of adsorption-desorption process were carried out, the adsorption capacity decreased to 489.2 mg x g(-1), 76.6% to its original adsorption capacity. However, when sepiolite was used as the adsorbent, no sorption can be observed after three cycles of adsorption-desorption process. Compared to sepiolite, this composite adsorbent presents higher adsorption capacity, faster adsorption rate and better reusable ability.