RESUMO
We have studied 22-oxahemiporphycene molecules by a combination of scanning tunneling microscopy at low temperatures and density functional theory calculations. In contrast to other molecular switches with typically two switching states, these molecules can in principle exist in three different tautomers, due to their asymmetry and three inequivalent binding positions of a hydrogen atom in their macrocycle. Different tautomers are identified from the typical appearance on the surface and tunneling electrons can be used to tautomerize single molecules in a controllable way with the highest rates if the STM tip is placed close to the hydrogen binding positions in the cavity. Characteristic switching processes are explained by the different energy pathways upon adsorption on the surface. Upon applying higher bias voltages, deprotonation occurs instead of tautomerization, which becomes evident in the molecular appearance.
RESUMO
We present a direct observation of carbon-atom tunneling in the flipping reaction of formaldehyde between its two mirror-reflected states on a Cu(110) surface using low-temperature scanning tunneling microscopy (STM). The flipping reaction was monitored in real time, and the reaction rate was found to be temperature independent below 10 K. This indicates that this reaction is governed by quantum mechanical tunneling, albeit involving a substantial motion of the carbon atom (â¼1 Å). In addition, deuteration of the formaldehyde molecule resulted in a significant kinetic isotope effect ( RCH2O/ RCD2O ≈ 10). The adsorption structure, reaction pathway, and tunneling probability were examined by density functional theory calculations, which corroborate the experimental observations.