RESUMO
RATIONALE: An ion trap mass analyzer can be operated by either a sinusoidal waveform power supply or an impulse waveform power supply. The optimal conditions for the performance of ion trap which is driven by an impulse waveform power supply with sinusoidal dipolar voltage were investigated theoretically, and further verified by experiments. METHODS: The analytical relationship between ß and q values is derived theoretically for optimal performance, and the dependencies ß(q) for different trapezoidal waveforms are studied. To explain the dependence of resolution with working point q, the derivative dß/dq is also derived analytically for the case of a rectangular waveform power supply. The theoretical results are further verified by experiments. RESULTS: The results from both theoretical calculations and experiments are in very good agreement. The behaviour resolution with q is controlled by the dispersion dß/dq that was also confirmed by experiments, when the resolution increases with q. CONCLUSIONS: The optimal conditions of ß, qex values and required excitation time n are when S(q) is close to 1 for an ion trap driven by trapezoidal waveform voltage with sinusoidal dipolar voltage. It shown that with increasing impulse parameter τ the dispersion dß/dq decreases and the mass resolution also decreases as result. In the case of applying a rectangular waveform shape voltage, the mass selectivity is the same as for the sinusoidal wave shape. Copyright © 2016 John Wiley & Sons, Ltd.
RESUMO
Calcium oxalate (CaOx) crystals are biominerals present in a wide variety of plants. Formation of these crystals is a biomineralization process occurring in vacuoles within specialized cells called crystal idioblasts. This process is dependent on two key components: deprotonated oxalic acid, and calcium ions (Ca2+), and can result in multiple crystal morphologies. Raphides are needle-like CaOx crystals found in various plant organs and tissues. Though their function is highly debated, they can potentially store calcium, sequester heavy metals, protect against herbivory and possibly programmed cell death. The last review of the taxonomic and anatomical distribution of raphides across the plant kingdom dates back to 1980, in a review by Franceschi and Horner, prompting an updated systematic review of raphides in plants. We conduct a broad literature search to record plant taxa and tissue locations containing raphides. We provide an overview of raphide-forming plant taxa, discussing phylogenetic distribution of raphides at the order level, and report on the specific locations of raphides within plants. Our review reveals raphide occurrence has been studied in 33 orders, 76 families and 1305 species, with raphides presence confirmed in 24 orders, 46 families and 797 species. These taxa represented less than 1 % of known species per family. Leaves are the most prominent raphide-containing primary location in all three major angiosperm clades investigated: Eudicots, Magnoliids, and Monocots. Roots are least reported to contain raphides. The collation of such information lays the groundwork to unveil the genetic origin and evolution of raphides in plants, and highlights targets for future studies of the presence and role of plant raphides.