pH-Dependent Dual-Mode Detection toward Uranium by a Zinc-Tetraphenylethylene Fluorescent Metal-Organic Framework.

An interpenetrated tetraphenylethylene-based fluorescent metal-organic framework (ECUT-180) with exceptional sensitivity, excellent selectivity, and fast response (less than 30 s) toward uranium was successfully prepared. Especially, in the prescence of uranyl, ECUT-180 displays significant fluorescence turn-on under pH 2-3, while fluorescence turn-off under pH 4-8. The corresponding detection limits were determined to be 2.92 ppb at pH 2 and 0.86 ppb at pH 8, both of which are lower than the average uranium content (3.3 ppb) in seawater. Mechanism investigation reveals that the fluorescence enhancement on the strong acid condition can be assigned to uranium adsorption, while the quenching is caused by the resonance energy transfer.