1.
Chem Commun (Camb)
; 51(73): 13890-3, 2015 Sep 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26221636
RESUMO
A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.