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1.
Environ Sci Technol ; 54(5): 2985-2993, 2020 03 03.
Artigo em Inglês | MEDLINE | ID: mdl-32072813

RESUMO

Lithium-ion battery demand, particularly for electric vehicles, is projected to increase by over 300% throughout the next decade. With these expected increases in demand, cobalt (Co)-dependent technologies face the risk of significant impact from supply concentration and mining limitations in the short term. Increased extraction and secondary recovery form the basis of modeling scenarios that examine implications on Co supply to 2030. Demand for Co is estimated to range from 235 to 430 ktonnes in 2030. This upper bound on Co demand in 2030 corresponds to 280% of world refinery capacity in 2016. Supply from scheduled and unscheduled production as well as secondary production is estimated to range from 320 to 460 ktonnes. Our analysis suggests the following: (1) Co price will remain relatively stable in the short term, given that this range suggests even a supply surplus, (2) future Co supply will become more diversified geographically and mined more as a byproduct of nickel (Ni) over this period, and (3) for this demand to be met, attention should be paid to sustained investments in refined supply of Co and secondary recovery.


Assuntos
Cobalto , Lítio , Fontes de Energia Elétrica , Mineração , Níquel
2.
Nat Commun ; 12(1): 3753, 2021 06 18.
Artigo em Inglês | MEDLINE | ID: mdl-34145227

RESUMO

Climate change will increase the frequency and severity of supply chain disruptions and large-scale economic crises, also prompting environmentally protective local policies. Here we use econometric time series analysis, inventory-driven price formation, dynamic material flow analysis, and life cycle assessment to model each copper supply chain actor's response to China's solid waste import ban and the COVID-19 pandemic. We demonstrate that the economic changes associated with China's solid waste import ban increase primary refining within China, offsetting the environmental benefits of decreased copper scrap refining and generating a cumulative increase in CO2-equivalent emissions of up to 13 Mt by 2040. Increasing China's refined copper imports reverses this trend, decreasing CO2e emissions in China (up to 180 Mt by 2040) and globally (up to 20 Mt). We test sensitivity to supply chain disruptions using GDP, mining, and refining shocks associated with the COVID-19 pandemic, showing the results translate onto disruption effects.


Assuntos
COVID-19/economia , Dióxido de Carbono/química , Cobre/química , Política Ambiental/legislação & jurisprudência , SARS-CoV-2/patogenicidade , Resíduos Sólidos/economia , COVID-19/epidemiologia , COVID-19/transmissão , COVID-19/virologia , China/epidemiologia , Humanos , Indústrias/economia , SARS-CoV-2/isolamento & purificação , Resíduos Sólidos/estatística & dados numéricos
3.
ACS Appl Mater Interfaces ; 13(42): 50539-50551, 2021 Oct 27.
Artigo em Inglês | MEDLINE | ID: mdl-34637256

RESUMO

A functional material integrated with a variety of functions is highly desired in wastewater treatment. In this research, a mussel-inspired method of immobilizing silver nanoparticles on the skeleton of a melamine sponge is proposed and applied for water remediation. Ag NPs were reduced in situ and grown on a polydopamine-modified melamine sponge. The catalytic reduction of 4-nitrophenol (4-NP) in the presence of the obtained MS-PDA-Ag was evaluated, and the results demonstrated that the MS-PDA-Ag presented high catalytic reduction activity. In addition, the monolithic MS-PDA-Ag presents excellent reusability with no remarkable decrease in catalytic efficiency after multiple reuses. Owing to the immobilized Ag NPs, the MS-PDA-Ag can also effectively inhibit the growth of bacteria against both gram-positive and gram-negative species, making it possible for bacteria elimination in polluted water. To further explore the possibility of utilizing the MS-PDA-Ag for versatile applications, a superhydrophobic derivative (S-MS-PDA-Ag) was prepared by coating a low-surface-energy substance (octadecanethiol) on the surface of MS-PDA-Ag. The obtained S-MS-PDA-Ag presents the capacities of oil/organics adsorption and water repellence, which can separate the insoluble oil/organics from water. The melamine sponge immobilized with Ag NPs demonstrates prominent catalytic reduction of 4-NP, antibacterial activity and the superhydrophobic derivative presents the capacity of insoluble oil/organics separation from oil-water mixtures, exhibiting high potential in the remediation of polluted water.


Assuntos
Antibacterianos/farmacologia , Materiais Biomiméticos/farmacologia , Nanopartículas Metálicas/química , Nitrofenóis/química , Prata/farmacologia , Triazinas/química , Animais , Antibacterianos/química , Antibacterianos/isolamento & purificação , Materiais Biomiméticos/química , Materiais Biomiméticos/isolamento & purificação , Bivalves , Bactérias Gram-Negativas/efeitos dos fármacos , Bactérias Gram-Positivas/efeitos dos fármacos , Interações Hidrofóbicas e Hidrofílicas , Testes de Sensibilidade Microbiana , Óleos/química , Oxirredução , Prata/química , Prata/isolamento & purificação , Água/química , Purificação da Água
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