RESUMO
Microscale 3D-printing has revolutionized micro-optical applications ranging from endoscopy, imaging, to quantum technologies. In all these applications, miniaturization is key, and in combination with the nearly unlimited design space, it is opening novel, to the best of our knowledge, avenues. Here, we push the limits of miniaturization and durability by realizing the first fiber laser system with intra-cavity on-fiber 3D-printed optics. We demonstrate stable laser operation at over 20â mW output power at 1063.4â nm with a full width half maximum (FWHM) bandwidth of 0.11â nm and a maximum output power of 37â mW. Furthermore, we investigate the power stability and degradation of 3D-printed optics at Watt power levels. The intriguing possibilities afforded by free-form microscale 3D-printed optics allow us to combine the gain in a solid-state crystal with fiber guidance in a hybrid laser concept. Therefore, our novel ansatz enables the compact integration of a bulk active media in fiber platforms at substantial power levels.
RESUMO
Photoswitchable, ambipolar field-effect transistors (FETs) are fabricated with dense networks of polymer-sorted, semiconducting single-walled carbon nanotubes (SWCNTs) in top-gate geometry with photochromic molecules mixed in the polymer matrix of the gate dielectric. Both hole and electron transport are strongly affected by the presence of spiropyran and its photoisomer merocyanine. A strong and persistent reduction of charge carrier mobilities and thus drain currents upon UV illumination (photoisomerization) and its recovery by annealing give these SWCNT transistors the basic properties of optical memory devices. Temperature-dependent mobility measurements and density functional theory calculations indicate scattering of charge carriers by the large dipoles of the merocyanine molecules and electron trapping by protonated merocyanine as the underlying mechanism. The direct dependence of carrier mobility on UV exposure is employed to pattern high- and low-resistance areas within the FET channel and thus to guide charge transport through the nanotube network along predefined paths with micrometer resolution. Near-infrared electroluminescence imaging enables the direct visualization of such patterned current pathways with good contrast. Elaborate mobility and thus current density patterns can be created by local optical switching, visualized and erased again by reverse isomerization through heating.