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1.
Inorg Chem ; 60(20): 15124-15127, 2021 Oct 18.
Artículo en Inglés | MEDLINE | ID: mdl-34606249

RESUMEN

The magnetic structure of NaYMnWO6 was determined by neutron powder diffraction measurements. Below 9 K, the magnetic structure is a helix to wave vector k = (0, 0.447, 1/2), in contrast with NaYNiWO6, which shows a transverse spin density wave with k = (0.47, 0, 0.49). By analyzing the differences in the spin exchanges of NaYMnWO6 and NaYNiWO6, and in the magnetic anisotropies of the Mn2+ (d5, S = 5/2) and the Ni2+ (d2, S = 1) ions, we show what factors govern the propagation direction of a noncollinear magnetic structure and whether it becomes a helix or a cycloid.

2.
Inorg Chem ; 59(24): 17856-17859, 2020 Dec 21.
Artículo en Inglés | MEDLINE | ID: mdl-33285061

RESUMEN

The incommensurate magnetic structure (0.47, 0, 0.49) of NaYNiWO6 exhibits unconventional spin-density waves (SDWs) along the [100] direction, in which up and down spins alternate in each half-wave. This is in contrast to conventional SDWs, in which only one type of spin is present in each half-wave. We probed the formation of these unconventional SDWs by evaluating the spin exchanges of NaYNiWO6 based on density functional theory calculations and analyzing the nature of the spin frustration in NaYNiWO6 and by noting that a SDW is a superposition of two cycloids of opposite chirality. The unconventional SDWs along the [100] direction originate from the spin-frustrated antiferromagnetic chains of Ni2+ ions along that direction, leading to conventional SDWs along the [101] direction and unconventional SDWs along the [001] direction.

3.
F1000Res ; 12: 156, 2023.
Artículo en Inglés | MEDLINE | ID: mdl-36875496

RESUMEN

Background: Obesity is a major public health issue globally which is intrinsically linked to reduced heart rate variability (HRV). Physical inactivity and reduced resting HRV are linked to an increased risk of coronary heart disease, while athletes have a greater HRV. However, the exact correlation between physical activity and HRV remains uncertain. This systematic review aims to collect, report, and critically assess the current scientific literature about the association between physical activity and HRV in individuals with higher weight and obesity. Methods: A systematic search was carried out in electronic databases (Medline/PubMed, SCOPUS and CINAHL Plus) to retrieve studies that evaluated the relationship between physical activity and HRV in individuals with higher weight and obesity. Case-control, longitudinal/cohort, cross-sectional and observational studies were included. Using a critical narrative approach, information about the HRV, and physical activity was extracted and synthesized. The study was registered in PROSPERO: CRD42020208018 on October 9 2020. Results: After removing duplicates, 980 title/abstract records were checked for eligibility, and 12 papers were finally included in the narrative synthesis. The included studies contained physical activity as well as HRV in adults with higher weight or obesity with or without comorbidities. A negative relationship between moderate to vigorous physical activity and HRV indices had been found in two studies. There was also a negative relationship between sedentary time and HF (p = 0.049) and LF/HF (p = 0.036), as well as a positive relationship between sedentary time and LF (p = 0.014). Also dose-response association was found between vigorous exercise and higher SDNN, LF power, and HF power in one of the studies. Conclusions: This systematic review revealed a wide range of responses to physical activity and HRV; however, the current evidence uses a variety of approaches to objectively assess physical activity and measure HRV with different equipment.


Asunto(s)
Obesidad , Sobrepeso , Adulto , Humanos , Frecuencia Cardíaca , Estudios Transversales , Ejercicio Físico
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