Shock Response Spectrum Analysis of Fatigued Runners.

The purpose of this study was to determine the effect of fatigue on impact shock wave attenuation and assess how human biomechanics relate to shock attenuation during running. In this paper, we propose a new methodology for the analysis of shock events occurring during the proposed experimental procedure. Our approach is based on the Shock Response Spectrum (SRS), which is a frequency-based function that is used to indicate the magnitude of vibration due to a shock or a transient event. Five high level CrossFit athletes who ran at least three times per week and who were free from musculoskeletal injury volunteered to take part in this study. Two Micromachined Microelectromechanical Systems (MEMS) accelerometers (RunScribe®, San Francisco, CA, USA) were used for this experiment. The two RunScribe pods were mounted on top of the foot in the shoelaces. All five athletes performed three maximum intensity runs: the 1st run was performed after a brief warmup with no prior exercise, then the 2nd and the 3rd run were performed in a fatigued state. Prior to the 2nd and the 3rd run, the athletes were asked to perform at maximum intensity for two minutes on an Assault AirBike to tire them. For all five athletes, there was a direct correlation between fatigue and an increase in the aggressiveness of the SRS. We noticed that for all five athletes for the 3rd run the average SRS peaks were significantly higher than for the 1st run and 2nd run (p < 0.01) at the same natural frequency of the athlete. This confirms our hypothesis that fatigue causes a decrease in the shock attenuation capacity of the musculoskeletal system thus potentially involving a higher risk of overuse injury.

Active Biohybrid Nanocomposite Films Made from Chitosan, ZnO Nanoparticles, and Stearic Acid: Optimization Study to Develop Antibacterial Films for Food Packaging Application.

Chitosan is a biopolymer with great potential as food packaging due to its ability to create a film without additives and its better mechanical and antibacterial qualities compared to other biopolymers. However, chitosan film still has limitations due to its high moisture sensitivity and limited flexibility. Incorporating ZnO nanoparticles (ZnO-NPs) and stearic acid (SA) into chitosan films was expected to improve tensile strength, water vapor barrier, and antibacterial capabilities. This study aims to find the optimal formula for biohybrid nanocomposite films composed of chitosan, ZnO-NPs, and SA. The full factorial design approach-4 × 2 with 3 replicates, i.e., two independent variables, namely %ZnO-NPs at 4 levels (0%, 0.5%, 1%, and 3%, w/w) and %SA at 2 levels (0% and 5%, w/w)-was utilized to optimize chitosan-based biohybrid nanocomposite films, with the primary interests being antibacterial activities, water vapor barrier, and tensile strength. The incorporation of ZnO-NPs into chitosan films could increase antibacterial activity, while SA decreased it. The addition of SA had a good effect only in decreasing water vapor transmission rate (WVTR) values but a detrimental effect on other film properties mentioned above. The incorporation of ZnO-NPs enhanced all functional packaging properties of interest. The suggested solution of the optimization study has been validated. As a result, the formula with the inclusion of 1% ZnO-NPs without SA is optimal for the fabrication of active antibacterial films with excellent multifunctional packaging capabilities.

Inverse Identification of Single-Crystal Plasticity Parameters of HCP Zinc from Nanoindentation Curves and Residual Topographies.

This paper investigates the orientation-dependent characteristics of pure zinc under localized loading using nanoindentation experiments and crystal plasticity finite element (CPFEM) simulations. Nanoindentation experiments on different grain orientations exhibited distinct load-depth responses. Atomic force microscopy revealed two-fold unsymmetrical material pile-up patterns. Obtaining crystal plasticity model parameters usually requires time-consuming micromechanical tests. Inverse analysis using experimental and simulated loading-unloading nanoindentation curves of individual grains is commonly used, however the solution to the inverse identification problem is not necessarily unique. In this study, an approach is presented allowing the identification of CPFEM constitutive parameters from nanoindentation curves and residual topographies. The proposed approach combines the response surface methodology together with a genetic algorithm to determine an optimal set of parameters. The CPFEM simulations corroborate with measured nanoindentation curves and residual profiles and reveal the evolution of deformation activity underneath the indenter.

Spent Coffee Grounds as Building Material for Non-Load-Bearing Structures.

The gradual development of government policies for ecological transition in the modern construction sector leads researchers to explore new alternative and low environmental impact materials with a particular focus on bio-sourced materials. In this perspective, the mechanical, thermal insulation, and the sound absorption performances of a spent coffee grounds/potato starch bio-based composite were analyzed for potential application in buildings. Based on thermal conductivity and diffusivity tests, the coffee grounds waste biocomposite was characterized as an insulating material comparable with conventional thermal insulation materials of plant origin. Acoustical tests revealed absorption coefficients in the same range as other conventional materials used in building acoustical comfort. This bio-sourced material presented a sufficient compressive mechanical behavior for non-load-bearing structures and a sufficient mechanical capacity to be shaped into building bricks. Mechanical, thermal, and acoustic performances depend on the moisture environment. The groundwork was laid for an initial reflection on how this composite would behave in two opposite climates: the continental climate of Reims in France and the tropical climate of Belém in Brazil.

Novel Extruded Starch-Beet Pulp Composites for Packaging Foams.

This article concerns the elaboration and the characterization of a novel biobased potato starch-beet pulp composite for packaging applications as cushion foams. A twin-screw extruder was used to elaborate composite foams. SEM observations of these materials were conducted, and thermomechanical properties were studied in terms of thermal transitions (TGA, DSC) and viscoelastic properties (DMA). The effect of relative humidity content on viscoelastic properties was analyzed as a function of frequency. The different test results show that the composite structures are homogeneously mixed. The sponge-like structure of the beet-pulp disappears indicating a good compatibility between the two mixed constituents. The DSC curve of starch-beet pulp foam shows a single thermal transition at 153.6 °C, indicating the thermal homogeneity of the obtained composite material. The density value of starch-beet pulp foam is higher than conventional foams, but this can be optimized by adjusting the technological parameters of the extruder. The viscoelastic properties of the developed materials depend on the relative humidity.