PVDF-HFP encapsulated WS2nanosheets in droplet-based triboelectric nanogenerators for possible detection of human Na+/K+ion concentration.

Here we report the liquid-solid interaction in droplet-based triboelectric nanogenerators (TENG) for estimation of human Na+/K+levels. The exploitation of PVDF-HFP encapsulated WS2as active layer in the droplet-based TENG (DTENG) leads to the generation of electrical signal during the impact of water droplet. Comparison over the control devices indicates that surface quality and dielectric nature of the PVDF-HFP/WS2composite largely dictates the performance of the DTENG. The demonstration of excellent sensitivity of the DTENG towards water quality indicates its promising application towards water testing. In addition, the alteration in output signal with slightest variation in ionic concentration (Na+or K+) in water has been witnessed and is interpreted with charge transfer and ion transfer processes during liquid-solid interaction. The study reveals that the ion mobility largely affects the ion adsorption process on the active layer of PVDF-HFP/WS2and thus generates distinct output profiles for diverse ions like Na+and K+. Following that, the DTENG characteristics have been exploited to artificial urine where the varying output signals have been recorded for variation in urinary Na+ion concentration. Therefore, the deployment of PVDF-HFP/WS2in DTENG holds promising application towards the analyse of ionic characteristics of body fluids.

Flexible triboelectric nanogenerators of Au-g-C3N4/ZnO hierarchical nanostructures for machine learning enabled body movement detection.

Here we report the development of triboelectric nanogenerator (TENG) based self-powered human motion detector with chemically developed Au-g-C3N4/ZnO based nanocomposite on common cellulose paper platform. Compared to bare g-C3N4, the nanocomposite in the form of hierarchical morphology is found to exhibit higher output voltage owing to the contribution of Au and ZnO in increasing the dielectric constant and surface roughness. While generating power ∼3.5µW cm-2and sensitivity ∼3.3 V N-1, the flexible TENG, is also functional under common biomechanical stimuli to operate as human body movement sensor. When attached to human body, the flexible TENG is found to be sensitive towards body movement as well as the frequency of movement. Finally upon attaching multiple TENG devices to human body, the nature of body movement has been traced precisely using machine learning (ML) techniques. The execution of the learning algorithms like artificial neural network and random forest classifier on the data generated from these multiple sensors can yield an accuracy of 99% and 100% respectively to predict body movement with great deal of precision. The exhibition of superior sensitivity and ML based biomechanical motion recognition accuracy by the hierarchical structure based flexible TENG sensor are the prime novelties of the work.

Metal oxide nanocomposite based flexible nanogenerator: synergic effect of light and pressure.

Here, we report the fabrication of nanocomposite comprising of CuO and poly (vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) for application in flexible piezoelectric nanogenerators (PENG). The chemically grown CuO nanostructures have been characterized through electron microscopy, x-ray diffraction, and spectroscopic techniques. It has been found that the incorporation of optimal CuO nanostructures in PVDF-HFP can increase the output voltage of the PENG by 22 times and is assigned to the increment in the effective dielectric constant of host PVDF-HFP. Further, the nanogenerator exhibits a maximum power of âˆ¼20µW cm-2at 3 MΩ load and can charge a capacitor under continuous bio-mechanical impart. Further, upon slight alteration of the device configuration, the output of the nanocomposite-based nanogenerator can be enhanced under illumination condition. The increment in overall piezopotential through photoexcitation in optically active CuO nanostructures can be assigned to the increment in output voltage. The wavelength dependent output variation reveal the maximum output of the PENG under blue light. Further, under white light illumination, the nanogenerator exhibits a maximum power which is 3 times higher than in dark condition and can charge a capacitor 52 times faster. The development of such superior flexible and optically active nanogenerators are quite promising for futuristic self-powered devices operated under mechanical and solar energies.

Plasmon mediated enhancement and tuning of optical emission properties of two dimensional graphitic carbon nitride nanosheets.

We demonstrate surface plasmon induced enhancement and tunablilty in optical emission properties of two dimensional graphitic carbon nitride (g-C3N4) nanosheets through the attachment of gold (Au) nanoparticles. Raman spectroscopy has revealed surface enhanced Raman scattering that arises due to the combined effect of the charge transfer process and localized surface plasmon induced enhancement in electromagnetic field, both occurring at the nanoparticle-nanosheet interface. Photoluminescence studies suggest that at an optimal concentration of nanoparticles, the emission intensity can be enhanced, which is maximum within the 500-525 nm region. Further, the fabricated electroluminescent devices reveal that the emission feature can be tuned from bluish-green to red (∼160 nm shift) upon attaching Au nanoparticles. We propose that the π*→π transition in g-C3N4 can trigger surface plasmon oscillation in Au, which subsequently increases the excitation process in the nanosheets and results in enhanced emission in the green region of the photoluminescence spectrum. On the other hand, electroluminescence of g-C3N4 can induce plasmon oscillation more efficiently and thus can lead to red emission from Au nanoparticles through the radiative damping of particle plasmons. The influence of nanoparticle size and coverage on the emission properties of two dimensional g-C3N4, nanosheets has also been studied in detail.

ZnO Nanowall Network-Based Tactile/Gesture Sensors and Prediction with Machine Learning.

In low-dimensional material systems, augmented physical and chemical properties may be witnessed through a unique morphological evolution. Here, we report the development of an optimized nanowall network of ZnO for the fabrication of a flexible single-electrode triboelectric nanogenerator (STENG)-based tactile and gesture sensors. The chemically grown nanowall network with an adequate pore area endows superior triboelectric output (current ∼0.6 µA and power ∼20 µW/cm2) by offering an optimum surface area and dielectric constant for pressure sensing applications. The rational comparison of the triboelectric properties of nanowall and nanorod structures of ZnO reveals that the higher surface area offered by the hollow walls leads to superior output characteristics. The demonstration of pressure sensitivity of the STENG ∼1 V/N is promising for self-powered tactile sensing applications. The array of STENG sensors, when attached to a user hand, generates distinguishable signals while holding objects of varying curvature and mass. Again, the observation of sensitivity of ∼0.1 V per degree during finger movement activity indicates the gesture sensing ability of the nanowall-based TENG system, facilitating sign language expression through the movement of fingers. Further, the generated electrical signals during tactile and gesture sensing can be classified and recognized through the deployment of machine learning (ML) techniques. In fact, the implementation of Random Forest and K-Nearest Neighbor models has offered an accuracy of 96% while recognizing the output signals generated by the sensor arrays. The demonstration of superior sensing characteristics with the optimized nanowall network may be advantageous in innovating prototype sensors for the differently abled people to distinguish or classify objects on the basis of material, morphology, and mass during their regular activities.

2D WS2 embedded PVDF nanocomposites for photosensitive piezoelectric nanogenerators with a colossal energy conversion efficiency of ∼25.6.

Benefiting from the advantages of low cost, light weight and mechanical flexibility, piezoelectric nanogenerators have the potential for application in renewable energy harvesting from various unexplored sources. Here, we report the demonstration of the record efficiency of flexible piezoelectric nanogenerators (PENG) using composites of polyvinylidene fluoride (PVDF) and chemically exfoliated tungsten disulfide (WS2) nanosheets, which are found to be strongly photosensitive, making them attractive for self-powered optical devices. The presence of two-dimensional (2D) WS2 nanosheets in the PVDF matrix plays a dual role in enhancing the nucleation of the electroactive ß-phase as well as inducing strong photosensitivity in the nanocomposite. The PVDF-WS2 composed flexible device is able to produce an enormously high output voltage of ∼116 V (for an impact of 105 kPa) and a piezoelectric energy conversion efficiency of ∼25.6%, which is the highest among the reported values for PVDF-2D material based self-poled piezoelectric nanogenerators. This self-poled piezo-phototronic device exhibits strain-dependent photocurrent at zero bias and exhibits a responsivity of 6.98 × 10-3 A W-1 at 0.75% strain under the illumination of 410 nm. The fabricated PENG is also able to harvest energy from routine human activities (finger tapping, writing on paper, mouse clicking, etc.) and movement of human body parts. These results open up a new horizon in piezo-phototronic materials through the realization of photosensitive multifunctional PENGs, which can be scaled up for fabricating compact, high performance, portable and self-powered wearable electronic devices for smart sensor applications.

Development of Triboelectroceutical Fabrics for Potential Applications in Self-Sanitizing Personal Protective Equipment.

Attachment of microbial bodies including the corona virus on the surface of personal protective equipment (PPE) is found to be potential threat of spreading infection. Here, we report the development of a triboelectroceutical fabric (TECF) consisting of commonly available materials, namely, nylon and silicone rubber (SR), for the fabrication of protective gloves on the nitrile platform as model wearable PPE. A small triboelectric device (2 cm × 2 cm) consisting of SR and nylon on nitrile can generate more than 20 V transient or 41 µW output power, which is capable of charging a capacitor up to 65 V in only ∼50 s. The importance of the present work relies on the TECF-led antimicrobial activity through the generation of an electric current in saline water. The fabrication of TECF-based functional prototype gloves can generate hypochlorite ions through the formation of electrolyzed water upon rubbing them with saline water. Further, computational modelling has been employed to reveal the optimum structure and mechanistic pathway of antimicrobial hypochlorite generation. Detailed antimicrobial assays have been performed to establish effectiveness of such TECF-based gloves to reduce the risk from life-threatening pathogen spreading. The present work provides the rationale to consider the studied TECF, or other materials with comparable properties, as a material of choice for the development of self-sanitizing PPE in the fight against microbial infections including COVID-19.

Nanoceutical Fabric Prevents COVID-19 Spread through Expelled Respiratory Droplets: A Combined Computational, Spectroscopic, and Antimicrobial Study.

Centers for Disease Control and Prevention (CDC) warns the use of one-way valves or vents in face masks for potential threat of spreading COVID-19 through expelled respiratory droplets. Here, we have developed a nanoceutical cotton fabric duly sensitized with non-toxic zinc oxide nanomaterial for potential use as a membrane filter in the one-way valve for the ease of breathing without the threat of COVID-19 spreading. A detailed computational study revealed that zinc oxide nanoflowers (ZnO NFs) with almost two-dimensional petals trap SARS-CoV-2 spike proteins, responsible to attach to ACE-2 receptors in human lung epithelial cells. The study also confirmed significant denaturation of the spike proteins on the ZnO surface, revealing removal of the virus upon efficient trapping. Following the computational study, we have synthesized ZnO NF on a cotton matrix using a hydrothermal-assisted strategy. Electron-microscopic, steady-state, and picosecond-resolved spectroscopic studies confirm attachment of ZnO NF to the cotton (i.e., cellulose) matrix at the atomic level to develop the nanoceutical fabric. A detailed antimicrobial assay using Pseudomonas aeruginosa bacteria (model SARS-CoV-2 mimic) reveals excellent antimicrobial efficiency of the developed nanoceutical fabric. To our understanding, the nanoceutical fabric used in the one-way valve of a face mask would be the choice to assure breathing comfort along with source control of COVID-19 infection. The developed nanosensitized cloth can also be used as an antibacterial/anti CoV-2 washable dress material in general.

Piezo-phototronic mediated enhanced photodetection characteristics of plasmonic Au-g-C3N4/CdS/ZnO based hybrid heterojunctions on a flexible platform.

We have studied the piezo-phototronic induced enhancement in the photo-response of CdS/ZnO heterojunctions attached with plasmonic Au nanoparticle loaded 2D-graphitic carbon nitride (g-C3N4). The hybrid g-C3N4/CdS/ZnO heterojunction favours the charge carrier separation through the formation of a step-like band alignment. Furthermore, the integration of plasmonic Au loaded g-C3N4 nanosheets on the conventional CdS/ZnO heterojunction facilitates improved visible light absorption properties. The heterojunction device on a flexible platform under the application of a strain (∼0.017%) exhibits ∼102 times higher photoresponse over the control sample at a constant bias of ∼2 V. The variation in the photo-response under different bending conditions has been explained in terms of the improved charge transport through the modified energy bands at the interface of ZnO. The improved piezo-phototronic properties originated from the plasmonic properties of Au loaded g-C3N4 and the piezoelectric characteristics of c-axis oriented ZnO films may be used for future flexible photonic devices.

Highly Luminescent WS2 Quantum Dots/ZnO Heterojunctions for Light Emitting Devices.

Sonication induced vertical fragmentation of two-dimensional (2D) WS2 nanosheets into highly luminescent, monodispered, zero-dimensional (0D) quantum dots (QDs) is reported. The formation of 0D structures from 2D sheets and their surface/microstructure characterization are revealed from their microscopic and spectroscopic investigations. Size dependent optical properties of WS2 nanostructures have been explored by UV-vis absorption and photoluminescence spectroscopy. Interestingly, it is observed that, below a critical dimension (∼2 nm), comparable to the Bohr exciton radius, the tiny nanocrystals exhibit strong emission. Finally, the electroluminescence characteristics are demonstrated for the first time, by forming a heterojunction of stabilizer free WS2 QDs and ZnO thin films. The signature of white light emission in the light emitting device is attributed to the adequate intermixing of emission characteristics of WS2 QDs and ZnO. The observation of white electroluminescence may pave the way to fabricate prototype futuristic efficient light emitting devices.

Narrowing of band gap and effective charge carrier separation in oxygen deficient TiO2 nanotubes with improved visible light photocatalytic activity.

Oxygen vacancies are introduced into hydrothermally processed TiO2 nanotube by vacuum calcination. Formation of oxygen vacancies modifies the local coordination in TiO2 as evident from Raman spectroscopy and secondary ion mass spectrometry (SIMS) results. The surface area is increased from 172.5m(2)/g in pure to 405.1m(2)/g in defective TiO2 nanotube. The mid-band gap electronic states created by oxygen vacancies are mostly responsible for the effective narrowing of band gap. Charge carrier separation is sufficiently prolonged as the charged oxygen defect states inhibit facile carrier recombination. With high surface area, narrowed band gap and separated charge carriers defective TiO2 nanotube is a suitable candidate in the photodegradation of methylene blue (MB) and phenol under visible light illumination. Photosensitized electron transfer from MB to the conduction band of TiO2 and the photodegradation of MB is facilitated in presence of high density of oxygen vacancies. Unlike MB, phenol absorbs in the UV region and does not easily excited under visible light. Phenol shows activity under visible light by forming charge transfer complex with TiO2. Defect trapped carriers become available at the phenol-TiO2 interface and finally interact with phenol molecule and degrade it.